Waterborne coating composition

Patent metadata

Field	Value
Publication number	US-11084953-B2
Application number	US-202016750049-A
Country	US
Kind code	B2
Filing date	Jan 23, 2020
Priority date	Mar 25, 2011
Publication date	Aug 10, 2021
Grant date	Aug 10, 2021

Abstract

The invention relates to a method of making an aqueous coating composition comprising a blend of at least a first aqueous polymer dispersion and a second aqueous polymer dispersion comprising a film-forming second polymer wherein the first aqueous polymer dispersion comprises a first polymer having a number average molecular weight, Mn, of from 2000 to 120000, an acid value of 30 to 150 mg KOH/g, a glass transition temperature Tg of at least 20° C. as calculated with the Fox formula, and an ethylene-oxide content of from 1 to 20 wt %, the method comprising blending an aqueous dispersion of the first polymer having a solids content of 25 to 50 wt % and a pH of 4.5 to 8.0 with an aqueous dispersion of the second polymer having a solids content of 25 to 55 wt % and a pH of 4.5 to 8.0.

First claim

What is claimed is:

1. A method of making an aqueous coating composition comprising a blend of at least a first aqueous polymer dispersion and a second aqueous polymer dispersion comprising a film-forming second polymer
wherein the first aqueous polymer dispersion comprises a first polymer having a number average molecular weight; Mn, of from 2000 to 120000 determined by gel permeation chromatography using a mixture of tetrahydrofuran and acetic acid as eluent, an acid value of 30 to 150 mg KOH/g, a glass transition temperature Tg of at least 20° C. as calculated with the Fox formula, and a ethylene-oxide content of from 1 to 20 wt %, and is obtained by free radical polymerization of a monomer mixture comprising:
a) 5 to 20 wt % acid functional ethylenically unsaturated monomers or precursors thereof or ethylenically unsaturated monomers comprising ionic group precursors;
b) 5 to 25 wt % ethylenically unsaturated monomers containing a polyethylene glycol or mono alkoxy polyethylene glycol moiety;
c) up to 90 wt % of non-ionic ethylenically unsaturated monomers other than a) or h);
d) 0 to 10 wt % ethylenically unsaturated monomers with a functional group for crosslinking; and
e) 0 to 10 wt % of chain transfer agents;
wherein the sum of a) to e) is 100 wt %,
the method comprising blending an aqueous dispersion of the first polymer having a solids content of 25 to 50 wt % and a pH of 4.5 to 8.0 with an aqueous dispersion of the second polymer having a solids content of 25 to 55 wt % and a pH of 4.5 to 8.0.

2. The method of claim 1 wherein the film forming second polymer in the second aqueous polymer dispersion is a vinyl polymer, polyurethane or alkyd or combinations thereof.

3. The method of claim 1 wherein the second polymer is an aqueous vinyl polymer dispersion bearing carbonyl groups for cross-linking with a carbonyl reactive cross-linker or an auto-oxidisable organic polymer containing unsaturated fatty acid residues.

4. The method of claim 1 , wherein the second polymer is an auto-oxidisable polyurethane containing unsaturated fatty acid residues or an alkyd- or urethane modified alkyd emulsion.

5. The method of claim 1 wherein the weight based on the solids content of the first polymer to the second polymer in the aqueous coating composition is 10/90 to 70/30.

6. The method of claim 1 wherein the aqueous coating composition has a pH from 4.5 to 8.0.

7. The method of claim 1 wherein the second polymer has a weight average molecular weight, Mw, of from 20,000 to 2,000,000 g/mol as measured by gel permeation chromatography using a mixture of tetrahydrofuran and acetic acid.

8. The method of claim 1 wherein the second polymer has a glass transition temperature Tg of from −30° C. to 80° C.

9. The method of claim 1 wherein the first polymer and second polymer have (meth)acryloyl, oxidative or acetoacetoxy functional groups for co-crosslinking.

