Luminescence based fiber optic probe for the detection of rare earth elements

Patent metadata

Field	Value
Publication number	US-11170986-B2
Application number	US-201715785634-A
Country	US
Kind code	B2
Filing date	Oct 17, 2017
Priority date	Oct 17, 2017
Publication date	Nov 9, 2021
Grant date	Nov 9, 2021

Abstract

The disclosure relates to an apparatus, method and process for detecting rare earth elements. The system includes an LED powered by a first power source and a focusing lens in optical communication with the LED. A shortpass filter is in optical communication with the focusing lens; and a fiber bifurcated cable in optical communication with the shortpass filter. The system includes a probe tip in optical communication with the fiber bifurcated cable and a sample; a first aspheric lens in optical communication with the fiber bifurcated cable. A longpass filter is in optical communication with the first aspheric lens and a second aspheric lens in optical communication with the longpass filter. The system includes a spectrometer connected to a power source, where the spectrometer is in optical communication with the second aspheric lens.

First claim

What is claimed is:

1. An apparatus for detection of rare earth elements comprising:
A light source providing one or more luminescent signals;
a shortpass filter that reduces low energy emissions from the light source, the shortpass filter in optical communication with at least the light source;
a fiber bifurcated cable in optical communication with at least the shortpass filter and a sample, the fiber bifurcated cable providing and receiving one or more luminescent signals;
a probe tip in optical communication with the fiber bifurcated cable and the sample, the probe tip functionalized with a coating that enhances a detection limit for rare earth elements;
a longpass filter in optical communication with the fiber bifurcated cable receiving the one or more luminescent signals; and
a longpass filter is in optical communication with a spectrometer which analyzes the one or more luminescent signals.

2. The apparatus of claim 1 the light source is an LED light source having a wavelength of about 400 nm or shorter.

3. The apparatus of claim 2 wherein the LED light source has a wavelength of about 365 nm and an output between about 1.15 W and about 1.4 W.

4. The apparatus of claim 1 further comprising a focusing lens in optical communication with the light source and the shortpass filter.

5. The apparatus of claim 1 wherein the shortpass filter comprises a shortpass filter that permits at least 95% of the signal intensity from the light source.

6. The apparatus of claim 5 wherein the shortpass filter comprises a 390 nm shortpass filter.

7. The apparatus of claim 1 further comprising a first aspheric lens in optical communication with the fiber bifurcated cable and the longpass filter and a second apheric lens in optical communication with the longpass filter and the spectrometer.

8. The apparatus of claim 1 wherein the longpass filter comprises a 458 nm longpass filter or smaller wavelength eliminating low-energy signals from the light source to near zero.

9. The apparatus of claim 1 further comprising a sensitizer added to a solution phase to enhance a detection limit of rare earth elements.

10. An apparatus for detection of rare earth elements comprising:
an LED light source connected to a power source providing UV light;
a shortpass filter in optical communication with the LED light source, the shortpass filter reducing low energy emissions from the LED light source;
a fiber bifurcated cable in optical communication with the shortpass filter;
a probe tip in optical communication with the fiber bifurcated cable and a sample, where the probe tip is functionalized with a coating that enhances the detection limit for rare earth elements which could be comprised of an immobilized sensitizer in a silica-based sol-gel, a sorbent materials for rare earth ions, plasmonic nanoparticles, or another type of functional layer;
a first aspheric lens in optical communication with at least the fiber bifurcated cable;
a longpass filter in optical communication with the first aspheric lens;
a second aspheric lens in optical communication with the longpass filter; and
a second aspheric lens in optical communication with a spectrometer which analyzes the one or more luminescent signals.

11. The apparatus of claim 10 wherein the LED light source has a wavelength of about 365 nm and an output between about 1.15 W and about 1.4 W.

12. The apparatus of claim 10 further comprising a focusing lens in optical communication with the light source and the shortpass filter.

13. The apparatus of claim 10 wherein the shortpass filter comprises a shortpass filter that permits at least 95% of the signal intensity from the light source.

14. The apparatus of claim 13 wherein the shortpass filter comprises a 390 nm shortpass filter.

15. The apparatus of claim 10 wherein the longpass filter comprises a 458 nm longpass filter or smaller wavelength eliminating low-energy signals from the light source to near zero.

16. The apparatus of claim 10 further comprising a sensitizer added to a solution phase to enhance a detection limit of rare earth elements.

17. An apparatus for detection of rare earth elements comprising:
a light source providing one or more luminescent signals;
a shortpass filter that reduces low energy emissions from the light source, the shortpass filter in optical communication with at least the light source;
a fiber bifurcated cable in optical communication with at least the shortpass filter and a sample, the fiber bifurcated cable providing and receiving one or more luminescent signals;
a probe tip in optical communication with the fiber bifurcated cable and the sample, the probe tip functionalized with a coating that enhances a detection limit for rare earth elements, wherein the coating is selected from the group comprising an immobilized sensitizer, a silica-based sol-gel, a sorbent material for rare earth ions, plasmonic nanoparticles, or another type of functional layer;
a longpass filter in optical communication with the fiber bifurcated cable receiving the one or more luminescent signals; and
a longpass filter is in optical communication with a spectrometer which analyzes the one or more luminescent signals.

18. The apparatus of claim 17 wherein the light source is an LED light source having a wavelength of about 365 nm and an output between about 1.15 W and about 1.4 W.

19. The apparatus of claim 18 further comprising a focusing lens in optical communication with the light source and the shortpass filter.

20. The apparatus of claim 17 wherein the shortpass filter comprises a 390 nm shortpass filter.

Assignees

• Us Energy
• Us Dept Energy

Inventors

• Ahern John C
• Ohodnicki Jr Paul R
• Baltrus John P
• Poole Jacob Lorenzi

Classifications

• G01J3/4406

  Fluorescence spectrometry · CPC title

• G01N2021/8528

  Immerged light conductor · CPC title

• G01N21/6428

  Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" (in vivo A61B5/00; immunoassay G01N33/53) · CPC title

• G01N2021/6484

  Optical fibres · CPC title

• G01N2201/062

  LED's · CPC title