Multimodal polyethylene pipe

Patent metadata

Field	Value
Publication number	US-11286378-B2
Application number	US-201716332020-A
Country	US
Kind code	B2
Filing date	Sep 7, 2017
Priority date	Sep 12, 2016
Publication date	Mar 29, 2022
Grant date	Mar 29, 2022

Abstract

The present invention relates to a reactor system for a multimodal polyethylene polymerization process, comprising: (a) first reactor; (b) a hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, preferably selected, from vacuum pump, compressor, blower, ejector or a combination thereof, the depressurization equipment allowing to adjust an operating pressure to a pressure in a range of 100-200 kPa (abs); (c) the second reactor; and (d) a third reactor and use thereof as a pipe.

First claim

The invention claimed is:

1. A multimodal polyethylene composition made by a process for producing the multimodal polyethylene composition in a reactor system,
the reactor system comprising:
(a) a first reactor;
(b) a hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, the depressurization equipment allowing to adjust an operating pressure to a pressure in a range of 100-200 kPa (abs);
(c) the second reactor; and
(d) a third reactor,
the process comprising:

(a) polymerizing ethylene in an inert hydrocarbon medium in the first reactor in the presence of a catalyst system, selected from Ziegler-Natta catalyst or metallocene, and hydrogen in an amount of 0.1-95% by mol with respect to the total gas present in the vapor phase in the first reactor to obtain a low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol, a density of at least 0.965 g/cm 3 , and an MI2 in the range from 10 to 1,000 g/10 min, or a medium molecular weight polyethylene having a weight average molecular weight (Mw) of 90,000 to 150,000 g/mol, a density of at least 0.965 g/cm 3 and an MI2 in the range from 0.1 to 10 g/10 min;
(b) removing in the hydrogen removal unit 98.0 to 99.8% by weight of the hydrogen comprised in a slurry mixture obtained from the first reactor at a pressure in the range of 103-145 kPa (abs) and transferring the obtained residual mixture to the second reactor;
(c) polymerizing ethylene and optionally C 4 to C 12 α-olefin comonomer in the second reactor in the presence of a catalyst system, selected from Ziegler-Natta catalyst or metallocene, and in the presence of hydrogen in an amount obtained in step (b) to obtain a first high molecular weight polyethylene having a weight average molecular weight (Mw) of 150,000 to 1,000,000 g/mol or a first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of 1,000,000 to 5,000,000 g/mol in the form of a homopolymer or a copolymer and transferring a resultant mixture to the third reactor; and
(d) polymerizing ethylene, and optionally C 4 to C 12 α-olefin comonomer in the third reactor in the presence of a catalyst system, selected from Ziegler-Natta catalyst or metallocene, and hydrogen, wherein the amount of hydrogen in the third reactor is in a range of 0.1-70% by mol with respect to the total gas present in the vapor phase in the third reactor or optionally substantial absence of hydrogen to obtain a second high molecular weight polyethylene having a weight average molecular weight (Mw) of 150,000 to 1,000,000 g/mol or a second ultra high molecular weight polyethylene homopolymer or copolymer having a weight average molecular weight (Mw) of 1,000,000 to 5,000,000 g/mol,
the multimodal polyethylene composition comprising:

(A) 30 to 65 parts by weight of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol or the medium molecular weight polyethylene having a weight average molecular weight (Mw) of 90,000 to 150,000 g/mol;
(B) 5 to 40 parts by weight of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of 150,000 to 1,000,000 g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of 1,000,000 to 5,000,000 g/mol; and
(C) 10 to 60 parts by weight of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of 150,000 to 1,000,000 g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of 1,000,000 to 5,000,000 g/mol,
wherein (A), (B), and (C) each have a different weight average molecular weight, and
wherein a ratio Mw/Mn of the weight average molecular weight Mw of the multimodal polyethylene composition to the number average molecular weight Mn of the multimodal polyethylene composition is from 10 to 60.

2. The multimodal polyethylene composition according to claim 1 , wherein the ratio of Mw/Mn is from 17 to 22.

3. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a weight average molecular weight from 80,000 to 1,300,000 g/mol, measured by Gel Permeation Chromatography.

4. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a number average molecular weight from 5,000 to 30,000 g/mol, measured by Gel Permeation Chromatography.

5. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a Z average molecular weight from 1,000,000 to 6,000,000 g/mol, measured by Gel Permeation Chromatography.

6. The multimodal polyethylene composition according to claim 1 , wherein the multimodal polyethylene composition has a density of 0.945 to 0.965 g/cm 3 , according to ISO 1183 and/or a melt flow index MI 5 from 0.1 to 60 g/10 min.

7. The multimodal polyethylene composition according to claim 6 , wherein the melt flow index MI 5 is from 0.15 to 0.3 g/10 min.

8. The multimodal polyethylene composition according to claim 1 , wherein the total comonomer content with respect to the total amount of monomer units comprised in the low molecular weight polyethylene, the ultra high molecular weight polyethylene and the high molecular weight polyethylene is from 0.5 to 5% mol.

9. A pipe comprising the multimodal polyethylene composition according to claim 1 .

10. A method of using the pipe according to claim 9 , the method comprising flowing a fluid through the pipe under a pressure of at least 10.0 MPa or under atmospheric pressure.

11. The multimodal polyethylene composition of claim 1 , wherein the hydrogen removal unit of the reactor system in which the composition is produced further comprises a stripping column for the separation of hydrogen and a liquid diluent.

12. The multimodal polyethylene composition of claim 1 , wherein the depressurization equipment of the hydrogen removal unit of the reactor system in which the composition is produced further comprises a vacuum pump, a compressor, a blower, and ejector, or a combination thereof.

Assignees

• Thai Polyethylene Co Ltd
• Scg Chemicals Co Ltd

Inventors

• Suchao-In Natthaporn
• Klomkamol Warachad

Classifications

• C08L2203/18

  used for pipes · CPC title

• B01J19/00

  Chemical, physical or physico-chemical processes in general; Their relevant apparatus · CPC title

• C08L23/0815 Primary

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L23/06

  Polyethylene · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title