Epoxy resin composition

Patent metadata

Field	Value
Publication number	US-11091627-B2
Application number	US-201816476681-A
Country	US
Kind code	B2
Filing date	Jan 9, 2018
Priority date	Jan 10, 2017
Publication date	Aug 17, 2021
Grant date	Aug 17, 2021

Abstract

Provided is an epoxy resin composition having excellent adhesion and low dielectric characteristics. Specifically, provided is an epoxy resin composition comprising an acid-modified polyolefin resin and an epoxy resin having a specific structure.

First claim

The invention claimed is:

1. An epoxy resin composition comprising an epoxy resin and an acid-modified polyolefin resin, the epoxy resin being at least one epoxy resin selected from the group consisting of:
an epoxy resin represented by the formula (1-iia):

wherein X ii is a divalent group obtained by removing two hydrogen atoms from a saturated hydrocarbon ring or an unsaturated hydrocarbon ring, or from rings having a structure in which 2 to 6 saturated hydrocarbon rings and/or unsaturated hydrocarbon rings are condensed; or a divalent group represented by the formula (2 g -iia):

wherein Y is a bond, a C 1-6 alkylene group that may be substituted with a C 1-4 alkyl group, an oxygen atom (—O—), a sulfur atom (—S—), —SO—, or —SO 2 —;
R 1 is the same or different, and is a C 1-18 alkyl group, a C 2-9 alkenyl group, a cycloalkyl group, an aryl group, or an aralkyl group, wherein one or more carbon atoms of these groups may be replaced by at least one atom selected from the group consisting of an oxygen atom and a nitrogen atom;
R 2 is the same or different, and is a C 1-18 alkylene group, wherein one or more carbon atoms of this group other than a carbon atom directly bonded to a silicon atom may be replaced by at least one atom selected from the group consisting of an oxygen atom and a nitrogen atom;
R 3 is the same or different, and is a C 1-18 alkyl group, a C 2-9 alkenyl group, a cycloalkyl group, an aryl group, or an aralkyl group, wherein one or more carbon atoms of these groups may be replaced by at least one atom selected from the group consisting of an oxygen atom and a nitrogen atom;
m is an integer of 0 to 6; and
n is an integer of 0 to 3; and
an epoxy resin represented by the formula (1-iiia):

wherein X iii is a trivalent group obtained by removing three hydrogen atoms from a saturated hydrocarbon ring or an unsaturated hydrocarbon ring, or from rings having a structure in which 2 to 6 saturated hydrocarbon rings and/or unsaturated hydrocarbon rings are condensed;
or a trivalent group represented by the formula (2 g -iiia):

wherein Y is as defined above; and
R 1 , R 2 , R 3 , m, and n are as defined above,
wherein the acid-modified polyolefin resin is at least one member selected from the group consisting of an acid-modified polyolefin resin obtained by grafting a polyolefin resin with an acid-modified group, an acid-modified polyolefin resin obtained by copolymerizing an olefin and at least one of an unsaturated carboxylic acid and/or an acid anhydride thereof, and acid-modified polyolefin resins obtained by hydrogenating these acid-modified polyolefin resins.

2. The epoxy resin composition according to claim 1 , wherein the saturated hydrocarbon ring is a C 4-8 saturated hydrocarbon ring, and the unsaturated hydrocarbon ring is a C 4-8 unsaturated hydrocarbon ring.

3. The epoxy resin composition according to claim 1 , wherein the composition comprises an acid-modified polyolefin resin and at least one epoxy resin selected from the group consisting of:
an epoxy resin represented by the formula (1-IIa):

wherein R 1 , R 2 , and X ii are as defined in claim 1 ,
an epoxy resin represented by the formula (1-IIb):

wherein R 1 , R 2 , R 3 , X ii , and n are as defined in claim 1 , and
an epoxy resin represented by the formula (1-IIIa):

wherein R 1 , R 2 , R 3 , X iii , and n are as defined in claim 1 .

4. The epoxy resin composition according to claim 1 , wherein the acid-modified polyolefin resin has an acid value (mgKOH/g) of 0.5 to 500.

5. A varnish comprising the epoxy resin composition according to claim 1 and an organic solvent.

6. A cured product of the epoxy resin composition according to claim 1 .

7. A semiconductor sealing material, a liquid sealing material, a potting material, a sealing material, an interlayer insulation film, an adhesive layer, a coverlay film, an electromagnetic shielding film, a printed circuit board material, or a composite material, each of which uses the epoxy resin composition according to claim 1 .

8. A semiconductor sealing material, a liquid sealing material, a potting material, a sealing material, an interlayer insulation film, an adhesive layer, a coverlay film, an electromagnetic shielding film, a printed circuit board material, or a composite material, each of which uses the varnish according to claim 5 .

9. A semiconductor sealing material, a liquid sealing material, a potting material, a sealing material, an interlayer insulation film, an adhesive layer, a coverlay film, an electromagnetic shielding film, a printed circuit board material, or a composite material, each of which uses the cured product according to claim 6 .

10. The epoxy resin composition according to claim 1 , wherein the acid-modified polyolefin resin is an acid-modified polyolefin resin obtained by grafting a polyolefin resin with an acid-modified group,
the polyolefin resin is at least one member selected from the group consisting of polyethylene, polypropylene, and an olefin copolymer, and
the acid-modified group is a maleic anhydride group.

11. The epoxy resin composition according to claim 1 , wherein the acid-modified polyolefin resin is at least one member selected from the group consisting of a styrene-maleic anhydride copolymer, an ethylene-maleic anhydride copolymer, a propylene-maleic anhydride copolymer, and an isobutylene-maleic anhydride copolymer.

12. The epoxy resin composition according to claim 1 , wherein the acid-modified polyolefin resin is obtained by hydrogenating a resin obtained by grafting a polyolefin resin with an acid-modified group,
the polyolefin resin is at least one member selected from the group consisting of polyethylene, polypropylene, and an olefin copolymer, and
the acid-modified group is a maleic anhydride group.

13. The epoxy resin composition according to claim 1 , wherein the acid-modified polyolefin resin is obtained by hydrogenating at least one member selected from the group consisting of a styrene-maleic anhydride copolymer, an ethylene-maleic anhydride copolymer, a propylene-maleic anhydride copolymer, and an isobutylene-maleic anhydride copolymer.

Assignees

• Sumitomo Seika Chemicals

Inventors

• Fukuda Noriaki
• Harisaki Ryota
• Yamamoto Katsumasa

Classifications

• H10W74/476

  Organic materials comprising silicon · CPC title

• H10W74/47

  comprising organic materials, e.g. plastics or resins · CPC title

• H10P14/683

  carbon-based polymeric organic materials, e.g. polyimides, poly cyclobutene or PVC · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title

• C08L25/08

  Copolymers of styrene (C08L29/08, C08L35/06, C08L55/02 take precedence) · CPC title