Composite material having a very low content of carbon-based nanofillers, process for the preparation thereof and uses thereof

Patent metadata

Field	Value
Publication number	US-10125243-B2
Application number	US-201314405069-A
Country	US
Kind code	B2
Filing date	Jun 3, 2013
Priority date	Jun 4, 2012
Publication date	Nov 13, 2018
Grant date	Nov 13, 2018

Abstract

A composite material containing a polymer composition and a very low concentration of carbon nanofillers, in particular carbon nanotubes, having improved mechanical properties. The method for producing said composite material and to the different uses thereof. The use of carbon nanofillers at a concentration of between 0.1 ppm and 99 ppm in order to improve mechanical properties, in particular the tensile properties of a polymer matrix encasing at least one polymer selected from a thermoplastic polymer alone or mixed with an elastomer resin base, while facilitating the shaping thereof into composite parts using any suitable technique, in particular injection, extrusion, compression or molding, and while improving the electrostatic dissipation capability thereof.

First claim

The invention claimed is:

1. Process for the preparation of a composite material comprising a polymeric composition and carbon-based nanofillers selected from the group consisting of carbon nanotubes, carbon nanofibres, graphene, and mixtures thereof,
wherein a content by weight of carbon-based nanofillers is between 1 ppm and 95 ppm,
wherein the polymeric composition comprises a polymer matrix including at least one thermoplastic polymer selected from the group consisting of homo- and copolymers of olefins; acrylic homo- and copolymers and poly(alkyl (meth)acrylate)s; homo- and copolyamides; poly(ethylene terephthalate); poly(butylene terephthalate); polyethers; polystyrene; copolymers of styrene and maleic anhydride; poly(vinyl chloride); fluoropolymers; natural or synthetic rubbers; thermoplastic polyurethanes; polyaryletherketones (PAEKs); polyetherimide; polysulphone; poly(phenylene sulphide); cellulose acetate; poly(vinyl acetate); and mixtures thereof; and optionally, an elastomeric resin base;
wherein the composite is free from polycarbonate; and
wherein the composite material is not electrically conductive, the process comprising the following stages:
a) introducing into and then kneading in a compounding device of a masterbatch concentrated in the carbon-based nanofillers, with the polymeric matrix, in order to obtain a precomposite comprising from 0.25% to 0.50% by mass of carbon-based nanofillers;
b) optionally converting the precomposite in agglomerated solid form;
c) introducing the precomposite into the polymer matrix in order to obtain the composite material.

2. Process for the preparation of a composite material according to claim 1 , wherein stage a) is carried out in at least two successive stages, the first resulting in a precomposite comprising from 2.5% to 10% by mass of carbon-based nanofillers and the second resulting in the precomposite comprising from 0.25% to 3% by mass of carbon-based nanofillers.

3. Process for the preparation of a composite material according to claim 1 , wherein the polymeric matrix of stage a) is identical to the polymer matrix of stage c).

4. Process for the preparation of a composite material according to claim 1 , wherein the introduction of precomposite into the polymer matrix according to stage c) is carried out dry, directly into the machine for forming the composite material.

5. Process for the preparation of a composite material, the process comprising the following stages:
a) introducing into and then kneading in a compounding device of a masterbatch concentrated in carbon-based nanofillers, with a polymeric matrix, in order to obtain a precomposite comprising from 0.25% to 0.50% by mass of carbon-based nanofillers;
b) optionally converting the precomposite in agglomerated solid form;
c) introducing the precomposite into the polymer matrix in order to obtain the composite material,
wherein the carbon-based nanofillers are selected from the group consisting of carbon nanotubes, carbon nanofibres, graphene, and mixtures thereof,
wherein a content by weight of carbon-based nanofillers is between 1 ppm and 95 ppm,
wherein the polymeric composition comprises a polymer matrix including at least one thermoplastic polymer selected from the group consisting of homo- and copolymers of olefins; acrylic homo- and copolymers and poly(alkyl (meth)acrylate)s; homo- and copolyamides; polycarbonates; poly(ethylene terephthalate); poly(butylene terephthalate); polyethers; polystyrene; copolymers of styrene and maleic anhydride; poly(vinyl chloride); fluoropolymers; natural or synthetic rubbers; thermoplastic polyurethanes; polyaryletherketones (PAEKs); polyetherimide; polysulphone; poly(phenylene sulphide); cellulose acetate; poly(vinyl acetate); and mixtures thereof; and optionally, an elastomeric resin base; and
wherein the composite material is not electrically conductive.

6. The process of claim 5 , wherein the thermoplastic polymer is selected from the group consisting of homo- and copolymers of olefins, polycarbonates, and homo- and copolymers of amides.

Assignees

• Arkema France

Inventors

• Korzhenko Alexander
• Delprat Patrick
• Bluteau Catherine
• Tymoshenko Andriy
• Goryachkin Anatolly
• Zakharov Dmitry

Classifications

• B29C48/41

  Intermeshing counter-rotating screws · CPC title

• B29C48/40

  using two or more parallel screws {or at least two parallel non-intermeshing screws}, e.g. twin screw extruders · CPC title

• B29C48/405

  Intermeshing co-rotating screws · CPC title

• C08J2323/12

  Polypropene · CPC title

• Y10T428/1372

  Randomly noninterengaged or randomly contacting fibers, filaments, particles, or flakes · CPC title