Processes for producing petrochemical products that utilize fluid catalytic cracking

Patent metadata

Field	Value
Publication number	US-11230672-B1
Application number	US-202017009048-A
Country	US
Kind code	B1
Filing date	Sep 1, 2020
Priority date	Sep 1, 2020
Publication date	Jan 25, 2022
Grant date	Jan 25, 2022

Abstract

According to one more embodiments, petrochemical products may be produced from a hydrocarbon material by a process that may comprise separating the hydrocarbon material into at least a lesser boiling point fraction, a medium boiling point fraction, and a greater boiling point fraction. The process may further comprise cracking at least a portion of the lesser boiling point fraction and the medium boiling point fraction in a second reactor unit in the presence of a second catalyst at a reaction temperature of from 500° C. to 700° C. to produce a second cracking reaction product, wherein the lesser boiling point fraction enters the second reactor unit upstream of wherein the medium boiling point fraction enters the second reactor.

First claim

What is claimed is:

1. A process for producing petrochemical products from a hydrocarbon material, the process comprising:
separating the hydrocarbon material into at least a lesser boiling point fraction, a medium boiling point fraction, and a greater boiling point fraction;
cracking at least a portion of the greater boiling point fraction in the presence of a first catalyst in a first reactor unit at a reaction temperature of from 500° C. to 700° C. to produce a first cracking reaction product;
cracking at least a portion of the lesser boiling point fraction and the medium boiling point fraction in a second reactor unit in the presence of a second catalyst at a reaction temperature of from 500° C. to 700° C. to produce a second cracking reaction product, wherein the lesser boiling point fraction enters the second reactor unit upstream of wherein the medium boiling point fraction enters the second reactor; and
separating the petrochemical products from one or both of the first cracking reaction product or the second cracking reaction product,
wherein the lesser boiling point fraction is initially exposed to greater temperatures in the second reactor unit, initially has a greater catalyst:oil ratio in the second reactor unit, has a greater residence time in the second reactor unit, or combinations thereof, as compared to the medium boiling point fraction.

2. The process of claim 1 , wherein the hydrocarbon material is crude oil.

3. The process of claim 1 , further comprising:
mixing the greater boiling point fraction with the first catalyst to crack at least a portion of the greater boiling point fraction; and
separating the first catalyst from at least a portion of the first cracking reaction product.

4. The process of claim 1 , further comprising:
mixing the lesser boiling point fraction with the second catalyst;
mixing the medium boiling point fraction with the second catalyst; and
separating the second catalyst from at least a portion of the second cracking reaction product.

5. The process of claim 1 , wherein at least 90 wt. % of the hydrocarbon material is present in the combination of the lesser boiling point fraction, the medium boiling point fraction, and the greater boiling point fraction.

6. The process of claim 1 , wherein:
the first cracking reaction product and the second cracking reaction product are combined to form a combined reaction product; and
the combined reaction product is separated into the petrochemical products.

7. The process of claim 1 , wherein the second reactor unit comprises a catalyst mixing zone and a cracking reaction zone.

8. The process of claim 1 , wherein at least 40 wt. % of the combination of the first cracking reaction product, the second cracking reaction product, or both, comprises ethylene, propene, butene, or pentene, or combinations of these.

9. The process of claim 1 , wherein a cut point of the lesser boiling point fraction and the medium boiling point fraction is from 140° C. to 175° C.

10. The process of claim 1 , wherein a cut point of the medium boiling point fraction and the greater boiling point fraction is from 300° C. to 450° C.

11. A process for operating a hydrocarbon feed conversion system for producing a petrochemical product stream from a hydrocarbon feed stream, the process comprising:
introducing the hydrocarbon feed stream to a feed separator;
separating the hydrocarbon feed stream into at least a lesser boiling point fraction stream, a medium boiling point fraction stream, and a greater boiling point fraction stream in the feed separator;
passing the greater boiling point fraction stream to a first fluidized catalytic cracking unit;
passing the lesser boiling point fraction stream and the medium boiling point fraction stream to a second fluidized catalytic cracking unit, wherein the lesser boiling point fraction stream is passed into the second fluidized catalytic cracking unit upstream of the medium boiling point fraction stream;
cracking at least a portion of the greater boiling point fraction stream in the first fluidized catalytic cracking unit in the presence of a first catalyst at a reaction temperature of from 500° C. to 700° C. to produce a first cracking reaction product stream;
cracking at least a portion of the lesser boiling point fraction stream and the medium boiling point fraction stream in the second fluidized catalytic cracking unit in the presence of a second catalyst and at a reaction temperature of from 500° C. to 700° C. to produce a second cracking reaction product stream; and
separating the petrochemical product stream from one or both of the first cracking reaction product stream or the second cracking reaction product stream,
wherein the lesser boiling point fraction stream is initially exposed to greater temperatures in the second reactor unit, initially has a greater catalyst:oil ratio in the second reactor unit, has a greater residence time in the second reactor unit, or combinations thereof, as compared to the medium boiling point fraction stream.

12. The process of claim 11 , wherein at least 90 wt. % of the hydrocarbon feed stream is present in the combination of the lesser boiling point fraction, the medium boiling point fraction, and the greater boiling point fraction.

13. The process of claim 11 , wherein a difference between the 5 wt. % boiling point and the 95 wt. % boiling point of the hydrocarbon feed stream is at least 100° C.

14. The process of claim 11 , wherein a cut point of the lesser boiling point fraction stream and the medium boiling point fraction stream is from 140° C. to 175° C., and wherein a cut point of the medium boiling point fraction and the greater boiling point fraction is from 300° C. to 450° C.

15. The process of claim 11 , wherein the second fluidized catalytic cracking unit comprises:
a catalyst mixing zone;
a cracking reaction zone; and
a separation zone.

16. The process of claim 11 , wherein:
the first cracking reaction product stream and the second cracking reaction product stream are combined to form a combined reaction product stream; and
the combined reaction product stream is separated into the petrochemical product stream.

17. The process of claim 11 , wherein the hydrocarbon feed stream is crude oil.

18. The process of claim 11 , wherein at least 40 wt. % of the combination of the first cracking reaction product stream, the second cracking reaction product stream, or both, comprises at least one of ethylene, propene, butene, or pentene.

19. The process of claim 1 , wherein each of the first reactor unit and the second reactor unit is a downflow reactor.

20. The process of claim 11 , wherein each of the first fluidized catalytic cracking unit and the second fluidized catalytic cracking unit is a downflow fluidized catalytic cracking unit.

Assignees

• Saudi Arabian Oil Co

Inventors

• Al Herz Mansour Ali
• Bourane Abdennour
• Al Jawad Ali
• Ballesteros Alberto Lozano

Classifications

• C10G2400/22

  Higher olefins · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G2300/1048

  Middle distillates · CPC title

• C10G2300/1044

  Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C · CPC title

• C10G2300/104

  Light gasoline having a boiling range of about 20 - 100 °C · CPC title