Resonant gas sensor

Patent metadata

Field	Value
Publication number	US-11137368-B2
Application number	US-202016887293-A
Country	US
Kind code	B2
Filing date	May 29, 2020
Priority date	Jan 4, 2018
Publication date	Oct 5, 2021
Grant date	Oct 5, 2021

Abstract

This disclosure provides a sensor for detecting an analyte. The sensor can include an antenna and sensing material both disposed on a substrate, where the sensing is electrically coupled to the antenna. The sensing material can include a carbon structure including a multi-modal distribution of pore sizes that define a surface area including bonding sites configured to interact with one or more additives and the analyte. The carbon structure is configured to generate a resonant signal indicative of one or more characteristics of the analyte in response to an electromagnetic signal. The carbon structure can include distinctly sized interconnected channels defined by the surface area and configured to be infiltrated by the analyte, and exposed surfaces configured to adsorb the analyte. Each of the interconnected channels can include microporous pathways and/or mesoporous pathways, which can increase a responsiveness of the sensing material proportionate to the analyte within the carbon structure.

First claim

What is claimed is:

1. A sensor configured to detect an analyte, comprising:
an antenna disposed on a substrate;
a sensing material disposed on the substrate and electrically coupled to the antenna, the sensing material comprising:
a carbon structure including a multi-modal distribution of pore sizes that define a surface area including bonding sites configured to interact with one or more additives and the analyte, the carbon structure configured to generate a resonant signal indicative of one or more characteristics of the analyte in response to an electromagnetic signal, the carbon structure comprising:
a plurality of distinctly sized interconnected channels defined by the surface area and configured to be infiltrated by the analyte; and
a plurality of exposed surfaces configured to adsorb the analyte.

2. The sensor of claim 1 , wherein each of the one or more distinctly sized interconnected channels includes at least one of microporous pathways or mesoporous pathways.

3. The sensor of claim 2 , wherein each of the microporous pathways or mesoporous pathways is configured to increase a responsiveness of the sensing material proportionate to an amount of the analyte within the carbon structure.

4. The sensor of claim 1 , wherein the sensing material is integrated into the antenna or positioned within a vicinity of the antenna.

5. The sensor of claim 1 , wherein one or more characteristics of the resonant signal are indicative of a presence of one or more known harmful substances in the sensing material.

6. The sensor of claim 5 , wherein the indication is based on a comparison of the one or more characteristics of the resonant signal with one or more characteristics of the known harmful substances.

7. The sensor of claim 1 , wherein the sensing material is configured to oscillate at:
a first amplitude at one or more resonant frequencies of the sensing material; and
a second amplitude at one or more non-resonant frequencies of the sensing material, wherein the first amplitude is greater in magnitude than the second amplitude.

8. The sensor of claim 1 , further comprising a pair of electrodes electrically coupled to a dielectric and the sensing material.

9. The sensor of claim 8 , wherein the sensing material and the dielectric are positioned between the pair of electrodes and comprise a tank circuit.

10. The sensor of claim 1 , wherein the carbon structure is at least partially bound by a polymer.

11. The sensor of claim 10 , wherein the polymer comprises one or more polymer additives configured to alter electrical properties of the sensing material by interacting with the analyte.

12. The sensor of claim 1 , wherein the carbon structure includes one or more tuned materials configured to increase a resonance sensitivity of the sensing material across one or more frequency ranges.

13. The sensor of claim 1 , wherein the carbon structure further comprises a plurality of three-dimensionally (3D) structured aggregates, each aggregate of the plurality of 3D structured aggregates including a plurality of nanoparticles.

14. The sensor of claim 13 , wherein the 3D structured agglomerates are configured to generate an impedance response indicative of one or more characteristics of the sensing material based on an excitation signal.

15. The sensor of claim 1 , wherein the sensing material is configured to generate one or more resonant signals indicative of a type of the analyte based on an electromagnetic signal.

16. A sensor system configured to detect an analyte, comprising:
a substrate; and
a resonant circuit configured to be removed without requiring replacement of the substrate, the resonant circuit disposed on the substrate and comprising:
an antenna disposed on the substrate;
a sensing material disposed on the substrate and electrically coupled to the antenna, the sensing material comprising:
a carbon structure including a multi-modal distribution of pore sizes that define a surface area including bonding sites configured to interact with one or more additives and the analyte, the carbon structure configured to generate a resonant signal indicative of one or more characteristics of the analyte in response to an electromagnetic signal, the carbon structure comprising:
a plurality of distinctly sized interconnected channels defined by the surface area and configured to be infiltrated by the analyte; and
a plurality of exposed surfaces configured to adsorb the analyte.

17. The sensor system of claim 16 , wherein the analyte is configured to be at least partially contained within a package.

18. The sensor system of claim 16 , wherein the resonant circuit is attached to the antenna by compression.

19. The sensor system of claim 16 , wherein degradation of a removable top layer of the sensing material is indicative of a need for replacement of the removable top layer.

20. The sensor system of claim 16 , wherein the resonant circuit is configured to detect the analyte flowing from a vehicle.

21. The sensor system of claim 16 , wherein the resonant circuit comprises a capacitive element that at least partially contains the sensing material.

22. The sensor system of claim 21 , further comprising a pair of electrodes electrically coupled to the capacitive element.

23. The sensor system of claim 16 , further comprising a circuit configured to generate the electromagnetic signal.

24. The sensor system of claim 23 , wherein a frequency of a peak in the resonant signal induced by dithering the electromagnetic signal is indicative of a presence of the analyte in the sensing material.

25. The sensor system of claim 24 , further comprising a circuit configured to determine a presence of the analyte in the sensing material based on a comparison between the frequency of the peak in the resonant signal and one or more frequencies indicative of harmful substances.

26. A method for detecting an analyte in a sensing material defined by a carbon structure including a plurality of distinctly sized interconnected channels, the method comprising:
receiving the analyte through the one or more distinctly sized interconnected channels into the carbon structure;
receiving at least one electromagnetic signal configured to oscillate over a range of frequencies; and
identifying the analyte based on a resonant signal of the carbon structure responsive to the at least one electromagnetic signal, wherein a frequency of a peak in the resonant signal induced by dithering the at least one electromagnetic signal is indicative of a presence of the analyte in the sensing material.

Assignees

• Lyten Inc

Inventors

• Stowell Michael W
• Lanning Bruce
• Lim Sung H
• Singh Shreeyukta
• Chmiola John

Classifications

• G01N33/0039

  O3 · CPC title

• B01J20/28066 Primary

  being more than 1000 m2/g · CPC title

• G01N27/4045

  for gases other than oxygen · CPC title

• G01N2291/014

  Resonance or resonant frequency · CPC title

• G01N33/004

  CO or CO2 · CPC title