Ion exchange membrane and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-11192098-B2
Application number	US-201615760440-A
Country	US
Kind code	B2
Filing date	Sep 19, 2016
Priority date	Sep 15, 2015
Publication date	Dec 7, 2021
Grant date	Dec 7, 2021

Abstract

A method for manufacturing an ion exchange membrane is provided. The method for manufacturing an ion exchange membrane, according to one embodiment of the present invention, comprises the step of electrospinning a support fiber producing solution and an ion exchange fiber producing solution respectively to prepare a laminate in which a support fiber mat consisting of a support fiber and an ion exchange fiber mat consisting of an ion exchange fiber are alternatively laminated. According to the present invention, it is possible to simply control factors, such as the thickness, electroconductivity and mechanical strength of the membrane, and the diameter/ratio of a pore, etc. to be suitable for the use of ion exchange membrane during the manufacturing process, to simplify the manufacturing process. As such, the ion exchange membrane manufactured by the method can be utilized as a universal ion exchange membrane which has a large ion exchange capacity, a small electrical resistance, and a small diffusion coefficient as well as excellent mechanical strength and durability.

First claim

The invention claimed is:

1. A redox flow battery separator, comprising:
at least one ion exchange fiber mat; and
at least one support fiber mat,
wherein the at least one support fiber mat and the at least one ion exchange fiber mat are accumulated such that one of the support fiber mat and the ion exchange fiber mat lies on the other,
wherein the weight ratio of the at least one support fiber mat to the at least one ion exchange fiber mat ranges from 1:0.8 to 1:1.4,
wherein the thickness ratio of a single support fiber mat to a single ion exchange fiber mat ranges from 1:0.2 to 1:0.8, and
wherein the support fiber mat has an average pore diameter of 0.1 μm to 10 μm and the ion exchange fiber mat has an average pore diameter of 0.1 μm to 1 μm.

2. The redox flow battery separator of claim 1 , having:
a degree of dimensional change (%) of 2 to 6 as calculated by Equation 1
degree of dimensional change(%)=( V wet −V dry )×100/ V dry ,

where V wet is the volume of the ion exchange membrane that has been immersed in distilled water for 24 hours, and V dry is the volume of the ion exchange membrane that has been vacuum-dried at 120° C. for 24 hours; and

an energy efficiency (%) of 97 to 105 as calculated by Equation 2:

energy
⁢

⁢
efficiency

=

∫
0
t

⁢

I
d

⁢

V
d

⁢
dt

∫
0
t

⁢

I
c

⁢

V
c

⁢
dt

where I d is discharge current amount, I c is charge current amount, V d is discharge voltage, V C is charge voltage, t is charge time or discharge time.

3. A method for manufacturing a redox flow battery separator, the method comprising:
electrospinning each of a support fiber producing solution and an ion exchange fiber producing solution at least once such that one of an ion exchange fiber mat in which ion exchange fibers are accumulated and a support fiber mat in which support fibers are accumulated lies on the other to obtain the redox flow battery separator,
wherein the weight ratio of the support fiber mat to the ion exchange fiber mat ranges from 1:0.8 to 1:1.4,
wherein the support fiber mat has an average pore diameter of 0.1 μm to 10 μm and the ion exchange fiber mat has an average pore diameter of 0.1 μm to 1 μm, and
wherein the thickness ratio of a single support fiber mat to a single ion exchange fiber mat ranges from 1:0.2 to 1:0.8.

4. The method according to claim 3 , wherein the ion exchange fiber producing solution comprises a first ion exchange fiber producing solution containing a cationic ion exchange fiber producing component and a second ion exchange fiber producing solution containing an anionic ion exchange fiber producing component,
wherein the first and second ion exchange fiber producing solutions are each electrospun to form separate ion exchange fiber mats that are adjacent to each other.

5. The method of claim 3 , wherein the redox flow battery separator has:
a degree of dimensional change (%) of 2 to 6 as calculated by Equation 1
degree of dimensional change(%)=( V wet −V dry )×100/ V dry ,

where V wet is the volume of the ion exchange membrane that has been immersed in distilled water for 24 hours, and V dry is the volume of the ion exchange membrane that has been vacuum-dried at 120° C. for 24 hours; and

an energy efficiency (%) of 97 to 105 as calculated by Equation 2:

energy
⁢

⁢
efficiency

=

∫
0
t

⁢

I
d

⁢

V
d

⁢
dt

∫
0
t

⁢

I
c

⁢

V
c

⁢
dt

where I d is discharge current amount, I c is charge current amount, V d is discharge voltage, V C is charge voltage, t is charge time or discharge time.

Assignees

• Amogreentech Co Ltd

Inventors

• Jeong Ui Young

Classifications

• H01M50/42

  Acrylic resins · CPC title

• H01M50/426

  Fluorocarbon polymers · CPC title

• H01M50/429

  Natural polymers · CPC title

• H01M50/414

  Synthetic resins, e.g. thermoplastics or thermosetting resins · CPC title

• B01D69/106

  Membranes in the pores of a support, e.g. polymerized in the pores or voids · CPC title