Drilling fluids with crosslinked sulfonate-containing polymers dispersed in high density brines

Patent metadata

Field	Value
Publication number	US-10000683-B2
Application number	US-201514904465-A
Country	US
Kind code	B2
Filing date	Jul 1, 2015
Priority date	Mar 3, 2015
Publication date	Jun 19, 2018
Grant date	Jun 19, 2018

Abstract

Crosslinked sulfonate-containing polymers may be stable in high density, monovalent brines, which may render such polymers particularly useful in drilling fluids in general and, especially, in the subclass of drilling fluids known as drill-in fluids. For example, a drilling fluid may include a crosslinked sulfonate-containing polymer dispersed in a monovalent brine having a density of about 8 lb/gal to about 20 lb/gal, wherein the crosslinked sulfonate-containing polymer comprises: reactants of a first repeating unit and a crosslinker that react to form the crosslinked sulfonate-containing polymer, wherein the first repeating unit is a sulfonic acid-containing monomer present from 50% to 99.99% by weight of the reactants, and wherein the crosslinker comprises at least two olefinic bonds.

First claim

The invention claimed is:

1. A method comprising:
drilling at least a portion of a wellbore penetrating a subterranean formation with a drilling fluid that comprises a crosslinked sulfonate-containing polymer dispersed in a monovalent brine having a density of about 8 lb/gal to about 20 lb/gal, wherein the crosslinked sulfonate-containing polymer comprises: reactants of a first repeating unit and a crosslinker that react to form the crosslinked sulfonate-containing polymer, wherein the first repeating unit is a sulfonic acid-containing monomer present from 50% to 99.99% by weight of the reactants and wherein the crosslinker comprises at least two olefinic bonds, and a plastic viscosity of the drilling fluid is within a range from 18 cP to 27 cP.

2. The method of claim 1 , wherein the crosslinked sulfonate-containing polymer further comprises reactants of a second repeating unit selected from the group consisting of an N-vinyl amide-containing monomer, a terminal double bond-containing monomer, and any combination thereof that is present from 1% to 50% by weight of the reactants.

3. The method of claim 2 , wherein the N-vinyl amide-containing monomer is selected from the group consisting of a pyrrolidone-containing N-vinyl amide, a piperidone-containing N-vinyl amide, a caprolactam-containing N-vinyl amide, an acrylate-containing N-vinyl amide, an alkene-containing N-vinyl amide, an alkyl-containing N-vinyl amide, and any combination thereof.

4. The method of claim 2 , wherein the N-vinyl amide-containing monomer is selected from the group consisting of N-vinyl-2-pyrrolidone; N-vinyl-2-caprolactam; N-vinyl-piperidone; N-vinyl-3-methyl pyrrolidone; N-vinyl-4-methylpyrrolidone; N-vinyl-5-methylpyrrolidone; N-vinyl-3-ethyl pyrrolidone; N-vinyl-3-butyl pyrrolidone; N-vinyl-3,3-dimethylpyrrolidone; N-vinyl-4, 5-dimethylpyrrolidone; N-vinyl-5,5-dimethylpyrrolidone; N-vinyl-3,3,5-trimethylpyrrolidone; N-vinyl-5-methyl-5-ethyl pyrrolidone; N-vinyl-3,4,5-trimethyl-3-ethyl pyrrolidone; N-vinyl-6-methyl-2-piperidone; N-vinyl-6-ethyl-2-piperidone; N-vinyl-3,5-dimethyl-2-piperidone; N-vinyl-4,4-dimethyl-2-piperidone; N-vinyl-6-propyl-2-piperidone; N-vinyl-3-octyl piperidone; N-vinyl-7-methyl caprolactam; N-vinyl-7-ethyl caprolactam; N-vinyl-4-isopropyl caprolactam; N-vinyl-5-isopropyl caprolactam; N-vinyl-4-butyl caprolactam; N-vinyl-5-butyl caprolactam; N-vinyl-4-butyl caprolactam; N-vinyl-5-tert-butyl caprolactam; N-vinyl-4-octyl caprolactam; N-vinyl-5-tert-octyl caprolactam; N-vinyl-4-nonyl caprolactam; N-vinyl-5-tert-nonyl caprolactam; N-vinyl-3,7-dimethyl caprolactam; N-vinyl-3,5-dimethyl caprolactam; N-vinyl-4,6-dimethyl caprolactam; N-vinyl-3,5,7-trimethyl caprolactam; N-vinyl-2-methyl-4-isopropyl caprolactam; N-vinyl-5-isopropyl-7-methyl caprolactam; N-vinylformamide; N-vinylacetamide; N-vinylpropanamide; N-vinyl-N-methylacetamide; and any combination thereof.

