Cathode, lithium-air battery including cathode and method of manufacturing lithium-air battery

Patent metadata

Field	Value
Publication number	US-11158865-B2
Application number	US-201916729917-A
Country	US
Kind code	B2
Filing date	Dec 30, 2019
Priority date	Jan 2, 2019
Publication date	Oct 26, 2021
Grant date	Oct 26, 2021

Abstract

A cathode configured to use oxygen as a cathode active material comprising a conductive layer including an electronic conductor, wherein the conductive layer is free of pores.

First claim

What is claimed is:

1. A cathode configured to use oxygen as a cathode active material, the cathode comprising:
a conductive layer comprising an electronic conductor, wherein the conductive layer is free of pores, and wherein the electronic conductor has a lithium ion conductivity; and
a solid electrolyte directly on the conductive layer.

2. The cathode of claim 1 , wherein the electronic conductor has an electronic conductivity of about 1.0×10 −4 S/cm or greater.

3. The cathode of claim 1 , wherein the electronic conductor has an ionic conductivity of about 1.0×10 −4 S/cm or greater.

4. The cathode of claim 1 , wherein the electronic conductor comprises a metal, a metal oxide, and a mixture thereof.

5. The cathode of claim 1 , wherein the electronic conductor comprises at least one of Ni, Pd, Pb, Fe, Ir, Co, Rh, Mn, Cr, Ru, Re, Sn, V, Ge, W, Zr, Ti, Mo, Hf, U, Nb, Th, Ta, Bi, Na, K, Rb, Cs, Ca, Sr, Ba, Y, La, Ce, Pr, Nd, Pm, Sm, Gd, Tb, Dy, Ho, Er, Mg, Al, Si, Sc, Zn, Ga, Rb, Ag, Cd, In, Sb, Pt, Au, or Pb, and oxides thereof.

6. The cathode of claim 4 , wherein the electronic conductor further comprises lithium.

7. The cathode of claim 1 , wherein the conductive layer has a thickness of about 3 nm to about 100 nm.

8. The cathode of claim 1 , further comprising at least one of Li 2 O 2 , LiOH, Li 2 CO 3 , or Li 2 O on a surface of the conductive layer.

9. A lithium-air battery comprising:
an anode comprising lithium or a lithium alloy;
a solid electrolyte on the anode; and
a cathode on the solid electrolyte, the cathode configured to use oxygen as a cathode active material, the cathode comprising
a conductive layer comprising an electronic conductor, wherein the conductive layer is free of pores, and wherein the electronic conductor has lithium ion conductivity; and

a solid electrolyte directly on the conductive layer.

10. The lithium-air battery of claim 9 , wherein the electronic conductor is disposed on an entire surface of the solid electrolyte.

11. The lithium-air battery of claim 9 , further comprising a discharge product on a surface of the cathode, wherein the discharge product comprises at least one of Li 2 O 2 , LiOH, Li 2 CO 3 , or Li 2 O.

12. The lithium-air battery of claim 11 , wherein an area of the surface of the cathode on which the discharge product is disposed is about 90 percent to 100 percent of a total surface area of the cathode.

13. The lithium-air battery of claim 9 , wherein, after discharging and charging the lithium-air battery, a discharge product is not present on a surface of the cathode.

14. The lithium-air battery of claim 13 , wherein the discharge product comprises at least one of a lithium oxide, a lithium peroxide, a lithium hydroxide, or a lithium carbonate.

15. The lithium-air battery of claim 13 , wherein the discharge product is at least one of Li 2 O 2 , LiOH, Li 2 CO 3 , or Li 2 O.

16. The lithium-air battery of claim 9 , wherein an amount of the conductive layer is about 1 part by weight to about 100 parts by weight, with respect to 100 parts by weight of a total weight of the cathode.

17. The lithium-air battery of claim 9 , wherein the solid electrolyte comprises at least one of a lithium-ion conducting glass, a crystalline lithium-ion conducting ceramic, or a crystalline lithium-ion conducting glass-ceramic.

18. The lithium-air battery of claim 9 , wherein the solid electrolyte comprises at least one of a lithium-aluminum-germanium-phosphate, a lithium-aluminum-titanium-phosphate, or a lithium-aluminum-titanium-silicon-phosphate.

19. A method of manufacturing a lithium-air battery, the method comprising:
disposing a solid electrolyte layer on an anode comprising lithium or a lithium alloy; and
coating an electronic conductor directly on a surface of the solid electrolyte layer opposite the anode to form a conductive layer free of pores to form a cathode configured to use oxygen as a cathode active material to manufacture the lithium-air battery,
wherein the electronic conductor has a lithium ion conductivity; and
the solid electrolyte is on the conductive layer.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Kim Hyunjin
• Choi Wonsung
• Kim Mokwon
• Kim Seongheon
• Im Dongmin
• Choi Kyounghwan

Classifications

• H01M2300/0065

  Solid electrolytes · CPC title

• H01M10/0562

  Solid materials · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/405

  Alloys based on lithium · CPC title

• H01M2300/0068

  inorganic · CPC title