Thermoplastic resin composition, method of preparing the same, and molded part manufactured using the same

Patent metadata

Field	Value
Publication number	US-11236224-B2
Application number	US-201716325138-A
Country	US
Kind code	B2
Filing date	Nov 13, 2017
Priority date	Sep 19, 2017
Publication date	Feb 1, 2022
Grant date	Feb 1, 2022

Abstract

Disclosed are a thermoplastic resin composition, a method of preparing the same, and a molded part manufactured using the same, wherein the thermoplastic resin composition includes a-1) 1 to 30% by weight of a first graft polymer obtained by graft-polymerizing an aromatic vinyl compound and a vinyl cyanide compound onto a conjugated diene rubber having an average particle diameter of 0.05 μm or more and less than 0.2 μm; a-2) 5 to 45% by weight of a second graft polymer obtained by graft-polymerizing an aromatic vinyl compound and a vinyl cyanide compound onto a conjugated diene rubber having an average particle diameter of 0.2 to 0.5 μm; b) 50 to 80% by weight of an aromatic vinyl compound-vinyl cyanide compound copolymer; and c) 1 to 10% by weight of a (meth)acrylic acid alkyl ester polymer.

First claim

The invention claimed is:

1. A plated thermoplastic resin composition, the thermoplastic resin composition comprising:
a-1) 1 to 30% by weight of a first graft polymer obtained by graft-polymerizing an aromatic vinyl compound and a vinyl cyanide compound onto a conjugated diene rubber having an average particle diameter of 0.05 μm or more and less than 0.2 μm;
a-2) 5 to 45% by weight of a second graft polymer obtained by graft-polymerizing an aromatic vinyl compound and a vinyl cyanide compound onto a conjugated diene rubber having an average particle diameter of 0.2 to 0.5 μm;
b) 50 to 80% by weight of an aromatic vinyl compound-vinyl cyanide compound copolymer; and
c) 1 to 10% by weight of a (meth)acrylic acid alkyl ester polymer,
wherein the thermoplastic resin composition is a plating material, and a plating process using a chromium-free etchant is used to plate the thermoplastic resin composition.

2. The plated thermoplastic resin composition according to claim 1 , wherein a weight ratio of the first graft polymer to the second graft polymer is 1:0.5 to 1:4.

3. The plated thermoplastic resin composition according to claim 1 , wherein each of the first and second graft copolymers is obtained by graft-polymerizing 10 to 70% by weight of an aromatic vinyl compound and 1 to 30% by weight of a vinyl cyanide compound onto 20 to 80% by weight of a conjugated diene rubber.

4. The plated thermoplastic resin composition according to claim 1 , wherein the aromatic vinyl compound-vinyl cyanide compound copolymer comprises 10 to 40% by weight of a vinyl cyanide compound.

5. The plated thermoplastic resin composition according to claim 1 , wherein the aromatic vinyl compound-vinyl cyanide compound copolymer has a weight average molecular weight of 50,000 to 200,000 g/mol.

6. The plated thermoplastic resin composition according to claim 1 , wherein the (meth)acrylic acid alkyl ester polymer is obtained by polymerizing one or more selected from methyl acrylate, ethyl acrylate, methyl methacrylate, ethyl methacrylate, and methyl ethacrylate.

7. The plated thermoplastic resin composition according to claim 1 , wherein the (meth)acrylic acid alkyl ester polymer is a block copolymer composed of a (meth)acrylic acid alkyl ester polymer and an aromatic vinyl compound-vinyl cyanide compound copolymer; a master batch of a (meth)acrylic acid alkyl ester polymer using an aromatic vinyl compound-vinyl cyanide compound copolymer as a base resin; or both.

8. The plated thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a melt index (220° C., 10 kg) of 14 to 40 g/10 min according to ASTM D1238.

9. The plated thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin composition has a plating adhesion of 8.0 N/cm or more.

10. The plated thermoplastic resin composition according to claim 1 , wherein a 6.4 mm thick sample of the composition has an impact strength of 20 kgfcm/cm 2 or more according to ASTM D256.

11. A method of manufacturing a plated part as in claim 1 , wherein the part is a molded part, comprising:
a step, in which the thermoplastic resin composition according to claim 1 is subjected to injection molding to obtain an injection-molded part;
a step of etching the injection-molded part using the chromium-free etchant, the chromium-free etchant containing KMnO 4 and phosphoric acid; and
a step of plating the etched injection-molded part by performing a plating process.

12. The molded and plated part according to claim 11 , wherein the molded part comprises a substrate comprising the thermoplastic resin composition and a plating layer coated on a surface of the substrate, wherein the plating layer is bonded to the substrate via anchoring.

13. A molded and plated part, comprising the plated thermoplastic resin composition according to claim 1 .

Assignees

• Lg Chemical Ltd

Inventors

• Lee Ju Hyeong
• Kang Byoung Il
• Han Se Jin

Classifications

• C25D3/04

  of chromium · CPC title

• C08L51/04 Primary

  grafted on to rubbers · CPC title

• C23C18/1641

  Organic substrates, e.g. resin, plastic · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L25/12 Primary

  with unsaturated nitriles · CPC title