Method of preparing aromatic vinyl compound-vinyl cyanide compound polymer and apparatus for preparing the same

Patent metadata

Field	Value
Publication number	US-11267906-B2
Application number	US-201916632505-A
Country	US
Kind code	B2
Filing date	Jul 9, 2019
Priority date	Dec 19, 2018
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

A method of preparing an aromatic vinyl compound-vinyl cyanide compound polymer includes polymerizing a reaction mixture containing an aromatic vinyl compound, a vinyl cyanide compound, and an organic solvent in a reactor and transferring the vaporized reaction mixture present in the upper space of the reactor to a heat exchanger via a pipe and condensing the vaporized reaction mixture. The condensed reaction mixture is transferred to one side of the pipe and sprayed into the pipe, the flow velocity of the reaction mixture vaporized in the reactor is reduced, and temperature is lowered. Accordingly, a phenomenon wherein polymer particles in a reactor are sucked into a heat exchanger is prevented, and occurrence of polymerization in the heat exchanger is suppressed. Therefore, productivity and quality may be improved.

First claim

The invention claimed is:

1. A method of preparing an aromatic vinyl compound-vinyl cyanide compound polymer, comprising:
polymerizing a reaction mixture containing 40 to 80% by weight of an aromatic vinyl compound, 10 to 35% by weight of a vinyl cyanide compound, and 5 to 35% by weight of an organic solvent in a reactor; and
transferring the vaporized reaction mixture present in an upper space of the reactor to a heat exchanger via a pipe and condensing the vaporized reaction mixture,
wherein the condensed reaction mixture is transferred to one side of the pipe and sprayed into the pipe.

2. The method according to claim 1 , wherein the spraying is performed so that a flow of the condensed reaction mixture is countercurrent to a flow of the vaporized reaction mixture.

3. The method according to claim 1 , wherein the spray comprises all or a portion of the reaction mixture transferred to the heat exchanger.

4. The method according to claim 1 , wherein a temperature of the reaction mixture transferred to the heat exchanger after the spraying is 100 to 140° C., and a temperature of the reaction mixture discharged from the heat exchanger is 15 to 50° C.

5. The method according to claim 1 , wherein a flow velocity of the reaction mixture transferred to the heat exchanger after the spraying is 1.0 to 2.0 m/sec.

6. The method according to claim 1 , wherein the polymerization reaction is performed at a temperature of 150 to 170° C. under a pressure of 1.0 to 4.0 kgf/cm 2 g.

7. The method according to claim 1 , wherein the aromatic vinyl compound is one or more selected from the group consisting of styrene, α-methyl styrene, p-methyl styrene, p-bromostyrene, p-chlorostyrene, and o-bromostyrene.

8. The method according to claim 1 , wherein the vinyl cyanide compound is acrylonitrile, methacrylonitrile, or a mixture thereof.

9. The method according to claim 1 , wherein the organic solvent is one or more selected from the group consisting of toluene, ethylbenzene, xylene, methyl ethyl ketone, and methyl isobutyl ketone.

10. An apparatus for preparing an aromatic vinyl compound-vinyl cyanide compound polymer, comprising:
a reactor in which a reaction mixture containing 40 to 80% by weight of an aromatic vinyl compound, 10 to 35% by weight of a vinyl cyanide compound, and 5 to 35% by weight of an organic solvent is polymerized;
a heat exchanger for condensing the reaction mixture vaporized in the reactor;
a gas pipe for transferring the vaporized reaction mixture from an upper space of the reactor to the heat exchanger; and
a condensate pipe for transferring the condensed reaction mixture from the heat exchanger to one side of the gas pipe,
wherein the condensate pipe comprises a spray nozzle.

11. The apparatus according to claim 10 , wherein the spray nozzle is installed so that a part or a whole thereof is located in the gas pipe and a flow of a condensed reaction mixture to be sprayed is countercurrent to a flow of a reaction mixture vaporized in the reactor.

12. A method of preparing an aromatic vinyl compound-vinyl cyanide compound polymer, comprising:
polymerizing a reaction mixture containing an aromatic vinyl compound, a vinyl cyanide compound, and an organic solvent in a reactor; and
transferring the vaporized reaction mixture present in an upper space of the reactor to a heat exchanger via a pipe and condensing the vaporized reaction mixture,
wherein the condensed reaction mixture is transferred to one side of the pipe and sprayed into the pipe, and
wherein a temperature of the reaction mixture transferred to the heat exchanger after the spraying is 100 to 140° C., and a temperature of the reaction mixture discharged from the heat exchanger is 15 to 50° C.

Assignees

• Lg Chemical Ltd

Inventors

• Shin Daeyoung
• Hwang Jeong A
• Joo Eun Jung
• Lee Won Kyun
• Jang Sungkeun

Classifications

• B01J2219/00164

  controlling the flow · CPC title

• C08F212/10 Primary

  with nitriles · CPC title

• C08F212/08 Primary

  Styrene · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• B01J19/18

  Stationary reactors having moving elements inside (B01J19/08, B01J19/26 take precedence) · CPC title