Lubricant blends to reduce refrigerant solubility

Patent metadata

Field	Value
Publication number	US-10612825-B2
Application number	US-201715591375-A
Country	US
Kind code	B2
Filing date	May 10, 2017
Priority date	May 10, 2016
Publication date	Apr 7, 2020
Grant date	Apr 7, 2020

Abstract

Compositions, methods, systems, and applications herein are directed to lubricant blends that balance solubility and viscosity of a refrigerant, where in some cases the lubricant blends herein help reduce solubility of a refrigerant. A lubricant blend includes a mixture of two or more different types of lubricants to reduce refrigerant solubility.

First claim

The invention claimed is:

1. A lubricant blend composition, comprising:
a first lubricant that includes polyol ester (POE) and has an International Standards Organization (ISO) viscosity at 40° C. of at or about 120 to at or about 220 centistoke (cSt); and
a second lubricant that includes alkylbenzene (AB) and has an ISO viscosity at 40° C. of at or about 4 to at or about 30 cSt,
the first lubricant is present at a higher volume percentage than the second lubricant,
the lubricant blend composition has a resulting viscosity suitable for mixing with a refrigerant including at least one of or blends of 1,1-dichloro-2,2,2-trifluoroethane, 1,1,1,3,3-pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1-difluoroethane, 1-chloro-3,3,3-trifluoropropene (Z), 2-chloro-3,3,3-trifluoropropene, 1,1-dichloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene (E), 1,3,3,3-tetrafluoropropene (Z), 1,2-dichloro-3,3,3-trifluoropropene (E), 1,2-dichloro-3,3,3-trifluoropropene (Z), 1,1,3-trichloro-3,3,3-trifluoropropene, 1,2-dichloroethylene (E), 1,2-dichloroethylene (Z), 1,1-dichloroethylene, 1,1,1,4,4,4-hexafluorobutene (Z), 1,1,1,4,4,4-hexafluorobutene (E), 1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, C2-C8 hydrocarbons, carbon dioxide, and ammonia, and
that exhibits a suitable miscibility and solubility in the refrigerant within a desired operating range of a vapor compression system.

2. The lubricant blend composition of claim 1 , wherein the first lubricant is present at or about 60 to at or about 90 percent by volume of the lubricant blend composition, and the second lubricant is present at or about 10 to at or about 40 percent by volume of the lubricant blend composition.

3. The lubricant blend composition of claim 1 , wherein the first lubricant is present at or about 80 to at or about 90 percent by volume of the lubricant blend composition, and the second lubricant is present at or about 10 to at or about 20 percent by volume of the lubricant blend composition.

4. The lubricant blend composition of claim 1 , wherein the first lubricant is present at or about 80 to at or about 85 percent by volume of the lubricant blend composition, and the second lubricant is present at or about 15 to at or about 20 percent by volume of the lubricant blend composition.

5. The lubricant blend composition of claim 1 , wherein the first lubricant is present at or about 85 to at or about 90 percent by volume of the lubricant blend composition, and the second lubricant is present at or about 10 to at or about 15 percent by volume of the lubricant blend composition.

6. A fluid for a vapor compression system, comprising
the lubricant blend composition of claim 1 , wherein the refrigerant with which the lubricant blend composition is suitable for mixing is present; and
the refrigerant with which the lubricant blend composition is suitable for mixing is a refrigerant blend including 1,1,1,4,4,4-hexafluorobutene (Z) as a first refrigerant and 1,2-dichloroethylene (E) as a second refrigerant.

7. The fluid of claim 6 , wherein the vapor compression system is a fluid chiller for a heating, ventilation, air conditioning, and refrigeration (HVACR) application, and the fluid chiller includes a centrifugal compressor.

8. The fluid of claim 6 , wherein the refrigerant blend includes, by weight of the refrigerant blend, the first refrigerant at or about 60 to at or about 90 percent by weight and the second refrigerant at or about 10 to at or about 40 percent by weight.

9. The fluid of claim 6 , wherein the refrigerant blend includes, by weight of the refrigerant blend, the first refrigerant at or about 70 to at or about 90 percent by weight and the second refrigerant at or about 10 to at or about 30 percent by weight.

10. The fluid of claim 6 , wherein the refrigerant blend includes, by weight of the refrigerant blend, the first refrigerant at or about 80 to at or about 90 percent by weight and the second refrigerant at or about 10 to at or about 20 percent by weight.

11. The fluid of claim 6 , wherein the refrigerant blend includes, by weight of the refrigerant blend, the first refrigerant at or about 75 to at or about 80 percent by weight and the second refrigerant at or about 20 to at or about 25 percent by weight.

12. A vapor compression system, including
a compressor;
a condenser;
an evaporator;
an expansion device; and
the lubricant blend composition of claim 1 which is blended with the refrigerant with which the lubricant blend composition is suitable for mixing.

13. The vapor compression system of claim 12 , wherein the vapor compression system is implemented as a fluid chiller for a heating, ventilation, air conditioning, and refrigeration (HVACR) application.

14. The vapor compression system of claim 13 , wherein the fluid chiller includes a centrifugal compressor.

15. A method of retrofitting a vapor compression system, comprising:
removing an existing fluid in the vapor compression system, the existing fluid includes a refrigerant and lubricant mixture;
replacing the existing fluid in the vapor compression system with a replacement fluid, the replacement fluid includes the lubricant blend composition of claim 1 and the refrigerant with which the lubricant blend composition is suitable for mixing; and
confirming an operating range of the vapor compression system with the replacement fluid.

16. A method of reducing the solubility of a refrigerant in a lubricant blend, comprising:
selecting the lubricant blend composition of claim 1 to be included as a mixture with a selected refrigerant of the refrigerant with which the lubricant blend composition is suitable for mixing;
confirming a miscibility of the lubricant blend composition and the selected refrigerant when mixed together over a desired operating range of the vapor compression system;
confirming a viscosity of the lubricant blend composition and the selected refrigerant when mixed together over the desired operating range of the vapor compression system.

Assignees

• Trane Int Inc

Inventors

• Majurin Julie A
• Strange Daniel A
• Steinke Daryl Dean

Classifications

• C10M2209/1055

  used as base material · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2020/101

  Containing Hydrofluorocarbons · CPC title

• C10M2209/1023

  used as base material · CPC title

• C10N2040/30

  Refrigerators lubricants {or compressors lubricants} · CPC title