Method for infiltrating with precursor solution using moisture control

Patent metadata

Field	Value
Publication number	US-11177482-B2
Application number	US-201816759822-A
Country	US
Kind code	B2
Filing date	Dec 6, 2018
Priority date	Dec 7, 2017
Publication date	Nov 16, 2021
Grant date	Nov 16, 2021

Abstract

Disclosed is a method for infiltrating a porous structure with a precursor solution by means of humidification. The infiltration method with a precursor solution using moisture control comprises the steps of: (S1) providing a substrate having porous structures deposited thereon; (S2) depositing, by electrospraying, a precursor solution on the substrate having porous structures deposited thereon; (S3) humidifying the porous structures having the precursor solution deposited thereon; and (S4) sintering the humidified porous structures.

First claim

What is claimed is:

1. A method for infiltrating with a precursor solution using moisture control, comprising the steps of:
(S1) providing a substrate having porous structures deposited thereon;
(S2) depositing, by electrospraying, a precursor solution on the substrate having porous structures deposited thereon;
(S3) humidifying the porous structures having the precursor solution deposited thereon; and
(S5) sintering the humidified porous structures.

2. The method for infiltrating with a precursor solution using moisture control according to claim 1 , wherein in the depositing step (S2), the precursor solution is electrosprayed on the substrate having the porous structures deposited thereon under a relative humidity of 10%.

3. The method for infiltrating with a precursor solution using moisture control according to claim 1 , wherein in the humidifying step (S3), humidification of the porous structures having the precursor solution deposited thereon is performed under a relative humidity of 70%.

4. The method for infiltrating with a precursor solution using moisture control according to claim 1 , wherein in the humidifying step (S3), the degree of infiltration of the precursor solution into the porous structure is controlled according to the amount of humidification.

5. The method for infiltrating with a precursor solution using moisture control according to claim 1 , wherein the substrate having the porous structures deposited thereon is a ceramic substrate having the porous ceramic structures deposited thereon.

6. The method for infiltrating with a precursor solution using moisture control according to claim 1 , wherein the substrate having the porous structures deposited thereon comprises an anode layer, an electrolyte layer, and a cathode layer of a solid oxide fuel cell.

7. The method for infiltrating with a precursor solution using moisture control according to claim 6 , wherein the porous structure includes a cathode layer.

8. The method for infiltrating with a precursor solution using moisture control according to claim 6 , wherein the precursor solution to be electrosprayed is a solution comprising deionized water as a solvent and any one selected from the group consisting of lanthanum nitrate hexahydrate, strontium nitrate, cobalt nitrate hexahydrate, citric acid, and a combination thereof.

9. The method for infiltrating with a precursor solution using moisture control according to claim 6 , wherein the precursor solution to be electrosprayed is a cathode material comprising any one of selected from the group consisting of Lanthanum Strontium Cobaltite (LSC) sol, Lanthanum Strontium Cobalt Ferrite (LSCF) sol, Samarium Strontium Cobaltite Oxide (SSC) sol, and a combination thereof.

10. The method for infiltrating with a precursor solution using moisture control according to claim 6 , wherein the precursor solution to be electrosprayed is a solution having the same composition as the material of the cathode layer.

11. The method for infiltrating with a precursor solution using moisture control according to claim 6 , wherein the sintering step (S5) is performed at 950° C.

12. The method for infiltrating with a precursor solution using moisture control according to claim 1 , wherein the method further comprises (S4) heating the humidified porous structures, between the humidifying step (S3) and the sintering step (S5).

13. The method for infiltrating with a precursor solution using moisture control according to claim 12 , wherein the substrate having the porous structures deposited thereon comprises an anode layer, an electrolyte layer, and a cathode layer of a solid oxide fuel cell.

14. The method for infiltrating with a precursor solution using moisture control according to claim 13 , wherein the heating step (S4) is performed at 110° C.

15. The method for infiltrating with a precursor solution using moisture control according to claim 13 , wherein the porous structure includes a cathode layer.

16. The method for infiltrating with a precursor solution using moisture control according to claim 13 , wherein the precursor solution to be electrosprayed is a solution comprising deionized water as a solvent and any one selected from the group consisting of lanthanum nitrate hexahydrate, strontium nitrate, cobalt nitrate hexahydrate, citric acid, and a combination thereof.

17. The method for infiltrating with a precursor solution using moisture control according to claim 13 , wherein the precursor solution to be electrosprayed is a cathode material comprising any one of selected from the group consisting of Lanthanum Strontium Cobaltite (LSC) sol, Lanthanum Strontium Cobalt Ferrite (LSCF) sol, Samarium Strontium Cobaltite Oxide (SSC) sol, and a combination thereof.

18. The method for infiltrating with a precursor solution using moisture control according to claim 13 , wherein the precursor solution to be electrosprayed is a solution having the same composition as the material of the cathode layer.

19. The method for infiltrating with a precursor solution using moisture control according to claim 13 , wherein the sintering step (S5) is performed at 950° C.

Assignees

• Global Frontier Ct Multiscale Energy Systems
• Korea Inst Sci & Tech
• Seoul Nat Univ R&Db Foundation
• GlobalFrontier Center ForMultiscale Energy Systems

Inventors

• Choi Man Soo
• Kim Jeong Hun
• Kim Hyoungchul
• Son Ji-Won
• Shin Sung Soo
• Lee Seung Yong

Classifications

• B05D3/0254

  After-treatment · CPC title

• H01M4/8885

  Sintering or firing · CPC title

• H01M4/8846

  Impregnation · CPC title

• H01M4/8842 Primary

  Coating using a catalyst salt precursor in solution followed by evaporation and reduction of the precursor · CPC title

• H01M2004/8689

  Positive electrodes · CPC title