Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock

Patent metadata

Field	Value
Publication number	US-11279663-B2
Application number	US-201916672052-A
Country	US
Kind code	B2
Filing date	Nov 1, 2019
Priority date	Feb 16, 2017
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

Provided here are systems and methods that integrate a hydrodearylation process and a transalkylation process into an aromatic recovery complex. Various other embodiments may be disclosed and claimed.

First claim

What is claimed is:

1. A process for recovery of alkyl mono-aromatic compounds and benzene, the process comprising the steps of:
supplying an aromatic bottoms stream comprising C 11+ aromatic compounds from an aromatic recovery complex to a hydrodearylation reactor with a hydrodearylation catalyst;
producing from the hydrodearylation reactor by processing the C 11+ aromatic compounds under hydrodearylation conditions a hydrodearylated liquid product stream comprising benzene, toluene, and C 8+ compounds;
supplying a portion of the hydrodearylated liquid product stream to a transalkylation reactor to react the hydrodearylated liquid product stream in the presence of a transalkylation catalyst to produce a transalkylation product stream including benzene, C 8+ aromatics including ethylbenzene and xylenes, and toluene;
separating in a first separation column the transalkylation product stream into three fractions including a first overhead stream comprising benzene, a first bottoms stream comprising C 8+ aromatics including ethylbenzene and xylenes, and a side-cut stream comprising toluene;
recycling toluene from the side-cut stream comprising toluene to the transalkylation reactor; and
producing para-xylene from the first bottoms stream comprising C 8+ aromatics including ethylbenzene and xylenes.

2. The process of claim 1 , wherein the aromatic bottoms stream is from a xylene rerun column of the aromatic recovery complex.

3. The process of claim 1 , further comprising the step of supplying a hydrogen feed stream to the transalkylation reactor.

4. The process of claim 1 , further comprising the step of supplying a hydrogen feed stream to the hydrodearylation reactor.

5. The process of claim 4 , wherein a portion of the hydrogen feed stream is supplied to a catalyst bed in the hydrodearylation reactor to quench the catalyst bed.

6. The process of claim 1 , wherein the hydrodearylation catalyst includes a support being at least one member of the group consisting of silica, alumina, titania, and combinations thereof, and further includes an acidic component being at least one member of the group consisting of amorphous silica-alumina, alumina, zeolite, and combinations thereof.

7. The process of claim 6 , wherein the zeolite is one or more of or derived from FAU, *BEA, MOR, MFI, or MWW framework types.

8. The process of claim 1 , wherein the hydrodearylation catalyst includes an IUPAC Group 6-10 metal being at least one member of the group consisting of iron, cobalt, nickel, molybdenum, tungsten, and combinations thereof.

9. The process of claim 8 , wherein the wherein the IUPAC Group 8-10 metal is 2 to 20 percent by weight of the hydrodearylation catalyst and the IUPAC Group 6 metal is 1 to 25 percent by weight of the catalyst.

10. The process of claim 1 , wherein conditions in the hydrodearylation reactor include an operating temperature in the range of about 200 to 450° C.

11. The process of claim 1 , wherein conditions in the hydrodearylation reactor include an operating temperature in the range of about 250 to 450° C.

12. The process of claim 1 , wherein conditions in the hydrodearylation reactor include an operating hydrogen partial pressure in the range of about 5 bar gauge to 100 bar gauge.

13. The process of claim 1 , further comprising the step of supplying a portion of the hydrodearylated liquid product stream to a catalytic dealkylation reactor comprising a dealkylation catalyst to produce a catalytic dealkylation product stream including benzene, wherein benzene content in the catalytic dealkylation product stream is greater than the benzene content in the transalkylation product stream.

14. The process of claim 13 , further comprising the step of supplying the catalytic dealkylation product stream to the first separation column.

15. The process of claim 13 , where the transalkylation catalyst and dealkylation catalyst each comprises a zeolite.

16. The process of claim 15 , where the transalkylation catalyst comprises at least one catalyst selected from the group consisting of: Beta zeolite; IMF zeolite; ITH zeolite; MFI zeolite; MOR zeolite; MWW zeolite; NES zeolite; Rhenium metal; and a TUN zeolite.

17. The process of claim 1 , where the transalkylation reactor operates at a temperature between about 400° C. to about 450° C., at a pressure between about 25 to about 35 bars, at a feed liquid hourly space velocity (LHSV) of between about 1 to about 3 h −1 , with at least one catalyst active phase metal including a noble metal or a rare earth metal, without steam, and under hydrogen addition.

18. The process of claim 13 , where the catalytic dealkylation reactor operates at a temperature between about 200° C. to about 500° C., at a pressure between about 10 to about 50 bars, at a feed LHSV of between about 1 to about 3 h −1 , with at least one catalyst active phase metal selected from the group consisting of chromium and its oxides, molybdenum and its oxides, platinum and its oxides, without steam, and under hydrogen addition.

19. The process of claim 13 , further comprising the step of recycling toluene from the side-cut stream comprising toluene to the catalytic dealkylation reactor.

Assignees

• Saudi Arabian Oil Co

Inventors

• Koseoglu Omer Refa
• Hodgkins Robert

Classifications

• C07C4/24 Primary

  by splitting polyarylsubstituted aliphatic compounds at an aliphatic-aliphatic bond, e.g. 1,4-diphenylbutane to styrene · CPC title

• C07C4/00

  Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms (redistribution reactions involving splitting C07C6/00; cracking hydrocarbon oils C10G) · CPC title

• C07C4/18

  Catalytic processes · CPC title

• C07C4/26

  by splitting polyaryl compounds at a bond between uncondensed six-membered aromatic rings, e.g. biphenyl to benzene · CPC title

• C07C2529/16

  containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title