Lubricant blends to reduce refrigerant solubility

Patent metadata

Field	Value
Publication number	US-11085680-B2
Application number	US-202016840614-A
Country	US
Kind code	B2
Filing date	Apr 6, 2020
Priority date	May 10, 2016
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

Compositions, methods, systems, and applications herein are directed to lubricant blends that balance solubility and viscosity of a refrigerant, where in some cases the lubricant blends herein help reduce solubility of a refrigerant. A lubricant blend includes a mixture of two or more different types of lubricants to reduce refrigerant solubility.

First claim

The invention claimed is:

1. A lubricant blend composition, comprising:
a first lubricant including one or more of polyol ester (POE), polyvinyl ether (PVE), and polyalkylene glycol (PAG); and
a second lubricant including one or more of alkylbenzene (AB), polyalphaolefin (PAO), mineral oil, and estolide, wherein
the first lubricant is present at a higher volume percentage than the second lubricant, and the first lubricant has a higher viscosity than the second lubricant, such that the lubricant blend composition:
has an International Standards Organization (ISO) viscosity at 40° C. of from at or about 73 cSt to at or about 120 cSt, and
exhibits a suitable miscibility and solubility within a desired operating range of a vapor compression system when mixed with a refrigerant, the refrigerant is at least one selected from the group consisting of 1,1-dichloro-2,2,2-trifluoroethane, 1,1,1,3,3-Pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1-difluoroethane, 1-chloro-3,3,3-trifluoropropene (Z), 2-chloro-3,3,3-trifluoropropene, 1,1-dichloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene (E), 1,3,3,3-tetrafluoropropene (Z), 1,2-dichloro-3,3,3-trifluoropropene (E), 1,2-dichloro-3,3,3-trifluoropropene (Z), 1,1,3-trichloro-3,3,3-trifluoropropene, 1,2-dichloroethylene (E), 1,2-dichloroethylene (Z), 1,1-dichloroethylene, 1,1,1,4,4,4-hexafluorobutene (Z), 1,1,1,4,4,4-hexafluorobutene (E), 1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, C2-C8 hydrocarbons, carbon dioxide, ammonia, and blends thereof.

2. The lubricant blend composition of claim 1 , wherein the first lubricant is present at or about 60 to at or about 90 percent by volume of the lubricant blend composition, and the second lubricant is present at or about 10 to at or about 40 percent by volume of the lubricant blend composition.

3. The lubricant blend composition of claim 1 , wherein the first lubricant is present at or about 80 to at or about 90 percent by volume of the lubricant blend composition, and the second lubricant is present at or about 10 to at or about 20 percent by volume of the lubricant blend composition.

4. The lubricant blend composition of claim 1 , wherein the first lubricant is present at or about 80 to at or about 85 percent by volume of the lubricant blend composition, and the second lubricant is present at or about 15 to at or about 20 percent by volume of the lubricant blend composition.

5. The lubricant blend composition of claim 1 , wherein the first lubricant is present at or about 85 to at or about 90 percent by volume of the lubricant blend composition, and the second lubricant is present at or about 10 to at or about 15 percent by volume of the lubricant blend composition.

6. The lubricant blend composition of claim 1 , wherein the first lubricant is the POE or the PVE and the second lubricant is the AB or the mineral oil.

7. The lubricant blend composition of claim 1 , wherein the first lubricant is the POE and the second lubricant is the AB.

8. A fluid for a vapor compression system, comprising:
the lubricant blend composition of claim 1 ; and
a refrigerant that is at least one selected from the group consisting of 1,1-dichloro-2,2,2-trifluoroethane, 1,1,1,3,3-pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1-difluoroethane, 1-chloro-3,3,3-trifluoropropene (Z), 2-chloro-3,3,3-trifluoropropene, 1,1-dichloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene (E), 1,3,3,3-tetrafluoropropene (Z), 1,2-dichloro-3,3,3-trifluoropropene (E), 1,2-dichloro-3,3,3-trifluoropropene (Z), 1,1,3-trichloro-3,3,3-trifluoropropene, 1,2-dichloroethylene (E), 1,2-dichloroethylene (Z), 1,1-dichloroethylene, 1,1,1,4,4,4-hexafluorobutene (Z), 1,1,1,4,4,4-hexafluorobutene (E), 1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, C2-C8 hydrocarbons, carbon dioxide, ammonia, and blends thereof.

