Positive active material for rechargeable lithium battery, positive electrode including same and rechargeable lithium battery including same

Patent metadata

Field	Value
Publication number	US-11114658-B2
Application number	US-201916279306-A
Country	US
Kind code	B2
Filing date	Feb 19, 2019
Priority date	Feb 19, 2018
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

Provided are a positive active material for a rechargeable lithium battery and a positive electrode including the same. The positive active material for a rechargeable lithium battery includes a first positive active material and a second positive active material, wherein the first positive active material includes at least one nickel-based lithium composite oxide, and the second positive active material is represented by Chemical Formula 2 and has an average particle diameter of about 300 nm to about 600 nm:Lia1Fe1-x1M1x1PO4.  [Chemical Formula 2]In Chemical Formula 2, 0.90≤a1≤1.8, 0≤x1≤0.7, and M1 may be Mg, Co, Ni, or a combination thereof.

First claim

What is claimed is:

1. A positive active material for a rechargeable lithium battery, comprising:
a first positive active material and a second positive active material mixed together,
wherein the first positive active material is a mixture of a first nickel-based lithium composite oxide and a second nickel-based lithium composite oxide, the first nickel-based lithium composite oxide and the second nickel-based lithium composite oxide having different average particle diameters,
the second positive active material is represented by Chemical Formula 2 and has an average particle diameter of about 300 nm to about 600 nm:
Li a1 Fe 1-x1 M1 x1 PO 4 ,  [Chemical Formula 2]

wherein, in Chemical Formula 2, 0.90≤a1≤1.8, 0≤x1≤0.7, and M1 is magnesium (Mg), cobalt (Co), nickel (Ni), or a combination thereof,
an amount of the first positive active material is about 90 wt % to about 98 wt % based on a total amount of the positive active material for a rechargeable lithium battery, and
an amount of the second positive active material is about 2 wt % to about 10 wt % based on a total amount of the positive active material for a rechargeable lithium battery.

2. The positive active material of claim 1 , wherein at least one selected from the group consisting of the first nickel-based lithium composite oxide and the second nickel-based lithium composite oxide comprises a compound represented by Chemical Formula 1:
Li a2 (Ni 1-x2-y-z Co x2 Me y M2 z )O 2 ,  [Chemical Formula 1]

wherein, in Chemical Formula 1:
M2 is an element selected from the group consisting of boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), chromium (Cr), iron (Fe), copper (Cu), and zirconium (Zr),
0.95≤a2≤1.3, x2<(1-x2-y-z), y<(1-x2-y-z), 0<x2<1, 0≤y<1, 0≤z<1, and
Me is at least one selected from the group consisting of Mn and Al.

3. The positive active material of claim 1 , wherein at least one selected from the group consisting of the first nickel-based lithium composite oxide and the second nickel-based lithium composite oxide is represented by at least one selected from the group consisting of LiNi 0.6 Co 0.2 Mn 0.2 O 2 , LiNi 0.5 Co 0.2 Mn 0.3O2 , LiNi 0.33 Co 0.33 Mn 0.33 O 2 , LiNi 0.8 Co 0.1 Mn 0.1 O 2 , LiNi 0.85 Co 0.1 Al 0.05 O 2 , and LiNi 0.95 Co 0.025 Al 0.025 O 2 .

4. A positive electrode for a rechargeable lithium battery, comprising:
a current collector; and
a positive active material layer on at least one surface of the current collector;
wherein the positive active material layer comprises the positive active material for the rechargeable lithium battery of claim 1 .

5. A positive electrode for a rechargeable lithium battery, comprising:
a current collector;
a positive active material layer on at least one surface of the current collector; and
a functional layer on the positive active material layer,
wherein the positive active material layer comprises a positive active material comprising:
a first positive active material and a second positive active material,
the first positive active material comprising at least one nickel-based lithium composite oxide, and
the second positive active material being represented by Chemical Formula 2 and having an average particle diameter of about 300 nm to about 600 nm:
Fe a1 Fe 1-x1 M1 x1 PO 4 ,  [Chemical Formula 2]

wherein, in Chemical Formula 2, 0.90≤a1≤1.8, 0≤x1≤0.7, and M1 is magnesium (Mg), cobalt (Co), nickel (Ni), or a combination thereof,
wherein the functional layer comprises a compound represented by Chemical Formula 3 and a binder:
Li a3 Fe 1-x3 M3 x3 PO 4 ,  [Chemical Formula 3]

wherein, in Chemical Formula 3, 0.90≤a3≤1.8, 0≤x3≤0.7, and
M3 is Mg, Co, Ni, or a combination thereof.

