Nanocomposite and method of producing same
US-2017321018-A1 · Nov 9, 2017 · US
US11158340B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11158340-B2 |
| Application number | US-201916546161-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 20, 2019 |
| Priority date | Aug 20, 2019 |
| Publication date | Oct 26, 2021 |
| Grant date | Oct 26, 2021 |
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In one general approach, a product includes an underlayer of a magnetic recording medium. The underlayer has encapsulated nanoparticles each comprising a magnetic nanoparticle encapsulated by an aromatic polymer, and a polymeric binder binding the encapsulated nanoparticles. A magnetic recording layer is formed above the underlayer. In another general approach, a product includes an electrically conductive underlayer of a magnetic recording medium. The underlayer has encapsulated nanoparticles each comprising a magnetic nanoparticle encapsulated by an aromatic polymer, and a polymeric binder binding the encapsulated nanoparticles. A magnetic recording layer is formed above the underlayer. The magnetic nanoparticles have an average magnetic field strength of less than 200 Oersted (Oe). An average concentration of the encapsulated nanoparticles in the underlayer is at least 35 vol %.
Opening claim text (preview).
What is claimed is: 1. A product, comprising: an underlayer of a magnetic recording medium, the underlayer having: encapsulated nanoparticles each comprising a magnetic nanoparticle encapsulated by an aromatic polymer, and a polymeric binder binding the encapsulated nanoparticles; and a magnetic recording layer formed above the underlayer. 2. The product as recited in claim 1 , wherein the magnetic nanoparticles have an average magnetic field strength of less than 200 Oersted (Oe). 3. The product as recited in claim 1 , wherein an average concentration of the encapsulated nanoparticles in the underlayer is at least 35 vol %. 4. The product as recited in claim 1 , wherein the underlayer is characterized as having an onset glass transition temperature of at least 35° centigrade in a tensile storage modulus (E′) vs. temperature plot. 5. The product as recited in claim 1 , wherein the underlayer is electrically conductive for assisting in dissipating a charge in the product, wherein the aromatic polymer includes a carbamate, wherein an average concentration of the encapsulated nanoparticles in the underlayer is at least 35 vol %, wherein no wear particles are present in the product. 6. The product as recited in claim 1 , wherein the magnetic nanoparticles include chromium oxide. 7. The product as recited in claim 1 , wherein an average diameter of the magnetic nanoparticles is in a range of 2 nanometers to 15 nanometers. 8. The product as recited in claim 1 , wherein the aromatic polymer includes a carbamate. 9. A product, comprising: an underlayer of a magnetic recording medium, the underlayer having: encapsulated nanoparticles each comprising a magnetic nanoparticle encapsulated by an aromatic polymer, and a polymeric binder binding the encapsulated nanoparticles; and a magnetic recording layer formed above the underlayer, wherein the aromatic polymer includes methylene bis diphenyl carbamate. 10. The product as recited in claim 1 , wherein an average thickness of the aromatic polymer is in a range of 1 nanometer to 8 nanometers. 11. The product as recited in claim 1 , wherein the polymeric binder includes an acrylic polymer. 12. The product as recited in claim 1 , wherein an average thickness of the underlayer is less than 1 micron. 13. The product as recited in claim 1 , wherein no wear particles are present in the underlayer. 14. The product as recited in claim 1 , wherein no wear particles are present in the product. 15. The product as recited in claim 1 , wherein the recording layer is substantially not physically intermixed with the underlayer in the product such that an upper surface of the underlayer is substantially flat, with a modulation of less than about 25% of a thickness of an interfacial boundary between the underlayer and the recording layer. 16. The product as recited in claim 1 , wherein the magnetic recording medium is a magnetic recording tape. 17. A product, comprising: an electrically conductive underlayer of a magnetic recording medium, the underlayer having: encapsulated nanoparticles each comprising a magnetic nanoparticle encapsulated by an aromatic polymer, and a polymeric binder binding the encapsulated nanoparticles; and a magnetic recording layer formed above the underlayer, wherein the magnetic nanoparticles have an average magnetic field strength of less than 200 Oersted (Oe), wherein an average concentration of the encapsulated nanoparticles in the underlayer is at least 35 vol %. 18. The product as recited in claim 17 , wherein the underlayer is characterized as having an onset glass transition temperature of at least 35° centigrade in a tensile storage modulus (E′) vs. temperature plot. 19. The product as recited in claim 17 , wherein the magnetic nanoparticles include chromium oxide. 20. The product as recited in claim 17 , wherein an average diameter of the magnetic nanoparticles is in a range of 2 nanometers to 15 nanometers. 21. The product as recited in claim 17 , wherein the aromatic polymer includes a carbamate. 22. The product as recited in claim 17 , wherein an average thickness of the aromatic polymer is in a range of 1 nanometer to 8 nanometers. 23. The product as recited in claim 17 , wherein the polymeric binder includes an acrylic polymer. 24. The product as recited in claim 17 , wherein no wear particles are present in the product. 25. The product as recited in claim 17 , wherein the aromatic polymer includes methylene bis diphenyl carbamate.
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