Thermoplastic resin composition, method for producing same, and molded body

Patent metadata

Field	Value
Publication number	US-9840615-B2
Application number	US-201615284691-A
Country	US
Kind code	B2
Filing date	Oct 4, 2016
Priority date	Dec 22, 2011
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

The purpose of the present invention is to provide: a thermoplastic resin composition which exhibits excellent rigidity, while having excellent impact strength characteristics; and a method for producing the thermoplastic resin composition. This thermoplastic resin composition, wherein a polyolefin resin contains a polyamide resin that is dispersed therein, is characterized in that: the thermoplastic resin composition is obtained by melting and kneading a polyolefin resin and a mixed resin that is obtained by melting and kneading a polyamide resin and a compatibilizer; and the compatibilizer is a modified elastomer that is obtained by providing an elastomer (such as an olefin-based thermoplastic elastomer or a styrene-based thermoplastic elastomer) with a reactive group that is reactive with the polyamide resin. The present invention also relates to a thermoplastic resin composition which is obtained by melting and kneading from 1% by mass to 80% by mass (inclusive) of a plant-derived polyamide resin such as polyamide 11, from 5% by mass to 75% by mass (inclusive) of a polyolefin resin and from 1% by mass to 30% by mass (inclusive) of a compatibilizer that is an olefin-based thermoplastic elastomer that is modified with an acid.

First claim

The invention claimed is:

1. A plant-derived polyamide resin-containing thermoplastic resin composition that is obtained by molten blending a polyamide resin, a polyolefin resin that does not comprise a reactive group that reacts with the polyamide resin, and a compatibilizer, wherein
the polyamide resin is at least one plant-derived polyamide resin selected from the group consisting of polyamide 11, polyamide 610, polyamide 614, polyamide 1010, and polyamide 10T,
the content of the polyamide resin is from 1% to 80% by mass based on 100% by mass of the total of the polyamide resin, the polyolefin resin, and the compatibilizer,
the content of the polyolefin resin is from 5% to 55% by mass based on 100% by mass of the total of the polyamide resin, the polyolefin resin, and the compatibilizer, and
the compatibilizer is an acid-modified olefin-based thermoplastic elastomer and the content of the compatibilizer is from 1% to 30% by mass based on 100% by mass of the total of the polyamide resin, the polyolefin resin, and the compatibilizer,
wherein the plant-derived polyamide resin-containing thermoplastic resin composition has a specific gravity from 0.89 to 0.98.

2. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 1 , wherein
the compatibilizer is an anhydrous maleic acid-modified ethylene 1-butene copolymer or an anhydrous maleic acid-modified ethylene octene copolymer.

3. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 2 , wherein
the polyamide resin is at least one selected from the group consisting of polyamide 11, polyamide 610, polyamide 1010, and polyamide 10T, and
the polyolefin resin is a polypropylene.

4. A molded article comprising the plant-derived polyamide resin-containing thermoplastic resin composition according to claim 1 , wherein the molded article is an exterior material, interior material, or structural material for automobiles, rail vehicles, ships, airplanes, buildings, or furniture, or a housing or structural member of a home appliance.

5. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 1 , wherein said content of said compatibilizer is in a range from 10% to 30% by mass.

6. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 5 ,
wherein said polyamide resin is polyamide 11, and
wherein said compatibilizer is an anhydrous maleic acid-modified ethylene 1-butene copolymer or an anhydrous maleic acid-modified ethylene octene copolymer.

7. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 6 ,
wherein the Charpy impact strength of said plant-derived polyamide resin containing thermoplastic resin is from 18.2 to 86.3 k J/m 2 .

8. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 1 ,
wherein the Charpy impact strength of said plant-derived polyamide resin containing thermoplastic resin is from 3.8 to 86.3 kJ/m 2 .

9. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 8 , wherein said compatibilizer is an anhydrous maleic acid-modified ethylene 1-butene copolymer or an anhydrous maleic acid-modified ethylene octene copolymer.

10. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 1 ,
wherein the flexural modulus of said plant-derived polyamide resin containing thermoplastic resin is from 710 to 1380 MPa.

11. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 10 , wherein said compatibilizer is an anhydrous maleic acid-modified ethylene 1-butene copolymer or an anhydrous maleic acid-modified ethylene octene copolymer.

12. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 1 ,
wherein said polyamide resin is at least one resin selected from the group consisting of polyamide 11, polyamide 610, and polyamide 1010, and
wherein the Charpy impact strength of said plant-derived polyamide resin containing thermoplastic resin is from 4.8 to 86.3 kJ/m 2 .

13. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 12 , wherein said compatibilizer is an anhydrous maleic acid-modified ethylene 1-butene copolymer or an anhydrous maleic acid-modified ethylene octene copolymer.

14. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 1 ,
wherein said polyamide resin is at least one resin selected from the group consisting of polyamide 11, polyamide 610, and polyamide 1010, and
wherein the flexural modulus of said plant-derived polyamide resin containing thermoplastic resin is from 710 to 1380 MPa.

15. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 14 , wherein said compatibilizer is an anhydrous maleic acid-modified ethylene 1-butene copolymer or an anhydrous maleic acid-modified ethylene octene copolymer.

16. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 1 ,
wherein said polyamide resin is polyamide 11, and
wherein the Charpy impact strength of said plant-derived polyamide resin containing thermoplastic resin is from 6.4 to 86.3 kJ/m 2 .

17. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 16 , wherein said compatibilizer is an anhydrous maleic acid-modified ethylene 1-butene copolymer or an anhydrous maleic acid-modified ethylene octene copolymer.

18. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 1 ,
wherein said polyamide resin is polyamide 11, and
wherein the flexural modulus of said plant-derived polyamide resin containing thermoplastic resin is from 710 to 1211 MPa.

19. The plant-derived polyamide resin containing thermoplastic resin composition according to claim 18 ,
wherein said compatibilizer is an anhydrous maleic acid-modified ethylene 1-butene copolymer or an anhydrous maleic acid-modified ethylene octene copolymer.

20. A plant-derived polyamide resin-containing thermoplastic resin composition that is obtained by molten blending a polyamide resin, a polyolefin resin that does not comprise a reactive group that reacts with the polyamide resin, and a compatibilizer, wherein
the polyamide resin is at least one plant-derived polyamide resin selected from the group consisting of polyamide 11, polyamide 610, polyamide 614, polyamide 1010, and polyamide 10T,
the content of the polyamide resin is from 55% to 80% by mass based on 100% by mass of the total of the polyamide resin, the polyolefin resin, and the compatibilizer,
the content of the polyolefin resin is from 10% to 40% by mass based on 100% by mass of the total of the polyamide resin, the polyolefin resin, and the compatibilizer, and
the compatibilizer is an acid-modified olefin-based thermoplastic elastomer and the content of the compatibilizer is from 5% to 30% by mass based on 100% by mass of the total of the polyamide resin, the polyolefin resin, and the compatibilizer,
wherein the plant-derived polyamide resin-containing thermoplastic resin composition has a specific gravity from 0.89 to 0.98.

Assignees

• Toyota Boshoku Kk
• Toyota Chuo Kenkyusho Kk

Inventors

• Kito Masayuki
• Ario Toshiyuki
• KAWADA Jumpei
• Mouri Makoto
• Watanabe Osamu
• Kato Makoto
• Okamoto Hirotaka

Classifications

• C08J2409/00

  Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08J5/00

  Manufacture of articles or shaped materials containing macromolecular substances (manufacture of semi-permeable membranes B01D67/00 - B01D71/00) · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08J2423/20

  having four to nine carbon atoms · CPC title

• C08L23/12 Primary

  Polypropene · CPC title