Integrated method and apparatus for catalytic cracking of heavy oil and production of syngas

Patent metadata

Field	Value
Publication number	US-11230674-B2
Application number	US-202017028930-A
Country	US
Kind code	B2
Filing date	Sep 22, 2020
Priority date	Sep 23, 2019
Publication date	Jan 25, 2022
Grant date	Jan 25, 2022

Abstract

The present disclosure provides an integrated method and apparatus for catalytic cracking of heavy oil and production of syngas. A cracking-gasification coupled reactor having a cracking section and a gasification section is used as a reactor in the method. A heavy oil feedstock is fed into a cracking section to contact with a bed material in a fluidized state that contains a cracking catalyst, a catalytic cracking reaction is conducted under atmospheric pressure to obtain light oil-gas and coke. The coke is carried downward by the bed material into a gasification section to conduct a gasification reaction to generate syngas; the syngas goes upward into the cracking section to merge with the light oil-gas, and is guided out from the coupled reactor and enter a gas-solid separation system. Oil-gas fractionation is performed to a purified oil-gas product output from the gas-solid separation system to collect light oil and syngas products.

First claim

What is claimed is:

1. An integrated method for catalytic cracking of heavy oil and production of syngas, wherein a cracking-gasification coupled reactor having a cracking section and a gasification section that are internally connected with each other is used as a reactor, the integrated method comprises:
feeding a heavy oil feedstock into the cracking section in an upper portion of the cracking-gasification coupled reactor to contact with a bed material in a fluidized state that contains a cracking catalyst, a catalytic cracking reaction is conducted under atmospheric pressure to obtain light oil-gas and coke; the coke is carried downward by the bed material into the gasification section in a lower portion of the cracking-gasification coupled reactor to conduct a gasification reaction to generate syngas; the syngas goes upward in the cracking-gasification coupled reactor into the cracking section to merge with the light oil-gas, and is guided out from the coupled reactor to a gas-solid separation system;
subjecting the light oil-gas and the syngas in the gas-solid separation system to at least a first-stage gas-solid separation, and bed material particles separated out are collected and divided into two parts, and returned to the cracking section and the gasification section, respectively, to form a first-stage circulation and a second-stage circulation of the bed material particles accordingly; and
performing oil-gas fractionation to a purified oil-gas product output from the gas-solid separation system to collect light oil and syngas products;
wherein, the integrated method, before the coke is carried by the bed material downward into the gasification section in a lower portion of the cracking-gasification coupled reactor, further comprises performing a steam stripping processing and a particle size refining processing sequentially to the downward bed material particles.

2. The integrated method according to claim 1 , wherein,
subjecting the light oil-gas and the syngas in the gas-solid separation system comprises: the first-stage gas-solid separation and further comprises a sequential second-stage gas-solid separation, wherein first-stage bed material particles and second-stage bed material particles are separated out in sequence and the purified oil-gas product is collected;
the first-stage bed material particles are returned to the cracking section to form the first-stage circulation; and the second-stage bed material particles are returned to the gasification section to form the second-stage circulation; wherein, a particle size of the first-stage bed material particles is greater than a particle size of the second-stage bed material particles; or,
subjecting the light oil-gas and the syngas in the gas-solid separation system to the first-stage gas-solid separation, and the bed material particles collected are sent back to the cracking section and the gasification section, respectively, through a material returning and distributing mechanism by means of fluidizing gas blowback, to form the first-stage circulation and the second-stage circulation.

3. The integrated method according to claim 2 , wherein, a particle size of the first-stage bed material particles is a, and 30≤a≤200 μm; a particle size of the second-stage bed particles is b, and 5<b<30 μm.

4. The integrated method according to claim 1 , wherein, a reaction temperature of the cracking reaction is 450-700° C., an agent-oil ratio is 4-20, a reaction time is 1-20 s, and an apparent gas velocity is 1-20 m/s, wherein the agent-oil ratio is a mass ratio between an amount of the bed material fed and an amount of the heavy oil feedstock fed.

5. The integrated method according to claim 1 , wherein, a reaction temperature of the gasification reaction is 850-1200□, a reaction pressure is atmospheric pressure, an apparent gas velocity is 0.1-5.0 m/s, and a residence time is 1-20 min.

6. The integrated method according to claim 2 , wherein, before the coke is carried by the bed material downward into the gasification section in a lower portion of the cracking-gasification coupled reactor, further comprising performing a steam stripping processing and a particle size refining processing sequentially to the downward bed material particles.

7. The integrated method according to claim 3 , wherein, before the coke is carried by the bed material downward into the gasification section in a lower portion of the cracking-gasification coupled reactor, further comprising performing a steam stripping processing and a particle size refining processing sequentially to the downward bed material particles.

8. The integrated method according to claim 4 , wherein, before the coke is carried by the bed material downward into the gasification section in a lower portion of the cracking-gasification coupled reactor, further comprising performing a steam stripping processing and a particle size refining processing sequentially to the downward bed material particles.

9. The integrated method according to claim 5 , wherein, before the coke is carried by the bed material downward into the gasification section in a lower portion of the cracking-gasification coupled reactor, further comprising performing a steam stripping processing and a particle size refining processing sequentially to the downward bed material particles.

10. The integrated method according to claim 1 , wherein, conditions of the steam stripping processing are: a mass ratio of water vapor to the heavy oil feedstock is 0.1-0.3, a temperature of the water vapor is 200-400° C., and an apparent gas velocity of the water vapor is 0.5-5.0 m/s.

11. The integrated method according to claim 1 , wherein Conradson carbon residue of the heavy oil feedstock is larger than or equal to 8%.

12. The integrated method according to claim 2 , wherein Conradson carbon residue of the heavy oil feedstock is larger than or equal to 8%.

13. The integrated method according to claim 3 , wherein Conradson carbon residue of the heavy oil feedstock is larger than or equal to 8%.

14. The integrated method according to claim 4 , wherein Conradson carbon residue of the heavy oil feedstock is larger than or equal to 8%.

15. The integrated method according to claim 5 , wherein Conradson carbon residue of the heavy oil feedstock is larger than or equal to 8%.

16. The integrated method according to claim 10 , wherein Conradson carbon residue of the heavy oil feedstock is larger than or equal to 8%.

17. An integrated apparatus for catalytic cracking of heavy oil and production of syngas configured to implement the integrated method according to claim 1 , comprising:
a cracking-gasification coupled reactor, comprising a cracking section and a gasification section that are internally connected with each other, and an oil-gas outlet located on top of the cracking-gasification coupled reactor and connected with the cracking section;
the cracking section is located above the gasification section;
the cracking section is provided with a feedstock inlet and a first solid phase inlet;
the gasification section is provided with a second solid phase inlet;
a gas-solid separation system, comprising: a material inlet, a gas phase outlet and a solid phase outlet;
a first gas-solid separator and a second gas-solid separator, the first gas-solid separator comprises a first material inlet, a first gas phase cutlet and a first solid phase outlet, and the second gas-solid separator comprises a second material inlet, a second gas phase outlet and a second solid phase outlet;
and a fractionating tower, comprising: a fractionating tower i

Assignees

• Univ China Petroleum Beijing

Inventors

• Lan Xingying
• Zhang Yuming
• Gao Jinsen
• Wang Chengxiu

Classifications

• C10G55/06 Primary

  including at least one catalytic cracking step · CPC title

• C10G2300/107

  Atmospheric residues having a boiling point of at least about 538 °C · CPC title

• C10J3/62

  with separate withdrawal of the distillation products · CPC title

• C10J3/48

  Apparatus; Plants · CPC title

• C10J2300/0959

  Oxygen · CPC title