Modifier and use method thereof, modifier production method and carrier for additive

Patent metadata

Field	Value
Publication number	US-11118049-B2
Application number	US-201816480026-A
Country	US
Kind code	B2
Filing date	Jan 19, 2018
Priority date	Jan 30, 2017
Publication date	Sep 14, 2021
Grant date	Sep 14, 2021

Abstract

Disclosed is a modifier that is blended with a polyolefin to obtain a molded body and methods for using the same and for producing the modifier. The modifier includes a continuous phase (A) containing a second polyolefin resin and a dispersed phase (B) containing a polyamide resin and a modified elastomer and composed of a melt-kneaded product of the polyamide resin and the modified elastomer, the modified elastomer is an elastomer having a reactive group that reacts with the polyamide resin, the elastomer is an olefin-based thermoplastic elastomer having, as a skeleton, a copolymer of ethylene or propylene and an α-olefin having 3-8 carbon atoms or a styrene-based thermoplastic elastomer having a styrene skeleton, and when a total of the continuous phase (A) and the dispersed phase (B) is taken as 100% by mass, a content of the dispersed phase (B) is 80% by mass or less.

First claim

The invention claimed is:

1. A method of combining a modifier with a polyolefin comprising:
mixing the modifier with a first polyolefin resin in an amount of 0.5 parts by mass or more but 80 parts by mass or less per 100 parts by mass of the first polyolefin resin, wherein
the modifier is capable of being added to the first polyolefin resin to obtain a molded body having improved impact resistance, and wherein the modifier comprises:
a continuous phase (A) containing a second polyolefin resin; and a dispersed phase (B) dispersed in the continuous phase (A) and containing a polyamide resin and a modified elastomer, wherein
the dispersed phase (B) is composed of a melt-kneaded product of the polyamide resin and the modified elastomer,
the modified elastomer is an elastomer having a reactive group that reacts with the polyamide resin,
the elastomer is an olefin-based thermoplastic elastomer having, as a skeleton, a copolymer of ethylene and a 3-8-carbon α-olefin, a copolymer of propylene and a 4-8-carbon α-olefin, or a styrene-based thermoplastic elastomer having a styrene skeleton, and
when a total of the continuous phase (A) and the dispersed phase (B) is taken as 100% by mass, a content of the dispersed phase (B) is 80% by mass or less.

2. A carrier for an additive for adding an additive to a first polyolefin resin, the carrier comprising:
a continuous phase (A) containing a second polyolefin resin; and a dispersed phase (B) dispersed in the continuous phase (A) and containing a polyamide resin and a modified elastomer, wherein
the dispersed phase (B) is composed of a melt-kneaded product of the polyamide resin and the modified elastomer,
the modified elastomer is an elastomer having a reactive group that reacts with the polyamide resin,
the elastomer is an olefin-based thermoplastic elastomer having, as a skeleton, a copolymer of ethylene and a 3-8-carbon α-olefin, a copolymer of propylene and a 4-8-carbon α-olefin, or a styrene-based thermoplastic elastomer having a styrene skeleton,
when a total of the continuous phase (A) and the dispersed phase (B) is taken as 100% by mass, a content of the dispersed phase (B) is 80% by mass or less,
wherein the first polyolefin resin is a block copolymerized polyolefin resin having an ethylene block as a dispersed phase, and
the additive is at least one of a flame retardant, a flame retardant aid, a filler, a colorant, an antimicrobial agent, an antistatic agent, and a foaming agent.

3. The method according to claim 1 , wherein when a total of the polyamide resin and the modified elastomer is taken as 100% by mass, a content of the polyamide resin is 10% by mass or more but 80% by mass or less.

4. The method according to claim 1 , wherein the dispersed phase (B) has a continuous phase (B 1 ) containing the polyamide resin and a fine dispersed phase (B 2 ) dispersed in the continuous phase (B 1 ) and containing the modified elastomer.

5. The method according to claim 1 , wherein the polyamide resin is polyamide 6.

6. The method according to claim 5 , wherein the second polyolefin resin has a number-average molecular weight of 300,000 or more.

7. The method according to claim 1 , wherein the first polyolefin resin is a block copolymerized polyolefin resin having an ethylene block as a dispersed phase.

8. The carrier according to claim 2 , wherein when a total of the polyamide resin and the modified elastomer is taken as 100% by mass, a content of the polyamide resin is 10% by mass or more but 80% by mass or less.

9. The carrier according to claim 2 , wherein the dispersed phase (B) has a continuous phase (B 1 ) containing the polyamide resin and a fine dispersed phase (B 2 ) dispersed in the continuous phase (B 1 ) and containing the modified elastomer.

10. The carrier according to claim 2 , wherein the polyamide resin is polyamide 6.

11. The carrier according to claim 10 , wherein the second polyolefin resin has a number-average molecular weight of 300,000 or more.

Assignees

• Toyota Boshoku Kk

Inventors

• Kato Keisuke

Classifications

• C08J2477/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08J2477/10 takes precedence) · CPC title

• C08J2453/00

  Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers · CPC title

• C08J2451/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08J2423/14

  Copolymers of propene (C08J2423/16 takes precedence) · CPC title

• C08J2423/08

  Copolymers of ethene (C08J2423/16 takes precedence) · CPC title