10. The method of claim 1 wherein the aqueous coating composition comprises less than 20 wt % volatile organic solvent.

11. The method of claim 1 further comprising addition of one or more components chosen from the group consisting oil up to 20 wt % of isocyanate cross linker;
up to 20 wt % of polyhydrazide cross linker;
up to 10 wt % of a silane cross linker;
up to 10 wt % of an (meth)acryloyl oligomer; and
up to 50 wt % of an aqueous polymer dispersion different from the first and second polymer dispersion.

12. The method according to claim 1 wherein the first polymer dispersion is obtained by free radical polymerization of the monomer mixture in the presence of at least one free-radical initiator and at least one surfactant, wherein the surfactant is a reactive surfactant comprising a free radically reactive double bond.

13. The method according to claim 1 wherein the first polymer dispersion is obtained by free radical polymerization of the monomer mixture in the presence of at least one free-radical initiator and at least one surfactant; wherein the surfactant is a reactive surfactant comprising a free radically reactive double bond having a general structure M+.—OOC—CH═CHCOOR, RO—(CH2-CH2-O)n-R1 or RO—(CH2-CH2-O)n-X or blends thereof, wherein R1 is an alkyl or hydrogen group, wherein X is an anionic group, and wherein R is an organic group comprising: an allylic or maleic free radically reactive double bond and an alkyl, aryl or aralkyl group containing at least 8 carbons; and n is an integer from 0 to 50 and M+ is Na+, K+, Li+, NH4+ or a protonated or quaternary amine.

14. The method according to claim 1 wherein the monomer mixture comprises ionic ethylenically unsaturated monomers or precursors a) comprising one or more groups chosen from the group consisting of carboxylic acid groups, carboxylic acid precursor groups, sulphonic acid groups and phosphonic acid groups.

15. The method according to claim 1 wherein the monomer mixture comprises ethylenically unsaturated monomers containing polyethylene oxide b) of the general formula R 3 —O—(CH2-CH2-O)n-R2, wherein R3 is acryl or methacryl; R2 is H or alkyl, n is an integer from 1 to 35.

16. The method according to claim 1 wherein the monomer mixture comprises one or more non-ionic ethylenically unsaturated monomers c) chosen from the group consisting of:
i. up to 100 wt % styrene and/or styrene derivatives;
ii. up to 100 wt % of one or more non-ionic(meth)acrylic monomers;
iii. up to 25 wt % vinyl monomers containing oxidative crosslinking groups;
iv. up to 10 wt % vinyl monomers containing self-crosslinkable groups;
v. up to 15 wt % vinyl monomers containing hydroxyl groups and;
vi. up to 5 wt % vinyl monomers containing wet adhesion promoters wherein the sum of the weight of monomers i-vi=100 wt % of non-ionic ethylenically unsaturated monomers c).

17. The method according to claim 1 wherein the first polymer has a number average molecular weight (Mn) of 4,000 to 12,000 g/mol and has a polydispersity of 1.2 to 3.

18. The method according to claim 1 wherein the acid functional groups of the first polymer are neutralized to an alpha value of from 0.05 to 0.70 and wherein the pH is from 6.0 to 8.0.

19. The method according to claim 1 wherein the acid functional groups of the first polymer are neutralized to an alpha value of from 0.10 to 0.25 and wherein the pH is from 6.5 to 7.5.

20. The method according to claim 1 wherein the pH difference of the first and second polymer dispersion is less than 2.

21. The method according to claim 16 wherein the monomer mixture comprises iv) up to 10 wt % vinyl monomers containing self-crosslinkable groups, which are ketone functional monomers.

22. The method according to claim 17 wherein the first polymer has a number average molecular weight (Mn) of 5,000 to 10,000 g/mol and has a polydispersity of 1.5 to 2.5.

Assignees

• Allnex Netherlands Bv

Inventors

• Akkerman Jaap Michiel
• Mestach Dirk Emiel Paula
• Pilaszek Wincenty Lambertus Stanislaw
• Adolphs Rob

Classifications

• C08F220/286

  and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate · CPC title

• C08F220/1812

  C12-(meth)acrylate, e.g. lauryl (meth)acrylate · CPC title

• C08F220/1804 Primary

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title

• C09D133/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08G18/348

  Hydroxycarboxylic acids · CPC title