Resin composition, prepreg, metal foil-clad laminate, resin sheet, and printed wiring board

Patent metadata

Field	Value
Publication number	US-11166370-B2
Application number	US-201816480088-A
Country	US
Kind code	B2
Filing date	Jan 19, 2018
Priority date	Jan 26, 2017
Publication date	Nov 2, 2021
Grant date	Nov 2, 2021

Abstract

A resin composition according to the present invention contains: (i) a reactant of a cyanate compound (A) and polybutadiene (B) and/or (ii) a reactant of a polymerized product of the cyanate compound (A) and the polybutadiene (B); and a maleimide compound (C).

First claim

The invention claimed is:

1. A resin composition comprising:
(i) a reactant of a cyanate compound (A) and a polybutadiene (B) and/or (ii) a reactant of a polymerized product of the cyanate compound (A) and the polybutadiene (B); and
a maleimide compound (C),
wherein the maleimide compound (C) comprises at least one selected from a group consisting of 2,2′-bis{4-(4-maleimidophenoxy)-phenyl}propane, bis(3-ethyl-5-methyl-4-maleimidophenyl)methane, a maleimide compound (C1) represented by the following formula (1-1), and a maleimide compound (C2) represented by the following formula (1-2),

wherein R 5 each independently represents a hydrogen atom or a methyl group, and n 1 represents an integer of 1 or more,

wherein a plurality of R each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, or a phenyl group, and n is an average value and satisfies 1<n≤5, and
wherein the polybutadiene (B) is an unmodified polybutadiene, and wherein the polybutadiene (B) comprises a 1,2-adduct and a 1,4-adduct at a mass ratio of 1:3 to 3:1.

2. The resin composition according to claim 1 , wherein the cyanate compound (A) comprises at least one cyanate compound (A1) selected from a group consisting of a bisphenol A-based cyanate compound, a bisphenol E-based cyanate compound, a bisphenol F-based cyanate compound, and a novolac-based cyanate compound.

3. The resin composition according to claim 2 , wherein the cyanate compound (A) further comprises a cyanate compound (A2) other than the cyanate compound (A1).

4. The resin composition according to claim 2 , wherein an amount of the polybutadiene (B) is 5 to 30 parts by mass based on 100 parts by mass of the cyanate compound (A1).

5. The resin composition according to claim 1 , wherein the polybutadiene (B) comprises a 1,2-adduct and a 1,4-adduct at a mass ratio of 1:1 to 3:1.

6. The resin composition according to claim 1 , wherein a content of the cyanate compound (A) in the resin composition is 1 to 90 parts by mass based on 100 parts by mass of resin solid components.

7. The resin composition according to claim 1 , wherein the maleimide compound (C) contains at least one selected from a group consisting of bis(3-ethyl-5-methyl-4-maleimidophenyl)methane, a maleimide compound (C1) represented by the following formula (1-1), and a maleimide compound (C2) represented by the following formula (1-2),

wherein R 5 each independently represents a hydrogen atom or a methyl group, and n 1 represents an integer of 1 or more,

wherein a plurality of R each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, or a phenyl group, and n is an average value and satisfies 1<n≤5.

8. The resin composition according to claim 1 , further comprising a filler (D).

9. The resin composition according to claim 8 , wherein a content of the filler (D) in the resin composition is 50 to 1600 parts by mass based on 100 parts by mass of the resin solid components.

10. The resin composition according to claim 1 , further comprising any one or more of a group selected from an epoxy resin, a phenolic resin, an oxetane resin, a benzoxazine compound, and a compound having a polymerizable unsaturated group.

11. A prepreg comprising:
a base material; and
the resin composition according to claim 1 , with which the base material is impregnated or coated.

12. A metal foil-clad laminate comprising:
at least one or more of the prepregs according to claim 11 laminated; and
a metal foil disposed on one surface or both surfaces of the prepreg.

13. A resin sheet comprising the resin composition according to claim 1 .

14. A printed wiring board comprising:
an insulating layer; and
a conductor layer formed on a surface of the insulating layer, wherein the insulating layer comprises the resin composition according to claim 1 .

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Koga Shota
• Takano Kentaro

Classifications

• C08J5/249

  characterised by the additives used in the prepolymer mixture · CPC title

• C08J5/244 Primary

  using glass fibres · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08L61/14

  Modified phenol-aldehyde condensates · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title