9. The fluid of claim 8 , wherein the vapor compression system is a fluid chiller for an HVACR application, and the fluid chiller includes a centrifugal compressor.

10. The fluid of claim 8 , wherein the refrigerant is a refrigerant blend including, by weight of the refrigerant blend, a first refrigerant at or about 60 to at or about 90 percent by weight and a second refrigerant at or about 10 to at or about 40 percent by weight.

11. The fluid of claim 8 , wherein the refrigerant is a refrigerant blend including, by weight of the refrigerant blend, a first refrigerant at or about 70 to at or about 90 percent by weight and a second refrigerant at or about 10 to at or about 30 percent by weight.

12. The fluid of claim 8 , wherein the refrigerant is a refrigerant blend including, by weight of the refrigerant blend, a first refrigerant at or about 80 to at or about 90 percent by weight and a second refrigerant at or about 10 to at or about 20 percent by weight.

13. The fluid of claim 8 , wherein the refrigerant is a refrigerant blend including, by weight of the refrigerant blend, a first refrigerant at or about 75 to at or about 80 percent by weight and a second refrigerant at or about 20 to at or about 25 percent by weight.

14. The fluid of any of claim 8 , wherein the refrigerant is a refrigerant blend including the 1,1,1,4,4,4-hexafluorobutene (Z) as the first refrigerant and the 1,2-dichloroethylene (E) as the second refrigerant.

15. A vapor compression system including comprising:
a compressor;
a condenser;
an evaporator;
an expansion device; and
the lubricant blend composition of claim 1 which is blended with a refrigerant, the refrigerant is at least one selected from the group consisting of 1,1-dichloro-2,2,2-trifluoroethane, 1,1,1,3,3-pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1-difluoroethane, 1-chloro-3,3,3-trifluoropropene (Z), 2-chloro-3,3,3-trifluoropropene, 1,1-dichloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene (E), 1,3,3,3-tetrafluoropropene (Z), 1,2-dichloro-3,3,3-trifluoropropene (E), 1,2-dichloro-3,3,3-trifluoropropene (Z), 1,1,3-trichloro-3,3,3-trifluoropropene, 1,2-dichloroethylene (E), 1,2-dichloroethylene (Z), 1,1-dichloroethylene, 1,1,1,4,4,4-hexafluorobutene (Z), 1,1,1,4,4,4-hexafluorobutene (E), 1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, C2-C8 hydrocarbons, carbon dioxide, ammonia, and blends thereof.

16. The vapor compression system of claim 15 , wherein the vapor compression system is implemented as a fluid chiller for an HVACR application.

17. The vapor compression system of claim 16 , wherein the fluid chiller includes a centrifugal compressor.

18. A method of retrofitting a vapor compression system, comprising:
removing an existing fluid in the vapor compression system, the existing fluid includes a refrigerant and lubricant mixture;
replacing the existing fluid in the vapor compression system with a replacement fluid, the replacement fluid includes the lubricant blend composition of claim 1 and a refrigerant, the refrigerant is at least one selected from the group consisting of 1,1-dichloro-2,2,2-trifluoroethane, 1,1,1,3,3-pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1-difluoroethane, 1-chloro-3,3,3-trifluoropropene (Z), 2-chloro-3,3,3-trifluoropropene, 1,1-dichloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene (E), 1,3,3,3-tetrafluoropropene (Z), 1,2-dichloro-3,3,3-trifluoropropene (E), 1,2-dichloro-3,3,3-trifluoropropene (Z), 1,1,3-trichloro-3,3,3-trifluoropropene, 1,2-dichloroethyl ene (E), 1,2-dichloroethyl ene (Z), 1,1-dichloroethyl ene, 1,1,1,4,4,4-hexafluorobutene (Z), 1,1,1,4,4,4-hexafluo

Assignees

• Trane Int Inc

Inventors

• Majurin Julie A
• Strange Daniel A
• Steinke Daryl Dean

Classifications

• C10M171/008 Primary

  Lubricant compositions compatible with refrigerants · CPC title

• C09K2205/24

  Only one single fluoro component present · CPC title

• C10M107/34

  Polyoxyalkylenes · CPC title

• C10M2203/1045

  used as base material · CPC title

• C10M2209/1045

  used as base material · CPC title