Liquid crystal elastomers

Patent metadata

Field	Value
Publication number	US-11214642-B2
Application number	US-201916653876-A
Country	US
Kind code	B2
Filing date	Oct 15, 2019
Priority date	Oct 15, 2018
Publication date	Jan 4, 2022
Grant date	Jan 4, 2022

Abstract

Shape-programmable liquid crystal elastomers. The shape-programmable liquid crystal elastomers being synthesized by filling an alignment cell with liquid crystal monomers. The liquid crystal monomers align to a surface of the alignment cell and then are polymerized with a dithiol chain transfer agent. The alignment cell is configured to impose a director orientation on a portion of the shape-programmable liquid crystal elastomer. For some embodiments, liquid crystal elastomer laminates are prepared by arranging a plurality of liquid crystal elastomers such that a director orientation of each liquid crystal elastomer of the plurality is in registered alignment with an adjacent liquid crystal elastomer of the plurality. The arrangement is secured and the plurality of liquid crystal elastomers cured.

First claim

What is claimed is:

1. A method of synthesizing a shape-programmable liquid crystal elastomer, the method comprising:
filling an alignment cell with liquid crystal monomers comprising a mixture of a first mesogenic diacrylate and a second mesogenic diacrylate having a ratio of the first mesogenic diacrylate to the second mesogenic diacrylate suppresses nematic-crystallization phase transition, wherein the liquid crystal monomers align to a surface of the alignment cell; and
polymerizing the liquid crystal monomers with a dithiol chain transfer agent,
wherein the alignment cell is configured to impose a director orientation on a portion of the shape-programmable liquid crystal elastomer.

2. The method of claim 1 , wherein the liquid crystal monomers are mesogenic diacrylates.

3. The method of claim 2 , wherein the mesogenic diacrylate is selected from the group consisting of 1,4-bis[4-(3-acryloyloxybutyloxy)benzoyloxy]-2-methylbenzene, 1,4-bis-[4-(6-acryloyloxyhexyloxy)benzoyloxy]-2-methylbenzene, and 1,4-bis[4-(11-acryloyloxyundecyloxy)-benzoyloxy]-2-methylbenzene.

4. The method of claim 1 , wherein the dithiol chain transfer agent is a C2-C6 alkyl-dithiol.

5. The method of claim 4 , wherein the dithiol chain transfer agent is selected from the group consisting of ethane dithiol, propane dithiol, hexane dithiol, and 1,4-benezenedimethanethiol.

6. The method of claim 1 , wherein an amount of thiol incorporated into the liquid crystal elastomer ranges from about 30% to about 50% by weight.

7. The method of claim 1 , further comprising:
introducing a photoinitiator before filling the alignment cell.

8. The method of claim 7 , wherein the photoinitiator is 2, 2-dimethoxy-2-phenylacetophenone.

9. The method of claim 7 , wherein the photoinitiator and liquid crystal monomers are melted before filling the alignment cell.

10. The method of claim 1 , wherein polymerizing liquid crystal monomers with a dithiol chain transfer agent includes applying ultraviolet light.

11. The method of claim 1 , wherein the filled alignment cell is cooled before the liquid crystal monomers are polymerized.

12. A liquid crystal elastomer laminate comprising:
a plurality of shape-programmable liquid crystal elastomers prepared in accordance with claim 1 , the plurality of shape-programmable liquid crystal elastomers being clamped and heated to form the laminate.

13. The liquid crystal elastomer laminate of claim 12 , wherein the imposed directors of the plurality of shape-programmable liquid crystal elastomers are aligned.

14. The liquid crystal elastomer laminate of claim 12 , wherein a layer of mesogenic diacrylate is placed between adjacent ones of the plurality of shape-programmable liquid crystal elastomers.

15. A method for preparing a liquid crystal elastomer laminate, the method comprising:
arranging a first layer comprising first liquid crystal elastomers on a surface of a second layer comprising second liquid crystal elastomers such that a director orientation of each of the first and second liquid crystal elastomers is in registered alignment, wherein each of the first and second liquid crystal elastomers is prepared in accordance with claim 1 ;
securing the arrangement of the first and second liquid crystal elastomers;
curing the first and second liquid crystal elastomers; and
releasing the cured first and second elastomers.

16. The method of claim 15 , further comprising:
coating at least one of the first and second liquid crystal elastomers with a mesogenic diacrylate before arranging the first and second liquid crystal elastomers.

17. The method of claim 15 , wherein curing the first and second liquid crystal elastomers further comprises:
heating the first and second liquid crystal elastomers; and
applying ultraviolet light to the first and second liquid crystal elastomers.

Assignees

• Us Gov Air Force
• Us Air Force

Inventors

• Godman Nicholas P
• White Timothy J
• Koerner Hilmar
• Kowalski Benjamin A
• Auguste Anesia D
• Guin Tyler C

Classifications

• C09D135/02

  Homopolymers or copolymers of esters (C09D135/06, C09D135/08 take precedence) · CPC title

• C08F222/20 Primary

  Esters containing oxygen in addition to the carboxy oxygen · CPC title

• C08F2/48

  by ultraviolet or visible light · CPC title

• C08F222/102 Primary

  of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate · CPC title

• C08F2810/20

  leading to a crosslinking, either explicitly or inherently · CPC title