Antistatic carbon composite, molded product, and preparation method therefor

Patent metadata

Field	Value
Publication number	US-11198780-B2
Application number	US-201615763674-A
Country	US
Kind code	B2
Filing date	Oct 17, 2016
Priority date	Apr 25, 2016
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

The present invention relates to a carbon composite, which comprises a polymer resin and a carbon material having specific conditions, thereby controlling a dielectric constant. According to the present invention, the carbon composite and a method for controlling a dielectric constant by using the same can be variously applied to a circuit, an electronic material and the like by establishing a correlation between the specific surface area of the carbon material and the dielectric property of the carbon composite.

First claim

What is claimed is:

1. An antistatic carbon composite material, comprising:
a thermoplastic resin;
0.1 to 10 wt % of carbon nanotubes based on the total weight of the thermoplastic resin; and
a conductive filler, wherein the conductive filler is fine graphitized fibers of 3.5 to 500 nm, carbon fibers having a fiber diameter of 3 to 12 μm or carbon particles having a diameter of 1 to 500 μm, and wherein the conductive filler has a difference in percolation threshold value from 10 to 50 wt % with respect to the nanotubtes,
wherein the thermoplastic resin comprises acrylonitrile-butadiene-styrene copolymer and polystyrene, and
wherein a content ratio of the acrylonitrile-butadiene-styrene copolymer to the polystyrene is from 1:9 to 2:8.

2. The antistatic carbon composite material according to claim 1 , wherein the carbon nanotubes have an average particle diameter of 5 nm to 50 nm and an average length of 10 μm to 100 μm.

3. The antistatic carbon composite material according to claim 1 , wherein the content of the carbon nanotubes is 0.5 to 3 wt %.

4. The antistatic carbon composite material according to claim 1 , wherein the carbon nanotubes are in the form of a rigid random coils.

5. The antistatic carbon composite material according to claim 1 , wherein the carbon nanotubes are a single-walled nanotubes, a multi-walled nanotubes, or a combination thereof.

6. The antistatic carbon composite material according to claim 1 , wherein the thermoplastic resin further comprises at least one selected from the group consisting of a polycarbonate resin, a polypropylene resin, a polyamide resin, an aramid resin, an aromatic polyester resin, a polyolefin resin, a polyester carbonate resin, a polyphenylene ether resin, a polyphenylene sulfide resin, a polysulfone resin, a polyether sulfone resin, a polyarylene resin, a cycloolefin resin, a polyetherimide resin, a polyacetal resin, a polyvinyl acetal resin, a polyketone resin, a polyether ketone resin, a polyether ether ketone resin, a polyaryl ketone resin, a polyether nitrile resin, a liquid crystal resin, a polybenzimidazole resin, a polyparabanic acid resin, a vinyl-based polymer or copolymer resin obtained by polymerizing or copolymerizing at least one vinyl monomers selected from the group consisting of an aromatic alkenyl compound, methacrylic acid ester, acrylic acid ester and a vinyl cyanide compound, a diene-aromatic alkenyl compound copolymer resin, a vinyl cyanide-diene-aromatic alkenyl compound copolymer resin, an aromatic alkenyl compound-diene-vinyl cyanide-N-phenyl maleimide copolymer resin, a vinyl cyanide-(ethylene-diene-propylene(EPDM))-aromatic alkenyl compound copolymer resin, a vinyl chloride resin and a chlorinated vinyl chloride resin.

7. The antistatic carbon composite material according to claim 1 , further comprising at least one additive selected from the group consisting of an antimicrobial agent, a releasing agent, a heat stabilizer, an antioxidant, a light stabilizer, a compatibilizer, a dye, an inorganic additive, a surfactant, a nucleating agent, a coupling agent, a filler, a plasticizer, an impact modifier, an admixture, a coloring agent, a stabilizer, a lubricant, an antistatic agent, a pigment, a flame retardant agent, and a mixture of one or more of the foregoing.

8. The antistatic carbon composite material according to claim 1 , wherein the carbon composite material has a percolation threshold of 2 to 60 wt % when the carbon nanotubes are added to the thermoplastic resin.

9. An antistatic molded product obtained by extrusion, injection, or a combination thereof of the antistatic carbon composite material according to claim 1 .

10. The antistatic molded product according to claim 9 , wherein the molded product is a transfer cart for electronic components, a coating material of transfer pipe for electronic components, or a thermoforming tray for electronic components.

11. The antistatic molded product according to claim 9 , wherein the impact strength of the molded product is 7 g·cm/cm or more.

12. The antistatic molded product according to claim 9 , wherein the abrasion resistance of the molded product is 1% or less.

13. A method for manufacturing an antistatic molded product comprising the steps of:
adding thermoplastic resin containing acrylonitrile-butadiene-styrene copolymer and polystyrene to a mixer to form a mixture and melting the mixture;
mixing 0.1 to 10 wt % carbon nanotubes based on the total weight of the thermoplastic resin, and conductive filler into the melted mixture; and
producing an antistatic molded product by extruding, injection, or a combination thereof,
wherein the content ratio of the acrylonitrile-butadiene-styrene copolymer to the polystyrene is from 1:9 to 2:8 wherein the conductive filler is fine graphitized fibers of 3.5 to 500 nm, carbon fibers having a fiber diameter of 3 to 12 urn or carbon particles having a diameter of 1 to 500 urn, and wherein the conductive filler has a difference in percolation threshold value from 10 to 50 wt % with respect to the carbon nanotubes.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Pyeong-Gi
• Kim Seokwon
• Kim Se Hyun
• Kim Tae Hyung
• Choi Suk Jo
• Cho Dong Hyun

Classifications

• B29K2507/04

  Carbon · CPC title

• B29K2995/0006

  Dielectric · CPC title

• C08K2201/001

  Conductive additives · CPC title

• B29C70/025 Primary

  with particular filler · CPC title

• C08K5/0008

  Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59 · CPC title