6. The positive electrode of claim 5 , wherein an average particle diameter of the compound represented by Chemical Formula 3 is about 0.2 μm to about 1 μm.

7. The positive electrode of claim 5 , wherein the binder comprises at least one selected from the group consisting of a styrene-butadiene rubber, an acrylate-based compound, an imide-based compound, a polyvinylidene fluoride-based compound, a polyvinylpyrrolidone-based compound, a nitrile-based compound, an acetate-based compound, a cellulose-based compound, and a cyano-based compound.

8. The positive electrode of claim 5 , wherein a ratio of a thickness of the positive active material layer to a thickness of the functional layer is about 30:1 to about 10:1.

9. The positive electrode of claim 5 , wherein:
the functional layer further comprises polymer particles, and
an amount of the polymer particles is about 20 wt % to about 70 wt % based on a total amount of the functional layer.

10. The positive electrode of claim 9 , wherein the polymer particles comprise at least one selected from the group consisting of polyethylene wax, acryl-based particles having a glass transition temperature (T g ) of less than or equal to about 100° C., and a combination thereof.

11. A rechargeable lithium battery, comprising:
the positive electrode of claim 4 ;
a negative electrode; and
an electrolyte solution.

12. The rechargeable lithium battery of claim 11 , wherein at least one selected from the group consisting of the first nickel-based lithium composite oxide and the second nickel-based lithium composite oxide comprises a compound represented by Chemical Formula 1:
Li a2 (Ni 1-x2-y-z Co x2 Me y M2 z )O 2 ,  [Chemical Formula 1]

wherein, in Chemical Formula 1:
M2 is an element selected from the group consisting of boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), chromium (Cr), iron (Fe), copper (Cu), and zirconium (Zr),
0.95≤a2≤1.3, x2<(1-x2-y-z), y<(1-x2-y-z), 0<x2<0≤y<1, 0≤z<1, and
Me is at least one selected from the group consisting of Mn and Al.

13. The rechargeable lithium battery of claim 11 , wherein at least one selected from the group consisting of the first nickel-based lithium composite oxide and the second nickel-based lithium composite oxide is represented by at least one selected from the group consisting of LiNi 0.6 Co 0.2 Mn 0.2 O 2 , LiNi 0.5 Co 0.2 Mn 0.3 O 2 , LiNi 0.33 Co 0.33 Mn 0.33 O 2 , LiNi 0.8 Co 0.1 Mn 0.1 O 2 , LiNi 0.85 Co 0.1 Al 0.05 O 2 , and LiNi 0.95 Co 0.025 Al 0.025 O 2 .

14. The rechargeable lithium battery of claim 11 , wherein an amount of the second positive active material is about 1 wt % to about 15 wt % based on a total amount of the positive active material for the rechargeable lithium battery.

15. The rechargeable lithium battery of claim 11 , wherein the positive electrode further comprises a functional layer on the positive active material layer,
wherein the functional layer comprises a compound represented by Chemical Formula 3 and a binder:
Li a3 Fe 1-x3 M3 x3 PO 4 ,  [Chemical Formula 3]

wherein, in Chemical Formula 3, 0.90≤a3≤1.8, 0≤x3≤0.7, and
M3 is Mg, Co, Ni, or a combination thereof.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Yoo Heeeun
• Nam Junghyun
• Seok Hoon
• Yoon Yeonhee
• Lee Kyuseo
• Jeon Bokkyu
• Ha Jaehwan

Classifications

• H01M4/622

  being polymers · CPC title

• H01M10/4235

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title

• H01M4/364 Primary

  as mixtures · CPC title

• H01M2200/00

  Safety devices for primary or secondary batteries · CPC title

• H01M10/052

  Li-accumulators · CPC title