Inorganic particles for nonaqueous electrolyte battery

Patent metadata

Field	Value
Publication number	US-11171386-B2
Application number	US-201716465660-A
Country	US
Kind code	B2
Filing date	Dec 1, 2017
Priority date	Dec 2, 2016
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

The purpose of the present invention is to provide a nonaqueous electrolyte battery having excellent lifespan characteristics and/or excellent safety, which are essential in practice. The basic inorganic particles for a nonaqueous electrolyte battery according to the present invention include basic inorganic particles, wherein a hydrophilicity parameter A for the basic inorganic particles satisfies the expression: 0.45≤A(BET1/BET2)≤2.0. In the expression, BET1 represents the specific surface area of the basic inorganic particles calculated from an adsorption isotherm which is measured through adsorption of water vapor to the basic inorganic particles by a BET method. BET2 represents the specific surface area of the basic inorganic particles calculated from an adsorption isotherm which is measured through adsorption of nitrogen to the basic inorganic particles by a BET method.

First claim

The invention claimed is:

1. Inorganic particles for a nonaqueous electrolyte battery, comprising basic inorganic particles, wherein a hydrophilic parameter A of the basic inorganic particles satisfies 0.45≤A (BET1/BET2)≤2.0, where BET1 is a specific surface area of the basic inorganic particles calculated by an adsorption isotherm measured by adsorbing water vapor to the basic inorganic particles according to a BET method, and BET2 is a specific surface area of the basic inorganic particles calculated by an adsorption isotherm measured by adsorbing nitrogen to the basic inorganic particles according to a BET method.

2. The inorganic particles for a nonaqueous electrolyte battery according to claim 1 , wherein a HF concentration decreases to less than 90% of an initial HF concentration in 5 minutes at 23° C. after adding the basic inorganic particles into 100 parts by weight of a cyclic and/or a linear carbonate solution having the HF concentration of 10 to 10,000 ppm and containing 0.1 to 6.0 mol/L of LiPF 6 such that an amount of the basic inorganic particles is [HF concentration (ppm)]/100 parts by weight.

3. The inorganic particles for a nonaqueous electrolyte battery according to claim 1 , wherein the basic inorganic particles comprise an element of Be, Mg, and/or an element belonging to an alkaline-earth metal.

4. The inorganic particles for a nonaqueous electrolyte battery according to claim 1 , wherein the basic inorganic particles further comprise an element belonging to a transition metal.

5. The inorganic particles for a nonaqueous electrolyte battery according to claim 1 , further comprising non-basic inorganic particles.

6. The inorganic particles for a nonaqueous electrolyte battery according to claim 5 , wherein the non-basic inorganic particles are an anion adsorbent and/or a cation adsorbent.

7. The inorganic particles for a nonaqueous electrolyte battery according to claim 6 , wherein the anion adsorbent is a Mg—Al, Mg—Fe, Ni—Fe, or Li—Al layered double hydroxide, a layered double hydroxide-alumina silica gel complex, boehmite, alumina, zinc oxide, lead oxide, iron oxide, iron oxyhydroxide, hematite, bismuth oxide, tin oxide, titanium oxide, or zirconium oxide, and the cation adsorbent is zirconium phosphate, titanium phosphate, apatite, titanate, niobate, or niobatetitanate.

8. The inorganic particles for a nonaqueous electrolyte battery according to claim 1 , wherein the basic inorganic particles are calcium silicate.

9. The inorganic particles for a nonaqueous electrolyte battery according to claim 8 , wherein the calcium silicate is wollastonite or xonotlite.

10. A nonaqueous electrolyte battery comprising a positive electrode, a negative electrode, a separator, a nonaqueous electrolytic solution, and an outer package, wherein the battery comprises the inorganic particles for a nonaqueous electrolyte battery according to claim 1 in the battery.

11. The nonaqueous electrolyte battery according to claim 10 , wherein an inorganic particle-containing layer containing the inorganic particles for a nonaqueous electrolyte battery is present between the positive electrode and the negative electrode.

12. A separator for a nonaqueous electrolyte battery comprising the inorganic particles for a nonaqueous electrolyte battery according to claim 1 .

13. A separator for a nonaqueous electrolyte battery comprising an inorganic particle-containing layer containing the inorganic particles for a nonaqueous electrolyte battery according to claim 1 .

14. A separator for a nonaqueous electrolyte battery comprising an inorganic particle-containing layer containing the inorganic particles for a nonaqueous electrolyte battery according to claim 1 at least on one side of the separator.

15. The separator for a nonaqueous electrolyte battery according to claim 14 , further comprising an aqueous polymer in the inorganic particle-containing layer.

16. A paint for a nonaqueous electrolyte battery, comprising the inorganic particles for a nonaqueous electrolyte battery according to claim 1 .

17. A resin solid material for a nonaqueous electrolyte battery, comprising the inorganic particles for a nonaqueous electrolyte battery according to claim 1 and a resin.

18. A lithium ion secondary battery comprising a laminated body or a roll of the laminated body, and a nonaqueous electrolyte, wherein a positive electrode, an inorganic particle-containing layer containing the inorganic particles for a nonaqueous electrolyte battery according to claim 1 , a separator, and a negative electrode are laminated in this order.

19. The separator for a nonaqueous electrolyte battery according to claim 12 , wherein a HF concentration decreases to less than 90% of an initial HF concentration in 5 minutes at 23° C. after putting the separator for a nonaqueous electrolyte battery into 100 parts by weight of a cyclic and/or a linear carbonate solution having a HF concentration of 10 to 10,000 ppm and containing 0.1 to 6.0 mol/L of LiPF 6 such that an amount of the basic inorganic particles for a nonaqueous electrolyte solution is [HF concentration (ppm)]/100 parts by weight.

20. The separator for a nonaqueous electrolyte battery according to claim 12 , wherein a HF concentration decreases to less than 90% of an initial HF concentration when 10 ml of a nonaqueous electrolyte solution passed through the separator at a speed of 250,000 ml/h/m 2 , such that an amount of the basic inorganic particles contained in the separator is [HF concentration (ppm)]/100 parts by weight with respect to 100 parts by weight of the nonaqueous electrolyte solution, wherein the nonaqueous electrolyte solution is a cyclic and/or a linear carbonate solution having a HF concentration of 10 to 10,000 ppm and containing 0.1 to 6.0 mol/L of LiPF 6 .

21. The inorganic particles for a nonaqueous electrolyte battery according to claim 5 , wherein the basic inorganic particles are selected from the group consisting of calcium silicate, basic zirconium phosphate, basic apatite, potassium silicotitanate and basic mica.

22. The inorganic particles for a nonaqueous electrolyte battery according to claim 21 , wherein the non-basic inorganic particles comprise alumina or boehmite.

23. The inorganic particles for a nonaqueous electrolyte battery according to claim 1 , wherein the basic inorganic particles further comprise an element selected from the group consisting of Al, Zn, Ga, Cd, In, Sn, Hg, Tl, Pb, and Bi.

Assignees

• Asahi Chemical Ind

Inventors

• Saeki Hiroyuki
• Ito Nobuhiro
• Matsui Kunio

Classifications

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M50/489

  Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties · CPC title

• H01M50/457

  comprising three or more layers · CPC title

• H01M50/451

  comprising layers of only organic material and layers containing inorganic material · CPC title

• H01M50/443

  Particulate material · CPC title