Yttrium fluoride spray material, yttrium oxyfluoride-deposited article, and making methods
US-2017114440-A1 · Apr 27, 2017 · US
US11111573B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11111573-B2 |
| Application number | US-202016777371-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 30, 2020 |
| Priority date | Jul 31, 2017 |
| Publication date | Sep 7, 2021 |
| Grant date | Sep 7, 2021 |
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A component includes a film containing polycrystalline yttrium oxide. In an X-ray diffraction pattern of the film, a ratio Im/Ic of a maximum intensity Im of a peak attributed to monoclinic yttrium oxide to a maximum intensity Ic of a peak attributed to cubic yttrium oxide satisfies an expression: 0≤Im/Ic≤0.002.
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What is claimed is: 1. A component, comprising a film containing crystalline yttrium oxide, wherein in an X-ray diffraction pattern of the film, a ratio I m /I c of a maximum intensity I m of a peak attributed to monoclinic yttrium oxide to a maximum intensity I c of a peak attributed to cubic yttrium oxide satisfies an expression: 0≤I m /I c ≤0.002, an average grain diameter of the crystalline yttrium oxide is 3.8 nm or less, and in an observation image obtained by observing a cross section in a thickness direction of the film by using a scanning electron microscope at 10000 magnification, a pore is not present or a maximum diameter of a pore is 10 nm or less. 2. The component according to claim 1 , wherein the X-ray diffraction pattern does not have a peak attributed to yttrium oxide whose crystal structure is different from a crystal structure of the cubic yttrium oxide. 3. The component according to claim 1 , wherein a thickness of the film is 100 μm or less. 4. The component according to claim 1 , wherein a thickness of the film is 10 μm or more and 50 μm or less. 5. The component according to claim 1 , wherein: a content of yttrium oxide in the film is 99 mass % or more; a content of aluminum in the film is 100 mass ppm or less; a content of magnesium in the film is 20 mass ppm or less; a content of sodium in the film is 50 mass ppm or less; a content of zinc in the film is 100 mass ppm or less; a content of calcium in the film is 100 mass ppm or less; a content of potassium in the film is 5 mass ppm or less; and a content of nickel in the film is 10 mass ppm or less. 6. The component according to claim 1 , wherein a tensile strength B of the film obtained after performing three cycles of exposing the component to a temperature environment between 400° C. and 600° C. for 30 minutes and then exposing the component to a temperature environment of 25° C. for 30 minutes, with respect to a tensile strength A of the film under a temperature environment of 25° C., satisfies an expression: ((A−B)/A)×100%≤20%. 7. A semiconductor manufacturing apparatus, comprising the component according to claim 1 . 8. The semiconductor manufacturing apparatus according to claim 7 , further comprising a mechanism for performing plasma processing, wherein the mechanism has the component. 9. The component according to claim 1 , wherein the X-ray diffraction pattern does not have a peak attributed to yttrium oxide whose crystal structure is different from a crystal structure of the cubic yttrium oxide, and a thickness of the film is 100 μm or less. 10. The component according to claim 1 , wherein the X-ray diffraction pattern does not have a peak attributed to yttrium oxide whose crystal structure is different from a crystal structure of the cubic yttrium oxide, a thickness of the film is 100 μm or less, a content of yttrium oxide in the film is 99 mass % or more, a content of aluminum in the film is 100 mass ppm or less, a content of magnesium in the film is 20 mass ppm or less, a content of sodium in the film is 50 mass ppm or less, a content of zinc in the film is 100 mass ppm or less, a content of calcium in the film is 100 mass ppm or less, a content of potassium in the film is 5 mass ppm or less, and a content of nickel in the film is 10 mass ppm or less. 11. A semiconductor manufacturing apparatus, comprising the component according to claim 9 . 12. A semiconductor manufacturing apparatus, comprising the component according to claim 10 .
of Group IV materials · CPC title
Oxidation · CPC title
Thermal treatment · CPC title
Controlling the film thickness or evaporation rate · CPC title
Sputtering · CPC title
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