Modified ultra-stable Y (USY) zeolite catalyst for deolefinization of hydrocarbon streams

Patent metadata

Field	Value
Publication number	US-11078431-B2
Application number	US-201916715555-A
Country	US
Kind code	B2
Filing date	Dec 16, 2019
Priority date	Dec 16, 2019
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

The present disclosure relates to a process for the deolefinization of hydrocarbon streams through an aromatic alkylation reaction by olefins, using a catalyst containing a framework-substituted zirconium and/or titanium and/or hafnium-modified ultra-stable Y (USY) type zeolite.

First claim

What is claimed is:

1. A process for deolefinization of a hydrocarbon feed containing aromatic compounds and olefins, the process comprising the step of contacting the hydrocarbon feed with a catalyst containing a framework-substituted ultra-stable Y (USY)-type zeolite in which a portion of aluminum atoms constituting a zeolite framework thereof is substituted with zirconium atoms and/or titanium and/or hafnium atoms, wherein the olefins alkylate the aromatic compounds in the hydrocarbon feed, thereby producing a deolefinated hydrocarbon product.

2. The process according to claim 1 , wherein the framework-substituted USY-type zeolite in the catalyst comprises zirconium atoms and titanium atoms.

3. The process according to claim 1 , wherein the framework-substituted USY-type zeolite in the catalyst comprises from about 0.1 to about 5% by mass zirconium and/or titanium and/or hafnium atoms, each calculated as the oxide basis.

4. The process according to claim 1 , wherein the framework-substituted USY-type zeolite in the catalyst further includes a support comprising inorganic oxides selected from the group consisting of alumina, silica-alumina and combinations thereof.

5. The process according to claim 1 , wherein the hydrocarbon feed comprises an aromatic rich hydrocarbon oil having a boiling point range of about 15° C. to about 500° C.

6. The process according to claim 1 , wherein the contacting is operated at reaction temperature range of about 50° C. to about 250° C., a pressure of about 1 to about 30 bars and a liquid hourly space velocity (LHSV) of about 0.5 to about 50 h −1 .

7. The process according to claim 1 , wherein the deolefinated product contains less than about 500 ppm sulfur.

8. The process according to claim 1 , wherein the deolefinated hydrocarbon product containing less than about 100 ppm nitrogen.

9. The process according to claim 1 , wherein the hydrocarbon feed contains greater than about 1 wt % olefins.

10. The process according to claim 1 , wherein the deolefinated hydrocarbon product contains less than about 10 wt % olefins.

11. The process according to claim 1 , wherein the hydrocarbon feed is deolefinated at least about 95 wt %.

12. The process according to claim 1 , wherein the deolefinated hydrocarbon product has bromine index less than about 60,000.

13. The process according to claim 1 , wherein the aromatic compounds in the hydrocarbon feed contains benzene and alkylated benzenes.

14. The process according to claim 13 , wherein the aromatic compounds in the hydrocarbon feed comprise C6 to C10 aromatic compounds.

15. The process according to claim 1 , wherein the deolefinated hydrocarbon product comprises less olefin hydrocarbons and more alkylated aromatic compounds as compared with the hydrocarbon feed.

16. The process according to claim 1 , wherein the hydrocarbon feed is fluid catalytic cracking (FCC) naphtha, coking naphtha or other naphtha coming from the cracking units in which no hydrogen is used.

17. The process according to claim 1 , wherein the catalyst further includes an active metal selected from the group consisting of IUPAC Group 7 to 11 metal of the Periodic Table.

18. The process according to claim 1 , wherein the deolefinated product contains less than about 10 ppm sulfur.

19. The process according to claim 1 , wherein the deolefinated product contains less than about 0.5 ppm sulfur.

20. The process according to claim 1 , wherein the deolefinated hydrocarbon product containing less than about 10 ppm nitrogen.

21. The process according to claim 1 , wherein the deolefinated hydrocarbon product containing less than about 0.5 ppm nitrogen.

22. The process according to claim 1 , wherein the deolefinated hydrocarbon product contains less than about 1 wt % olefins.

23. The process according to claim 1 , wherein the deolefinated hydrocarbon product contains less than about 0.5 wt % olefins.

24. The process according to claim 1 , wherein the hydrocarbon feed is deolefinated at least about 99 wt %.

25. The process according to claim 1 , wherein the hydrocarbon feed is deolefinated at least about 99.99 wt %.

26. The process according to claim 1 , wherein the deolefinated hydrocarbon product has bromine index less than about 10,000.

27. The process according to claim 1 , wherein the deolefinated hydrocarbon product has bromine index less than about 1,000.

28. A process for alkylating aromatic compounds in a hydrocarbon feed containing aromatic compounds and olefins, the process comprising the step of contacting the hydrocarbon feed with a catalyst containing framework-substituted ultra-stable Y (USY)-type zeolite in which a portion of aluminum atoms constituting a zeolite framework thereof is substituted with zirconium atoms and/or titanium and/or hafnium atoms, wherein the olefins alkylate the aromatic compounds in the hydrocarbon feed, thereby producing alkylated aromatic compounds.

Assignees

• Saudi Arabian Oil Co
• Jgc Catalysts & Chemicals Ltd
• Japan Coop Center Petroleum

Inventors

• Koseoglu Omer Refa
• Hodgkins Robert Peter
• Watabe Mitsunori
• Kagawa Tomoyasu
• Uchida Koji

Classifications

• C10G35/24

  Controlling or regulating of reforming operations · CPC title

• C10G35/065 Primary

  containing crystalline zeolitic molecular sieves, other than aluminosilicates · CPC title

• C10G29/20 Primary

  Organic compounds not containing metal atoms · CPC title

• C07C2529/16

  containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• C07C2529/08

  of the faujasite type, e.g. type X or Y · CPC title