Methods and systems of upgrading heavy aromatics stream to petrochemical feedstock

Patent metadata

Field	Value
Publication number	US-10508066-B2
Application number	US-201916388563-A
Country	US
Kind code	B2
Filing date	Apr 18, 2019
Priority date	Feb 16, 2017
Publication date	Dec 17, 2019
Grant date	Dec 17, 2019

Abstract

Provided here are systems and methods that integrate a hydrodearylation process and a transalkylation process into an aromatic recovery complex. Various other embodiments may be disclosed and claimed.

First claim

What is claimed is:

1. A process for recovery of alkyl mono-aromatic compounds, the process comprising the steps of:
supplying a feed stream containing C 9+ compounds from an aromatic complex to a separator to produce a first product stream containing C 9 and C 10 compounds and a second product stream containing one or more of heavy alkyl aromatic compounds and alkyl-bridged non-condensed alkyl multi-aromatic compounds;
supplying the first product stream containing C 9 and C 10 compounds to a transalkylation/toluene disproportionation process unit to yield a third product stream enriched in C 8 compounds;
allowing a hydrogen stream and the second product stream to react in presence of a catalyst under specific reaction conditions in a hydrodearylation reactor to yield a fourth product stream containing one or more alkyl mono-aromatic compounds and a fifth product stream containing C 11+ compounds; and
supplying the fourth product stream to the toluene transalkylation/toluene disproportionation process unit to produce alkyl mono-aromatic compounds.

2. The process of claim 1 , wherein the fourth product stream and the first product stream containing C 9 and C 10 compounds are mixed to form a feed stream for the toluene transalkylation/toluene disproportionation process unit.

3. The process of claim 1 , wherein the feed stream is from a xylene rerun column of an aromatic recovery process.

4. The process of claim 1 , wherein the feed stream is undiluted by a solvent.

5. The process of claim 1 , wherein a portion of the hydrogen stream is supplied to a catalyst bed in the hydrodearylation reactor to quench the catalyst bed.

6. The process of claim 5 , wherein the catalyst includes a support being at least one member of the group consisting of silica, alumina, titania, and combinations thereof, and further includes an acidic component being at least one member of the group consisting of amorphous silica-alumina, alumina, zeolite, and combinations thereof.

7. The process of claim 6 , wherein the zeolite is one or more of or derived from FAU, *BEA, MOR, MFI, or MWW framework types.

8. The process of claim 5 , wherein the catalyst includes an IUPAC Group 6-10 metal being at least one member of the group consisting of iron, cobalt, nickel, molybdenum, tungsten, and combinations thereof.

9. The process of claim 8 , wherein the wherein the IUPAC Group 8-10 metal is 2 to 20 percent by weight of the catalyst and the IUPAC Group 6 metal is 1 to 25 percent by weight of the catalyst.

10. The process of claim 1 , wherein conditions in the hydrodearylation reactor include an operating temperature in the range of about 200 to 450° C.

11. The process of claim 1 , wherein conditions in the hydrodearylation reactor include an operating temperature in the range of about 250 to 450° C.

12. The process of claim 1 , wherein conditions in the hydrodearylation reactor include an operating hydrogen partial pressure in the range of about 5 bar gauge to 100 bar gauge.

13. The process of claim 1 , wherein one of the alkyl mono-aromatic compounds produced by the toluene transalkylation/toluene disproportionation is a para-xylene.

14. The process of claim 1 , further comprising:
supplying the fourth product stream containing one or more alkyl mono-aromatic compounds to a separator to recover a benzene-containing stream; and
supplying the benzene-containing stream to the toluene transalkylation/toluene disproportionation process unit to produce alkyl mono-aromatic compounds.

15. The process of claim 14 , further comprising:
recovering a C 8 stream from the separator; and
supplying the C 8 stream to a para-xylene unit to produce para-xylene.

16. The process of claim 14 , further comprising:
recovering a C 9+ stream from the separator; and
supplying the C 9+ stream to the toluene transalkylation/toluene disproportionation process unit to produce alkyl mono-aromatic compounds.

17. The process of claim 1 , further comprising:
supplying the fourth product stream containing one or more alkyl mono-aromatic compounds to a separator to recover a toluene-containing stream; and
supplying the toluene-containing stream to the toluene transalkylation/toluene disproportionation process unit to produce alkyl mono-aromatic compounds.

Assignees

• Saudi Arabian Oil Co

Inventors

• Koseoglu Omer Refa
• Hodgkins Robert

Classifications

• C07C6/126 Primary

  of more than one hydrocarbon · CPC title

• C07C4/24 Primary

  by splitting polyarylsubstituted aliphatic compounds at an aliphatic-aliphatic bond, e.g. 1,4-diphenylbutane to styrene · CPC title

• C07C2529/16

  containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• C07C4/26

  by splitting polyaryl compounds at a bond between uncondensed six-membered aromatic rings, e.g. biphenyl to benzene · CPC title