Fiber assisted re-crosslinkable polymer gel and preformed particle gels for fluid loss and conformance control

Patent metadata

Field	Value
Publication number	US-11268009-B2
Application number	US-202017014608-A
Country	US
Kind code	B2
Filing date	Sep 8, 2020
Priority date	Jun 2, 2016
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

Described herein are compositions useful for controlling fluid flow, for example in a target zone of a subterranean environment, and methods of forming and using the same. The composition generally comprises a quantity of fibers and a quantity of swellable particles, which may be dispersed in a carrier fluid. The composition may be synthesized in the form of a bulk gel or may be gelatinated during use. The fibers in the compositions provide improved performance as compared to prior PPG and RPPG particle-containing compositions. Specifically, the compositions reinforce the re-cross-linked/re-associated hydrogel plug in underground features and support proper rehydration of RPPG particles with water or brine to better to provide structural support for the particles within the gel and to more completely fill underground void space conduits.

First claim

The invention claimed is:

1. A composition useful for controlling fluid flow, said composition comprising a quantity of fibers and a quantity of swellable particles comprising a crosslinking agent and/or an assembling agent interspersed among polymer chains.

2. The composition of claim 1 , wherein the quantity of fibers comprises a natural fiber material.

3. The composition of claim 2 , wherein the quantity of fibers comprises vegetable fiber, wood fiber, animal fiber, mineral fiber, and/or biological fiber.

4. The composition of claim 1 , wherein the quantity of fibers comprises a man-made fiber material.

5. The composition of claim 4 , wherein the quantity of fibers comprises semi-synthetic and/or synthetic fiber.

6. The composition of claim 5 , wherein the quantity of fibers comprises cellulose regenerated fibers, metallic fibers, carbon fibers, silicon carbide fibers, fiberglass, mineral fibers, and/or polymer fibers.

7. The composition of claim 6 , wherein the quantity of fibers comprises a synthetic fiber material selected from the group consisting of polyethylene, polypropylene, nylons, and polyvinyl alcohol.

8. The composition of claim 1 , wherein the fibers within the quantity of fibers have an average length of about 0.1 mm to about 100 mm.

9. The composition of claim 1 , wherein the fibers within the quantity of fibers have an average diameter of about 0.1 μm to about 1,000 μm.

10. The composition of claim 1 , wherein the fibers within the quantity of fibers have an aspect ratio of about 10 to about 1000.

11. The composition of claim 1 , wherein the swellable particles comprise polymer chains formed from one or more monomers selected from the group consisting of acrylamides, sugars/saccharides, chloroprene, nitrile-containing compounds, sulfonates, acrylates, methacrylate, silicates, nano-clays and combinations of the foregoing.

12. The composition of claim 11 , wherein the swellable particles comprise an assembling agent selected from the group consisting of polyacrylamide, one of the multivalent Group III-VII transition metal molecules, methylene bisacrylamide, polyethylene glycol, dimethacrylate, phenol-formaldehyde, diallylamine, triallylamine, divinyl sulfonate, diethylene glycol diallyl aldehydes, diethyeneglycol diallyl ether, polyethyleneimine, dichlorophenol, benzoyl peroxide, di-tert-butyl peroxide, dibutyl hydrogen phosphite (DBHP), and mixtures thereof.

13. The composition of claim 1 , wherein the swellable particles comprise a polymer matrix comprised of a monomer having a re-cross-linking moiety, a monomer having an acid resistance moiety, a monomer having a CO 2 -philic moiety, and/or a cross-linkable monomer.

14. The composition of claim 1 , wherein the swellable particles comprise a cross-linking agent and/or a re-cross-linking agent.

15. The composition of claim 1 , wherein the swellable particles further comprise tackifiers, plasticizers, polymers, aromatic compounds, polysaccharides, deoxidants, adjustors of gelant, clays, nanoclay, initiators, stabilizers, celluloses, epoxy resins, silica, silicon oxide, aluminum oxide, carbon nanotubes, graphene, ethylenediaminetetraacetic acid, nanoparticles, oxygen scavengers, chelating agents, thickening agents, fibers, and/or biocides.

16. The composition of claim 1 , wherein the composition comprises the quantity of fibers and the quantity of swellable particles at a weight ratio of about 1:1000 to about 10:1.

17. The composition of claim 1 , wherein the quantity of fibers and the quantity of swellable particles are dispersed in a carrier fluid.

18. The composition of claim 17 , wherein the carrier fluid comprises an aqueous solvent system.

19. The composition of claim 17 , wherein the composition comprises from about 0.01% by weight to about 20% by weight of the quantity of fibers.

20. The composition of claim 17 , wherein the composition comprises from about 0.1% to about 40% by weight of the quantity of swellable particles.

21. A method of forming a gel formation in a target zone of a subterranean environment, said method comprising introducing the composition of any one of claims 1 through 20 into the subterranean environment.

22. The method of claim 21 , further comprising performing one or more of the following:
(i) contacting the composition with a fluid, thereby causing the composition to swell;
(ii) exposing the composition to a temperature of at least 50° C. within the target zone, thereby causing at least a portion of the cross-linkable polymer chains to cross-link.

23. The method of claim 22 , wherein the swelling (i) results in the association, cross-linking, and/or reassembly of the cross-linkable polymer chains.

24. The method of claim 22 , wherein said swelling (i) causes the quantity of particles to associate, combine together, and form a bulk gel.

25. The method of claim 22 , wherein the fluid is an aqueous solvent system.

26. The method of claim 21 , wherein the environment is selected from the group consisting of wells, pipelines, and fractures.

27. The method of claim 21 , wherein the quantity of particles have an initial average particle size prior to contact with the fluid and wherein upon contact with the fluid, the quantity of particles swell to a second average particle size that is about 5 times to about 200 times that of the initial average particle size.

28. A method of forming the composition of any one of claims 1 - 20 , the method comprising:
(i) dispersing the quantity of fibers in a carrier fluid and forming a homogenous mixture; and
(ii) dispersing the quantity of swellable particles in the homogenous mixture, thereby causing at least a portion of the quantity of swellable particles to swell.

29. A method of forming the composition of any one of claims 1 - 20 , the method comprising:
(i) mixing the quantity of fibers and the quantity of swellable particles to form a homogenous mixture; and
(ii) contacting the homogenous mixture with a carrier fluid, thereby causing at least a portion of the quantity of swellable particles to swell.

Assignees

• Univ Missouri

Inventors

• Bai Baojun
• Wang Ze
• Sun Zhe
• Pu Jingyang
• Schuman Thomas

Classifications

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• C08J5/045

  with vegetable or animal fibrous material · CPC title

• C08K2003/2227

  of aluminium · CPC title

• C04B14/48

  Metal · CPC title

• C08J2433/26

  Homopolymers or copolymers of acrylamide or methacrylamide · CPC title