Method and a system for separating and treating impurities from a hydrogen chloride liquid mixture

Patent metadata

Field	Value
Publication number	US-11267703-B2
Application number	US-201716312358-A
Country	US
Kind code	B2
Filing date	Jun 30, 2017
Priority date	Jun 30, 2016
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

The present invention relates to a method and a system for separating and treating impurities from a hydrogen chloride liquid mixture from the process for preparing isocyanate with phosgenation including sending hydrogen chloride liquid mixture into a gas-liquid separation column for separation to yield a liquid phase flow with impurities at the bottom of the gas-liquid separation column, neutralizing the liquid phase flow comprising impurities with an alkaline liquid in the neutralization tank to yield a neutralized solution, and sending the neutralized solution into a waste liquid treatment device from said neutralization tank for treatment.

First claim

The invention claimed is:

1. A method of separating and treating impurities from a hydrogen chloride liquid mixture, comprising the steps of:
sending said hydrogen chloride liquid mixture comprising impurities into a gas-liquid separation column for separation to yield a liquid phase flow comprising impurities at the bottom of said gas-liquid separation column, and said impurities comprising ammonium chloride;
making said liquid phase flow comprising impurities flow into a neutralization tank, neutralizing said liquid phase flow comprising impurities with an alkaline liquid in said neutralization tank to yield a neutralized solution; and
sending the neutralized solution into a waste liquid treatment device from said neutralization tank for treatment,
and obtaining said hydrogen chloride liquid mixture from a process for preparing isocyanate with phosgenation.

2. The method according to claim 1 , wherein said neutralization tank is arranged below said gas-liquid separation column, and the pressure in said neutralization tank is not higher than the pressure in said gas-liquid separation column.

3. The method according to claim 1 , wherein a buffer tank is further arranged between said gas-liquid separation column and said neutralization tank, such that said liquid phase flow comprising impurities sequentially flows into said buffer tank from the bottom of said gas-liquid separation column through a first liquid phase flow pipeline L 1 , and then flows into the neutralization tank through a second liquid phase flow pipeline L 2 from said buffer tank.

4. The method according to claim 3 , wherein said buffer tank is arranged below said gas-liquid separation column, and said neutralization tank is arranged below said buffer tank, the pressure in said buffer tank being not higher than the pressure in said gas-liquid separation column, and the pressure in said neutralization tank is not higher than the pressure in said buffer tank.

5. The method according to claim 3 , wherein the volume of said liquid phase flow comprising impurities buffered in said buffer tank does not exceed 90% of the volume of said buffer tank.

6. The method according to claim 1 , wherein the liquid phase flow comprising impurities flows into the neutralization tank through a liquid phase flow pipeline L 1 from the bottom of said gas-liquid separation column, and wherein the liquid phase flow pipeline is purged with an inert gas after said liquid phase flow comprising impurities flows through said liquid phase flow pipeline.

7. The method according to claim 1 , wherein the pH value of said neutralized solution is not less than 8.

8. The method according to claim 1 , wherein said alkaline liquid comprises a base selected from one or more of the following group consisting of: alkali metal hydroxides, and alkaline earth metal hydroxides.

9. The method according to claim 1 , wherein said method is a continuous or batch operation.

10. A system for separating and treating impurities from a hydrogen chloride liquid mixture, comprising:
a gas-liquid separation column having a top and a bottom, an inlet stream comprising a liquid mixture of hydrogen chloride and impurities comprising ammonium chloride, an outlet stream comprising hydrogen chloride gas at the top of the gas-liquid separation column, a first liquid phase flow outlet stream at the bottom of the gas-liquid separation column, wherein the first liquid phase flow comprises impurities comprising ammonium chloride, and a first liquid phase flow pipeline connected to the bottom of the gas-liquid separation column;
a neutralizing tank connected via the first liquid phase flow pipeline to the bottom of the gas-liquid separation column for receiving said first liquid phase flow comprising impurities,
and neutralizing said liquid phase flow comprising impurities with an alkaline liquid in said neutralization tank to yield a neutralized solution; and
a waste liquid treatment device for receiving and treating said neutralized solution from said neutralization tank
wherein the system further comprises a pipeline for a hydrogen chloride liquid mixture from a production site for preparing isocyanate with phosgenation which comprises the inlet stream comprising the liquid mixture of hydrogen chloride and impurities comprising ammonium chloride.

11. The system according to claim 10 , wherein the pressure in said neutralization tank is not higher than the pressure in said gas-liquid separation column.

12. The system according to claim 10 , further comprising an inert gas purge valve for purging said first liquid phase flow pipeline with an inert gas after said first liquid phase flow comprising impurities flows through the first liquid phase flow pipeline.

13. A method of preparing isocyanate with phosgenation, comprising the steps of:
obtaining an isocyanate product and a gas mixture comprising hydrogen chloride from a phosgenation reaction process;
treating said gas mixture comprising hydrogen chloride to yield a hydrogen chloride liquid mixture; and
separating and treating said hydrogen chloride liquid mixture according to the method of claim 1 .

14. A system for preparing isocyanate with phosgenation, comprising:
a phosgenation reaction unit for carrying out a phosgenation reaction to yield an isocyanate product and a gas mixture comprising hydrogen chloride;
a hydrogen chloride-containing gas mixture treatment unit for treating said gas mixture comprising hydrogen chloride to yield a hydrogen chloride liquid mixture; and
a hydrogen chloride liquid mixture separation and treatment unit for separating and treating said hydrogen chloride liquid mixture according to the system of claim 10 .

15. A system for separating and treating impurities from a hydrogen chloride liquid mixture, comprising:
a gas-liquid separation column having a top and a bottom, an inlet stream comprising a liquid mixture of hydrogen chloride and impurities comprising ammonium chloride, an outlet stream comprising hydrogen chloride gas at the top of the gas-liquid separation column, a first liquid phase flow outlet stream at the bottom of the gas-liquid separation column, wherein the first liquid phase flow comprises impurities comprising ammonium chloride, and a first liquid phase flow pipeline connected to the bottom of the gas-liquid separation column;
a buffer tank connected via the first liquid phase flow pipeline, for buffering said first liquid phase flow comprising impurities,
a neutralizing tank connected to the buffer tank via a second liquid phase flow pipeline, for neutralizing the buffered liquid phase flow comprising impurities with an alkaline liquid to form a neutralized solution;
wherein the first liquid phase flow comprising impurities sequentially flows into said buffer tank from the bottom of said gas-liquid separation column through said first liquid phase flow pipeline, and then flows into the neutralization tank through the second liquid phase flow pipeline from the buffer tank,
a waste liquid treatment device for receiving and treating the neutralized solution from the neutralization tank and
wherein the system further comprises a pipeline for a hydrogen chloride liquid mixture from a production site for preparing isocyanate with phosgenation which comprises the inlet stream comprising the liquid mixture of hydrogen chloride and impurities comprising ammonium chloride.

16. The system according to claim 15 , wherein the pressure in the gas-liquid separation column is from 5 to 25 bar gauge pressure, and the pressure in the buffer tank is from 0 to 10 bar gauge pressure.

Assignees

• Covestro Deutschland Ag

Inventors

• Rittermeier Andre
• Hellmich Rainer
• Soppe Alfred
• Wu Luyan
• Qian Micky
• Lehner Peter
• Bittner Jürgen
• Steffens Friedhelm
• Fink Henrike
• Jakobs Eric

Classifications

• C07C263/20

  Separation; Purification · CPC title

• C01B7/0712 Primary

  by distillation · CPC title

• C07C263/10

  by reaction of amines with carbonyl halides, e.g. with phosgene · CPC title