Methods of catalytic hydrogenation for ethylene glycol formation
US-2015375209-A1 · Dec 31, 2015 · US
US9376325B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9376325-B2 |
| Application number | US-201313922328-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 20, 2013 |
| Priority date | Sep 10, 2007 |
| Publication date | Jun 28, 2016 |
| Grant date | Jun 28, 2016 |
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A new configuration of ZSM-5 is provided whereby the crystals have a higher average silica to alumina ratio at the edges of each crystallite than in the center as determined from a narrow slit line scan profile obtained from SEM/EDX or TEM/EDX elemental analysis. Such ZSM-5 crystals are obtained by a preparation process using L-tartaric acid. The new configuration ZSM-5 provides significantly reduced xylene losses in ethylbenzene dealkylation, especially when combined with silica as binder, and one or more hydrogenation metals selected from platinum, tin, lead, silver, copper, and nickel.
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That which is claimed is: 1. An ethylbenzene dealkylation process, which process comprises: contacting, in the presence of hydrogen, a feedstock which comprises ethylbenzene with a catalyst composition, comprising ZSM-5 crystals, comprising a ZSM-5 crystallite having an average SAR at the edge of the crystallite and an average SAR at the centre of the crystallite, as determined via SEM/EDX or TEM/EDX elemental analysis, wherein the average SAR at the edge of the crystallite is high…
Operations & Transport · mapped topic
Operations & Transport · mapped topic
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