5. The method of claim 2 , wherein the terminal double bond-containing monomer is selected from the group consisting of acrylamide, N-substituted acrylamides, methacrylamide, N-substituted methacrylamides, acrylates, methacrylates, acrylic acid, methacrylic acid, N-allylamides, vinyl alcohol, vinyl ethers, vinyl esters, allyl alcohol, allyl ethers, allyl esters, vinylpyridine, vinylimidazole, allylimidazole, diallyldimethylammonium halide, any salt thereof, and any combination thereof.

6. The method of claim 1 , wherein the crosslinked sulfonate-containing polymer is present in the drilling fluid at about 0.1% to about 10% by weight of the drilling fluid.

7. The method of claim 1 , wherein the sulfonic acid-containing monomer is selected from the group consisting of an acrylic sulfonic acid, a methylallyl sulfonic acid, an allyl sulfonic acid, a styrene sulfonic acid, a vinyl sulfonic acid, a vinyl aromatic sulfonic acid, any salt thereof, and any combination thereof.

8. The method of claim 1 , wherein the sulfonic acid-containing monomer is selected from the group consisting of 2-acrylamido-2-methylpropane sulfonic acid, 2-(meth)acrylamido-2-methylpropanesulfonic acid, α-methyl styrenesulfonic acid, 2-sulfoethyl methacrylate, vinylbenzene sulfonic acid, 3-allyloxy-2-hydroxy-1-propanesulfonic acid, any salt thereof, any ester thereof, and any combination thereof.

9. The method of claim 1 , wherein the crosslinker is selected from the group consisting of a crosslinker with at least two vinyl groups; a crosslinker with at least two allyl groups; a crosslinker with at least two acrylate groups; a crosslinker with at least two methacrylate groups; a crosslinker with at least two acrylamide groups; a crosslinker with at least two methacrylamide groups; a crosslinker with at least two groups from at least two of a vinyl group, an allyl group, an acrylate group, a methacrylate group, an acrylamide group, and a methacrylamide group; and any combination thereof.

10. The method of claim 1 , wherein the monovalent brine comprises at least one selected from the group consisting of lithium formate, sodium formate, potassium formate, rubidium formate, cesium formate, lithium acetate, sodium acetate, potassium acetate, rubidium acetate, cesium acetate, lithium chloride, sodium chloride, potassium chloride, rubidium chloride, cesium chloride, lithium bromide, sodium bromide, potassium bromide, rubidium bromide, cesium bromide, and any combination thereof.

11. The method of claim 1 , wherein the portion of the wellbore extends through a hydrocarbon-containing portion of the subterranean formation.

12. A method comprising:
drilling at least a portion of a wellbore penetrating a subterranean formation with a drilling fluid that comprises a crosslinked sulfonate-containing polymer dispersed in a monovalent brine having a density of about 8 lb/gal to about 20 lb/gal, wherein the crosslinked sulfonate-containing polymer comprises: reactants of a first repeating unit, a second repeating unit and a crosslinker that react to form the crosslinked sulfonate-containing polymer, wherein the first repeating unit is a sulfonic acid-containing monomer present from 50% to 99.99% by weight of the reactants, the second repeating unit is an N-vinyl amide-containing monomer present from 1% to 50%, and wherein the crosslinker comprises at least two olefinic bonds, and a plastic viscosity of the drilling fluid is within a range from 18 cP to 27 cP.

Assignees

• Halliburton Energy Services Inc

Inventors

• Galindo Kay Ann
• Zhou Hui
• Zha Weibin

Classifications

• C09K8/12 Primary

  containing synthetic organic macromolecular compounds or their precursors · CPC title

• C09K8/035 Primary

  Organic additives · CPC title

• E21B7/00

  Special methods or apparatus for drilling · CPC title

• C09K8/02 Primary

  Well-drilling compositions · CPC title

• E21B21/00

  Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor (freeing objects stuck in boreholes by flushing E21B31/03) · CPC title