Hybrid-guided block copolymer assembly
US-2015356989-A1 · Dec 10, 2015 · US
US2017194026A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2017194026-A1 |
| Application number | US-201615060871-A |
| Country | US |
| Kind code | A1 |
| Filing date | Mar 4, 2016 |
| Priority date | Jan 4, 2016 |
| Publication date | Jul 6, 2017 |
| Grant date | — |
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According to one embodiment, a perpendicular magnetic recording medium includes a substrate, an underlayer including projections arranged at an average interval of 3 to 20 nm, an amorphous magnetic recording layer having a plurality of columnar magnetic grains on the surface of the projections, each having a magnetization easy axis in a direction perpendicular to a surface of the underlayer. The underlayer is formed such that 0.5d≦r≦1.5d, where r is the radius of curvature of a vertical section of each projection and d is the average interval between the projections.
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What is claimed is: 1 . A perpendicular magnetic recording medium comprising: a substrate; an underlayer including a plurality of projections arranged on the substrate at an average interval of 3 to 20 nm; and an amorphous magnetic recording layer having a plurality of magnetic grains formed as a column on the surface of the projections, the magnetic grains each having a magnetization easy axis in a direction perpendicular to a surface of the underlayer, wherein the projections are represented by the following formula (1) 0.5≦ r≦ 1.5 d (1) where r is the radius of curvature of a vertical section of each projection and d is the average interval between the projections. 2 . The perpendicular magnetic recording medium of claim 1 , wherein the underlayer has a multilayered structure of a first underlayer including projections and a second underlayer including projections formed on the first underlayer. 3 . The perpendicular magnetic recording medium of claim 2 , wherein the second underlayer is amorphous. 4 . The perpendicular magnetic recording medium of claim 2 , wherein the second underlayer is an anti-oxidation layer. 5 . The perpendicular magnetic recording medium of claim 4 , wherein the anti-oxidation layer includes at least one element selected from a group consisting of titanium, tantalum, hafnium, niobium, and zirconium, and at least one element selected from a group consisting of chrome, iron, nickel, copper, molybdenum, rhodium, palladium, and iridium. 6 . The perpendicular magnetic recording medium of claim 4 , wherein the anti-oxidation layer has a thickness of 1 to 30 nm. 7 . The perpendicular magnetic recording medium of claim 1 , wherein the amorphous magnetic recording layer contains a rare-earth element-transition metal alloy. 8 . The perpendicular magnetic recording medium of claim 7 , wherein the rare-earth element-transition metal alloy contains any of samarium, gadolinium, terbium, and dysprosium as a rare-earth element. 9 . The magnetic recording medium of claim 7 , wherein the rare-earth element-transition metal alloy contains one of iron and cobalt as a transition metal. 10 . The perpendicular magnetic recording medium of claim 7 , wherein the rare-earth element-transition metal alloy contains a terbium-cobalt alloy. 11 . The perpendicular magnetic recording medium of claim 1 , wherein the amorphous magnetic recording layer contains an additive which is any one of platinum, gold, silver, indium, chrome, titanium, silicon, aluminum, and boron. 12 . The perpendicular magnetic recording medium of claim 11 , wherein an amount of the additive is 30% or less of an entire composition of the amorphous magnetic recording layer. 13 . The perpendicular magnetic recording medium of claim 1 , wherein the amorphous recording layer has a thickness of 3 to 30 nm. 14 . The perpendicular magnetic recording medium of claim 1 , further comprising a nonmagnetic protective layer, wherein the nonmagnetic protective layer protects a part or the entirety of sidewalls of the amorphous magnetic recording layer. 15 . The perpendicular magnetic recording medium of claim 14 , wherein the nonmagnetic protective layer includes one to five layers therein. 16 . The perpendicular magnetic recording medium of claim 14 , wherein the nonmagnetic protective layer has a thickness of 0.5 to 3 nm. 17 . The perpendicular magnetic recording medium of claim 14 , wherein a total thickness of the nonmagnetic protective layer is one third or less of a total thickness of the amorphous magnetic recording layer. 18 . The perpendicular magnetic recording medium of claim 14 , wherein the nonmagnetic protective layer is formed of any of or an alloy of Pt, Pd, Au, Cu, Cr, and Al. 19 . The perpendicular magnetic recording medium of claim 1 , wherein, in the proximity of a crossing point representing the coercivity, the gradient α of the magnetization curve of the amorphous magnetic recording layer is less than five, the gradient being given by the following formula (2) α=4π dM/dH|H=Hc (2) where M is the magnetization, H is the magnetic field, and Hc is the coercivity. 20 . A manufacturing method of a perpendicular magnetic recording medium, the method comprising: forming, on a substrate, an underlayer including projections; and depositing an amorphous magnetic recording layer on surfaces of the projection, wherein the forming the underlayer including projections comprises: forming a first underlayer on the substrate; applying a nanoparticle dispersion fluid on the first underlayer to form a nanoparticle monolayer; and etching the first underlayer through the nanopartcles, and wherein the projections included in the underlayer are represented by the following formula (1) 0.5 d≦r≦ 1.5 d (1) where r is the radius of curvature of a vertical section of each projection and d is the average interval between the projections. 21 . The manufacturing method of claim 20 , further comprising: forming a second underlayer including projections in advance to the deposition of the amorphous magnetic recording layer; and forming a multilayered underlayer including the first underlayer and the second underlayer, wherein the projections included in the multilayered underlayer are represented by the following formula (1) 0.5 d≦r≦ 1.5 d (1) where r is the radius of curvature of a vertical section of each projection and d is the average interval between the projections. 22 . The manufacturing method of claim 21 , wherein the second underlayer is amorphous. 23 . The manufacturing method of claim 21 , wherein the second underlayer is an anti-oxidation layer. 24 . The manufacturing method of claim 23 , wherein the anti-oxidation layer includes at least one element selected from a group consisting of titanium, tantalum, hafnium, niobium, and zirconium, and at least one element selected from a group consisting of chrome, iron, nickel, copper, molybdenum, rhodium, palladium, and iridium. 25 . The manufacturing method of claim 23 , wherein the anti-oxidation layer has a thickness of 1 to 30 nm. 26 . The manufacturing method of claim 20 , wherein the amorphous magnetic recording layer contains a rare-earth element-transition metal alloy. 27 . The manufacturing method of claim 26 , wherein the rare-earth element-transition metal alloy contains any of samarium, gadolinium, terbium, and dysprosium as a rare-earth element. 28 . The manufacturing method of claim 26 , wherein the rare-earth element-transition metal alloy contains one of iron and cobalt as a transition metal. 29 . The manufacturing method of claim 26 , wherein the rare-earth element-transition metal alloy contains a terbium-cobalt alloy. 30 . The manufacturing method of claim 20 , wherein the amorphous magnetic recording layer contains an additive which is any one of platinum, gold, silver, indium, chrome, titanium, silicon, aluminum, and boron. 31 . The manufacturing method of claim 30 , wherein an amount of the additive is 30% or less of an entire composition of the amorphous magnetic recording layer. 32 . The manufacturing method of claim 20 , wherein the amorphous recording layer has a thickness of 3 to 30 nm. 33 . The manufacturing method of
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