Glass substrate, liquid crystal antenna and high-frequency device

Patent metadata

Field	Value
Publication number	US-11239549-B2
Application number	US-202017022365-A
Country	US
Kind code	B2
Filing date	Sep 16, 2020
Priority date	Mar 20, 2018
Publication date	Feb 1, 2022
Grant date	Feb 1, 2022

Abstract

Provided is a glass substrate with which it is possible to reduce dielectric loss in high-frequency signals, and which also has excellent thermal shock resistance. This invention satisfies the relation {Young's modulus (GPa)×average thermal expansion coefficient (ppm/° C.) at 50-350° C.}≤300 (GPa·ppm/° C.), wherein the relative dielectric constant at 20° C. and 35 GHz does not exceed 10, and the dielectric dissipation factor at 20° C. and 35 GHz does not exceed 0.006.

First claim

The invention claimed is:

1. A glass substrate satisfying the following relationship:
{[Young's modulus (GPa)]×[average coefficient of thermal expansion at 50-350° C. (ppm/° C.)]}≤300 (GPa·ppm/° C.), and

having a relative permittivity as measured at 20° C. and 35 GHz of 10 or less and a dielectric loss tangent as measured at 20° C. and 35 GHz of 0.006 or less.

2. The glass substrate according to claim 1 , having the Young's modulus of 70 GPa or less.

3. The glass substrate according to claim 1 , having the average coefficient of thermal expansion at 50-350° C. of 5 ppm/° C. or less.

4. The glass substrate according to claim 1 , having a relative permittivity as measured at 20° C. and 10 GHz of 10 or less and a dielectric loss tangent as measured at 20° C. and 10 GHz of 0.006 or less.

5. The glass substrate according to claim 1 , having an area of a main surface of 100 cm 2 -100,000 cm 2 and a thickness of 0.01 mm-2 mm.

6. The glass substrate according to claim 1 , wherein at least a part of an end surface thereof is chamfered.

7. The glass substrate according to claim 1 , having a Vickers hardness of 400-550.

8. The glass substrate according to claim 1 , having a cracking load of higher than 1.96 N.

9. The glass substrate according to claim 1 , having a density of 2.5 g/cm 3 or less.

10. The glass substrate according to claim 1 , having a compressive stress layer formed in at least a part of a surface of the main surface.

11. The glass substrate according to claim 1 , having a porosity of 0.1% or less.

12. The glass substrate according to claim 1 , having a transmittance for light having 350-nm wavelength of 50% or higher.

13. The glass substrate according to claim 1 , having β-OH value of 0.05 mm −1 -0.8 mm −1 .

14. The glass substrate according to claim 1 , comprising SiO 2 as a main component, and in mole percentage on an oxide basis,
comprising Al 2 O 3 and B 2 O 3 in a total amount of 1-40%,
having a content molar ratio represented by {Al 2 O 3 /(Al 2 /O 3 +B 2 O 3 )} of 0-0.45, and
comprising one or more alkaline-earth metal oxides in a total amount of 0.1-13%.

15. The glass substrate according to claim 1 , comprising one or more alkali metal oxides in a total amount of 0.001-5% in mole percentage on an oxide basis.

16. The glass substrate according to claim 15 , having a content molar ratio represented by {Na 2 O/(Na 2 O+K 2 O)} of 0.01-0.99, among the alkali metal oxides.

17. The glass substrate according to claim 1 , satisfying the following relationship of contents in mole percentage on an oxide basis:
{1.02×SiO 2 +3.42×Al 2 O 3 +0.74×B 2 O 3 +9.17×MgO+12.55×CaO+13.85×SrO+14.44×BaO+31.61×Na 2 O+20.35×K 2 O}≤300.

18. The glass substrate according to claim 1 , comprising Al 2 O 3 in an amount of 0-10% and B 2 O 3 in an amount of 9-30% in mole percentage on an oxide basis.

19. The glass substrate according to claim 1 , comprising Fe in an amount of 0-0.012% in terms of Fe 2 O 3 in mole percentage on an oxide basis.

20. The glass substrate according to claim 1 , which is for use in a liquid-crystal antenna or a high-frequency circuit.

21. A liquid-crystal antenna comprising the glass substrate according to claim 1 .

22. A high-frequency device comprising the glass substrate according to claim 1 .

Assignees

• Agc Inc

Inventors

• Nomura Shuhei
• Ono Kazutaka

Classifications

• C03C4/0085

  for UV-transmitting glass · CPC title

• H01Q1/38 Primary

  formed by a conductive layer on an insulating support {(patch antennas H01Q9/0407; microstrip dipole antennas H01Q9/065; microstrip slot antennas H01Q13/106; transmission line microstrip antennas H01Q13/206; manufacturing reflecting surfaces using insulating material for supporting the reflecting surface  H01Q15/142)} · CPC title

• C03C3/091 Primary

  containing aluminium · CPC title

• C03C3/087

  containing calcium oxide, e.g. common sheet or container glass · CPC title

• H01Q9/0407

  Substantially flat resonant element parallel to ground plane, e.g. patch antenna (dipole H01Q9/285; monopole H01Q9/40) · CPC title