Metallization pattern on solid electrolyte or porous support of sodium battery process

Patent metadata

Field	Value
Publication number	US-9356314-B2
Application number	US-201313776262-A
Country	US
Kind code	B2
Filing date	Feb 25, 2013
Priority date	Feb 25, 2013
Publication date	May 31, 2016
Grant date	May 31, 2016

Abstract

A new battery configuration and process are detailed. The battery cell includes a solid electrolyte configured with an engineered metallization layer that distributes sodium across the surface of the electrolyte extending the active area of the cathode in contact with the anode during operation. The metallization layer enhances performance, efficiency, and capacity of sodium batteries at intermediate temperatures at or below about 200° C.

First claim

What is claimed is:

1. A solid electrolyte, comprising:
a metallization layer comprising a densified metal selected from the group consisting of: platinum (Pt); gold (Au); silver (Ag), nickel (Ni), copper (Cu), molybdenum (Mo), tin (Sn), lead (Pb), alloys thereof, and combinations thereof of a selected thickness bonded to the anode side of the solid electrolyte with a plurality of circular or rectangular features of a selected size distributed in the form of a grid in a plane defined across the surface of the solid electrolyte that defines a metallization pattern, the features accumulate sodium metal in operation forming distinct metal islands that expand the area of the anode in active ionic contact with the cathode compared to the solid electrolyte absent the metallization layer.

2. The solid electrolyte of claim 1 , wherein the solid electrolyte comprises beta double prime alumina, a sodium ion conductive ceramic, a super-ionic conductor, Na 3 Zr 2 Si 2 PO 12 , and combinations thereof.

3. The solid electrolyte of claim 1 , wherein the metallization pattern comprises a metal or a metal alloy having a reduction potential greater than sodium.

4. The solid electrolyte of claim 1 , wherein the metallization pattern includes a thickness below about 100 microns.

5. The solid electrolyte of claim 1 , wherein the distribution of features in the metallization pattern is homogeneous.

6. The solid electrolyte of claim 1 , wherein the distribution of features in the metallization pattern is non-homogeneous.

7. The solid electrolyte of claim 1 , wherein the features in the metallization pattern include a size less than or equal to about 1 millimeter to about 20 microns.

8. A sodium battery, comprising:
a solid electrolyte with a metallization layer comprising a densified metal selected from the group consisting of: platinum (Pt); gold (Au); silver (Ag), nickel (Ni), copper (Cu), molybdenum (Mo), tin (Sn), lead (Pb), alloys thereof, and combinations thereof bonded to the anode side thereof with a plurality of circular or rectangular features of a selected size distributed in the form of a grid in a plane defined across the surface that defines a metallization pattern therein, the features accumulate sodium metal in operation at temperatures selected at or below about 200° C. that form distinct metal islands that expand the area of the anode in active ionic contact with the cathode compared to the solid electrolyte absent the metallization layer.

9. The battery of claim 8 , wherein the solid electrolyte comprises beta double prime alumina, a sodium ion conductive ceramic, a super-ionic conductor, Na 3 Zr 2 Si 2 PO 12 , and combinations thereof.

10. The battery of claim 8 , wherein the metallization pattern comprises a metal or a metal alloy with a reduction potential greater than sodium.

11. The battery of claim 8 , wherein the metallization pattern includes a thickness below about 100 microns.

12. The battery of claim 8 , wherein the distribution of features in the metallization pattern is homogeneous.

13. The battery of claim 8 , wherein the distribution of features in the metallization pattern is non-homogeneous.

14. The battery of claim 8 , wherein the features in the metallization pattern include a size less than or equal to about 1 millimeter to about 20 microns.

Assignees

• Kim Jin Yong
• Li Guosheng
• Lu Xiaochuan
• Sprenkle Vincent L
• Lemmon John P
• Battelle Memorial Institute

Inventors

• Kim Jin Yong
• Li Guosheng
• Lu Xiaochuan
• Sprenkle Vincent L
• Lemmon John P

Classifications

• H01M10/3936

  Electrolyte with a shape other than plane or cylindrical · CPC title

• H01M2300/0094

  in the form of layered products, e.g. coatings · CPC title

• H01M10/0562 Primary

  Solid materials · CPC title

• H01M6/20

  working at high temperature (deferred-action thermal cells H01M6/36) · CPC title

• H01M10/3927 Primary

  Several layers of electrolyte or coatings containing electrolyte · CPC title