Lithium composite oxide sintered body plate

Patent metadata

Field	Value
Publication number	US-11211599-B2
Application number	US-201916531420-A
Country	US
Kind code	B2
Filing date	Aug 5, 2019
Priority date	Feb 13, 2017
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

Provided is a lithium complex oxide sintered plate for use in a positive electrode of a lithium secondary battery. The lithium complex oxide sintered plate has a structure in which a plurality of primary grains having a layered rock-salt structure are bonded, and has a porosity of 3 to 40%, a mean pore diameter of 15 μm or less, an open porosity of 70% or more, and a thickness of 15 to 200 μm. The plurality of primary grains has a primary grain diameter, i.e., a mean diameter of the primary grains, of 20 μm or less and a mean tilt angle of more than 0° to 30° or less. The mean tilt angle is a mean value of the angles defined by the (003) planes of the primary grains and the plate face of the lithium complex oxide sintered plate.

First claim

What is claimed is:

1. A lithium complex oxide sintered plate for use in a positive electrode of a lithium secondary battery, wherein the lithium complex oxide sintered plate includes a first major plate face and a second major plate face that is opposite from and parallel to the first major plate face, a structure in which a plurality of primary grains having a layered rock-salt structure are bonded, and has:
a porosity of 3 to 40%,
a mean pore diameter of 0.1 μm or more and 15 μm or less,
an open pore rate of 70% or more and 95% or less, and
a thickness of 15 to 200 μm,
wherein the primary grains have a primary grain diameter of 0.5 μm or more and 20 μm or less and a mean tilt angle of more than 0° to 30° or less, the primary grain diameter being a mean diameter of the primary grains, the mean tilt angle being a mean value of the angles defined by the (003) planes of the primary grains and one of the first or second major plate faces of the lithium complex oxide sintered plate;
wherein a ratio of individual primary grains having tilt angles of 0° to 30° among all the primary grains is 60% or more, and the tilt angle is defined by the (003) plane of the primary grain and one of the first or second major plate faces of the lithium complex oxide sintered plate; and
wherein the sintered plate does not include a binder.

2. The lithium complex oxide sintered plate according to claim 1 , wherein the ratio of the individual primary grains having tilt angles of 0° to 30° among all the primary grains is 80% or more.

3. The lithium complex oxide sintered plate according to claim 1 , wherein the ratio of the individual primary grains having tilt angles of 0° to 30° among all the plurality of primary grains is 90% or more.

4. The lithium complex oxide sintered plate according to claim 1 , having a thickness of 30 to 150 μm.

5. The lithium complex oxide sintered plate according to claim 1 , having a thickness of 50 to 100 μm.

Assignees

• Ngk Insulators Ltd

Inventors

• Yura Yukinobu
• Okada Shigeki

Classifications

• H01M4/0404

  by coating on electrode collectors · CPC title

• C04B2235/3275

  Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite · CPC title

• C04B35/01

  based on oxide ceramics · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• C04B38/02

  by adding chemical blowing agents · CPC title