Butene-1 polymer composition having high melt flow rate

Patent metadata

Field	Value
Publication number	US-11267911-B2
Application number	US-201816633241-A
Country	US
Kind code	B2
Filing date	Aug 3, 2018
Priority date	Aug 4, 2017
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

A butene-1 polymer composition having a MFR value of from 100 to 300 g/10 min., measured according to ISO 1133 at 190° C. with a load of 2.16 kg, made from or containing:A) a butene-1 homopolymer or a copolymer of butene-1 with one or more comonomers selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of up to 5% by mole;B) a copolymer of butene-1 with one or more comonomers selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of from 6% to 20% by mole;wherein the composition having a total copolymerized comonomer content from 4% to 15% by mole, referred to the sum of A) and B), and a content of fraction soluble in xylene at 0° C. of 75% by weight or less, determined on the total weight of A) and B).

First claim

What is claimed is:

1. A butene-1 polymer composition having a MFR value from 100 to 300 g/10 min measured according to ISO 1133 at 190° C. with a load of 2.16 kg, and comprising:
A) a butene-1 homopolymer or a copolymer of butene-1 with one or more comonomers selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content (C A ) of up to 5% by mole; and
B) a copolymer of butene-1 with one or more comonomers selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content (C B ) of from 6% to 20% by mole;

wherein the butene-1 polymer composition has a total copolymerized comonomer content from 4% to 15% by mole based on a sum of A) and B), and a content of fraction soluble in xylene at 0° C. of 75% by weight or less based on a total weight of A) and B).

2. The butene-1 polymer composition of claim 1 , comprising from 30% to 70% by weight of A) and from 30% to 70% by weight of B), based on the total weight of A) and B).

3. The butene-1 polymer composition of claim 1 , having DH TmII values of from 4 to 15 J/g, measured with a scanning speed corresponding to 10° C./min.

4. The butene-1 polymer composition of claim 1 , having a Mw/Mn value, where Mw is weight average molar mass and Mn is number average molar mass, both measured by GPC, equal to or lower than 3.5.

5. The butene-1 polymer composition of claim 1 , having a Mz value, measured by GPC, of 90,000 g/mol or higher.

6. The butene-1 polymer composition of claim 1 , having a Mw value equal to or greater than 50,000 g/mol.

7. A process for preparing the butene-1 polymer composition of claim 1 , comprising:
carrying out at least two sequential stages in two or more reactors connected in series, wherein A) and B) are prepared in separate subsequent stages, operating in each stage, except the first stage, in the presence of a polymer formed and a catalyst used in a preceding stage.

8. The process of claim 7 , carried out in the presence of a metallocene catalyst obtained by contacting:
a stereorigid metallocene compound;
an alumoxane or a compound that forms an alkyl metallocene cation; and, optionally,
an organo aluminum compound.

9. A manufactured article comprising:
the butene-1 polymer composition of claim 1 .

10. The manufactured article of claim 9 wherein the manufactured article is a film or a fiber.

11. A hot-melt adhesive composition comprising:
the butene-1 polymer composition of claim 1 .

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Marchini Roberta
• Spataro Stefano
• Pica Roberta

Classifications

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• C08F2/001

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L2314/06

  Metallocene or single site catalysts · CPC title

• C08F110/08

  Butenes · CPC title