Process and apparatus for cracking hydrocarbons with recycled catalyst to produce additional distillate

Patent metadata

Field	Value
Publication number	US-9783749-B2
Application number	US-201514642977-A
Country	US
Kind code	B2
Filing date	Mar 10, 2015
Priority date	Mar 10, 2015
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A process and apparatus is for recycling LCO and/or HCO to an FCC unit to recover additional distillate. Spent catalyst recycle in the FCC unit may be used to improve distillate yield. A hydroprocessing zone may saturate cycle oil aromatics for cracking in an FCC unit. The recycle cracked stream may be recycled to a downstream hydroprocessing zone to avoid a first hydroprocessing zone for hydrotreating feed to the FCC unit. Additional recovery of cycle oil for recycle is obtained by heating slurry oil prior to vacuum separation.

First claim

The invention claimed is:

1. A process for catalytically cracking hydrocarbons comprising:
feeding a fresh hydrocarbon feed stream to a hydroprocessing zone to hydroprocess the hydrocarbon feed stream to provide a hydroprocessed effluent stream;
separating hydroprocessed products from said hydroprocessed effluent stream to provide an FCC feed stream;
feeding said FCC feed stream to an FCC reactor and contacting said FCC feed stream with catalyst to catalytically crack said FCC feed stream to provide a cracked stream;
disengaging said catalyst from said cracked stream;
regenerating a first portion of said catalyst disengaged from said cracked stream;
recycling a second portion of said catalyst disengaged from said cracked stream to be contacted with said FCC feed stream without undergoing regeneration, wherein said second portion has about 0.7 to about 1.1 wt % coke on catalyst;
separating a recycle cracked stream from said cracked stream; and
feeding said recycle cracked stream to said hydroprocessing zone.

2. The process of claim 1 wherein a ratio of catalyst to oil in said FCC reactor is between about 8 and about 20.

3. The process of claim 1 wherein the second portion of catalyst comprises between about 10 and about 50 wt % of the catalyst in a riser of the FCC reactor.

4. The process of claim 1 wherein the average coke on the catalyst in the reaction zone is between about 0.1 and about 0.6 wt %.

5. The process of claim 1 further comprising feeding said cracked stream to a main fractionation column and taking said recycle cracked stream from an outlet in the main fractionation column.

6. The process of claim 5 further comprising:
fractionating said cracked stream into products including a slurry oil stream from a bottom outlet of a main fractionation column;
separating said slurry oil stream into a cycle oil stream and a heavy stream under vacuum pressure; and
recycling said cycle oil stream as said recycle cracked stream.

7. The process of claim 6 further comprising heating said slurry oil stream before separating said slurry oil stream.

8. The process of claim 1 wherein said fresh hydrocarbon feed stream comprises vacuum gas oil having a T5 of at least 316° C. (600° F.).

9. A process for catalytically cracking hydrocarbons comprising:
feeding a fresh hydrocarbon feed stream to a hydroprocessing zone to hydroprocess the hydrocarbon feed stream to provide a hydroprocessed effluent stream;
separating hydroprocessed products from said hydroprocessed effluent stream to provide an FCC feed stream;
feeding said FCC feed stream to an FCC reactor and contacting said FCC feed stream with catalyst to catalytically crack said FCC feed stream to provide a cracked stream;
disengaging said catalyst from said cracked stream;
regenerating a first portion of said catalyst disengaged from said cracked stream;
recycling a second portion of said catalyst disengaged from said cracked stream to be contacted with said FCC feed stream without undergoing regeneration, wherein said second portion has about 0.7 to about 1.10 wt % coke on catalyst; and
separating a recycled cracked stream from said cracked stream and feeding said recycle cracked stream to said hydroprocessing zone.

10. The process of claim 9 wherein a ratio of catalyst to oil in said FCC reactor is between about 8 and about 20.

11. The process of claim 9 wherein the second portion of catalyst comprises between 10 and 50 wt % of the catalyst in a riser of the FCC reactor.

12. The process of claim 9 wherein the average coke on the catalyst in the reaction zone is between about 0.1 and about 0.6 wt %.

13. The process of claim 9 further comprising feeding said cracked stream to a main fractionation column and taking said recycle cracked stream from an outlet in the main fractionation column.

14. The process of claim 13 further comprising
fractionating said cracked stream into products including a slurry oil stream from a bottom outlet of a main fractionation column;
separating said slurry oil stream into a cycle oil stream and a heavy stream under vacuum pressure; and
recycling said cycle oil stream as said recycle cracked stream.

15. The process of claim 14 further comprising heating said slurry oil stream before separating said slurry oil stream.

16. The process of claim 9 wherein said fresh hydrocarbon feed stream comprises vacuum gas oil having a T5 of at least 316° C. (600° F.).

17. A process for catalytically cracking hydrocarbons comprising:
feeding a fresh hydrocarbon feed stream to a hydroprocessing zone to hydroprocess the hydrocarbon feed stream to provide a hydroprocessed effluent stream;
feeding an FCC feed stream to an FCC reactor and contacting said FCC feed stream with catalyst to catalytically crack said FCC feed stream to provide a cracked stream;
disengaging said catalyst from said cracked stream;
regenerating a first portion of said catalyst disengaged from said cracked stream; and
recycling a second portion of said catalyst disengaged from said cracked stream to be contacted with said FCC feed stream without undergoing regeneration, wherein said second portion has about 0.7 to about 1.10 wt % coke on catalyst; and
separating a recycled cracked stream from said cracked stream and feeding said recycle cracked stream to said hydroprocessing zone.

18. The process of claim 17 wherein a ratio of catalyst to oil in said FCC reactor is between about 8 and about 20.

19. The process of claim 17 wherein the second portion of catalyst comprises between 10 and 50 wt % of the catalyst in a riser of the FCC reactor.

Assignees

• Uop Llc

Inventors

• Davydov Lev

Classifications

• C10G45/44

  Hydrogenation of the aromatic hydrocarbons · CPC title

• C10G11/18

  according to the "fluidised-bed" technique · CPC title

• C10G45/02

  to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing · CPC title

• C10G69/04 Primary

  including at least one step of catalytic cracking in the absence of hydrogen · CPC title