Sintering aid for glasses for machinable phyllosilicate based structures

Patent metadata

Field	Value
Publication number	US-11225433-B2
Application number	US-201615740102-A
Country	US
Kind code	B2
Filing date	Dec 2, 2016
Priority date	Feb 19, 2016
Publication date	Jan 18, 2022
Grant date	Jan 18, 2022

Abstract

A sintered machinable glass-ceramic is provided. The machinable glass-ceramic is formed by mixing phyllosilicate material having a sheet structure, with a glass fit and firing the mixture at relatively low temperatures to sinter the phyllosilicate, while maintaining the sheet-like morphology of the phyllosilicate and its associated cleaving properties. The sintered machinable glass-ceramic can be machined with conventional metal working tools and includes the electrical properties of the phyllosilicate. Producing the sintered machinable glass-ceramic does not require the relatively high-temperature bulk nucleation and crystallization needed to form sheet phyllosilicate phases in situ.

First claim

What is claimed is:

1. A sintered machinable glass-ceramic comprising phyllosilicate ceramic defined as a continuous phase, and a glass component defined as a discontinuous phase, the glass component including a glass frit,
the glass frit comprising before firing
BaO at 30-65 wt %,
CaO at 2-15 wt %,
Al 2 O 3 at 2-8 wt %,
B 2 O 3 at 4-12 wt %, and
SiO 2 at 15-35 wt %.

2. The machinable glass-ceramic according to claim 1 , wherein the glass component is included at 8-71 wt % of the total weight of the phyllosilicate ceramic and the glass component.

3. The machinable glass-ceramic according to claim 2 , wherein the glass component is included at 40-60 wt % of the total weight of the phyllosilicate ceramic and the glass component.

4. The machinable glass-ceramic according to claim 3 , wherein the glass component is included at 45-55 wt % of the total weight of the phyllosilicate ceramic and the glass component.

5. The machinable glass-ceramic according to claim 1 , wherein the phyllosilicate ceramic before sintering, is in the form of a powder or flakes.

6. The machinable glass-ceramic according to claim 1 , wherein the phyllosilicate ceramic comprises a mica group phyllosilicate mineral.

7. The machinable glass-ceramic according to claim 1 , further comprising before firing an inorganic filler selected from the group consisting of alumina, anorthite, gahnite, mullite, bismuth oxide, boron oxide, fused silica, crystalline silica, molybdenum oxide, titania, titanates, magnesium silicate, calcium silicate, strontium silicate, barium silicate, magnesium titanate, calcium titanate, strontium titanate, barium titanate, eucryptite, cordierite, cobalt oxide, chromium oxide, tungsten oxide, zinc oxide, zinc silicate, zircon, and zirconia, alkaline earth borates, zinc borate, zirconyl phosphates, and combinations thereof.

8. The machinable glass-ceramic according to claim 1 , further comprising before firing a coloring agent selected from the group consisting of Corundum structure Pigment Green 17, Pigment Brown 29, Red 101, Red 102, Red 230, Red 231, Rutile structure Pigment Black 24, Brown 24, Brown 37, Brown 40, Yellow 53, Yellow 161, Yellow 162, Yellow 163, Yellow 164, Yellow 189, Red 236, Spinel structure Pigment Black 12, Black 26, Black 27, Black 28, Black 29, Black 30, Blue 28, Blue 36, Blue 72, Brown 33, Brown 34, Brown 35, Green 26, Green 50, and other structures such as Borate Violet 48, Garnet Green 51, Olivine Blue 73, Periclase Black 25, Phenacite Blue 74, Phosphate Violet 14, Violet 47, Priderite Yellow 157, Pyrochlore Yellow 41, Sphene Red 233, and Zircon Blue 71, Red 232, Yellow 159, and combinations thereof.

9. The machinable glass-ceramic according to claim 1 , wherein the phyllosilicate ceramic substantially maintains its plate-like structure after sintering.

10. A method of forming a sintered machinable glass-ceramic, the method comprising:
providing phyllosilicate in powder or flakes form,
providing a glass component comprising a glass frit,
the glass frit comprising before firing
BaO at 30-65 wt %,
CaO at 2-15 wt %
Al 2 O 3 at 2-8 wt %,
B 2 O 3 at 4-12 wt %, and
SiO 2 at 15-35 wt %,

mixing the phyllosilicate powder and the glass component, and
sintering the mixture of the phyllosilicate powder and the glass component, thereby forming a sintered machinable glass-ceramic;
wherein the phyllosilicate defines a continuous phase in the sintered machinable glass-ceramic and the glass component defines a discontinuous phase in the sintered machinable glass-ceramic; and
wherein the phyllosilicate substantially maintains its plate-like structure after sintering.

11. The method according to claim 10 , wherein the glass component is included at 8-71 wt % of the total weight of the phyllosilicate powder and the glass component.

12. The method according to claim 11 , wherein the glass component is included at 40-60 wt % of the total weight of the phyllosilicate powder and the glass component.

13. The method according to claim 12 , wherein the glass component is included at 45-55 wt % of the total weight of the phyllosilicate powder and the glass component.

14. The method according to claim 10 , wherein the phyllosilicate comprises a mica group phyllosilicate mineral.

15. The method according to claim 10 , wherein mixing includes adding a binder to the mixture of the phyllosilicate powder and the glass component.

16. The method according to claim 15 , further comprising pressing the mixture into a desired shape before firing.

17. A sintered machinable glass-ceramic comprising phyllosilicate ceramic, and a glass component including a glass frit,
the glass frit comprising before firing
BaO at 30-65 wt %,
CaO at 2-15 wt %,
Al 2 O 3 at 2-8 wt %,
B 2 O 3 at 4-12 wt %, and
SiO 2 at 15-35 wt %, and

further comprising one or more oxides selected from the group consisting of Nb 2 O 5 , Ta 2 O 5 , Sb 2 O 5 , Y 2 O 3 , La 2 O 3 , CeO 2 , and TeO 2 .

18. The machinable glass-ceramic according to claim 17 , wherein the glass component is included at 8-71 wt % of the total weight of the phyllosilicate ceramic and the glass component.

19. The machinable glass-ceramic according to claim 17 , wherein the softening point of the machinable glass-ceramic ranges from 550° C. to 900° C.

Assignees

• Ferro Corp

Inventors

• Sridharan Srinivasan
• Sakoske George E
• Maloney John J
• Gleason Cody
• Prinzbach Gregory R
• Smith Bradford
• Wang Chih Cheng

Classifications

• C03C3/064 Primary

  containing boron · CPC title

• C03C8/04

  containing zinc · CPC title

• C03C14/00

  Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix (devitrified glass ceramics C03C10/00) · CPC title

• C03C10/0045 Primary

  containing SiO2, Al2O3 and MgO as main constituents · CPC title

• C03C3/066

  containing zinc · CPC title