Solar thermochemical processing system and method

Patent metadata

Field	Value
Publication number	US-11077418-B2
Application number	US-201815950068-A
Country	US
Kind code	B2
Filing date	Apr 10, 2018
Priority date	Jul 26, 2011
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

A solar thermochemical processing system is disclosed. The system includes a first unit operation for receiving concentrated solar energy. Heat from the solar energy is used to drive the first unit operation. The first unit operation also receives a first set of reactants and produces a first set of products. A second unit operation receives the first set of products from the first unit operation and produces a second set of products. A third unit operation receives heat from the second unit operation to produce a portion of the first set of reactants.

First claim

We claim:

1. A method of storing solar energy, the method comprising:
providing reactants to a first endothermic reactor to produce a first set of products, wherein the first endothermic reactor receives at least some concentrated solar energy as a heat source; further reacting the first set of products in a first exothermic reactor to produce a second set of products, wherein the heat of the reaction from the first exothermic reactor is provided to the first endothermic reactor to supplement the concentrated solar energy;
wherein the first endothermic reactor comprises a methane steam reforming catalyst and wherein the reactants comprise methane and steam, wherein the first set of products comprises syngas; wherein the first exothermic reactor comprises a methanol synthesis reactor;
wherein the step in which the heat of reaction from the first exothermic reactor is provided to the first endothermic reaction comprises preheating the reactants using heat from the methanol synthesis reactor to vaporize water to form steam and then providing the steam to the first endothermic reactor; and
separating the second set of products to store fuel.

2. The method of claim 1 wherein the separating comprises recovering methanol with unreacted syngas.

3. The method of claim 2 further comprising providing at least a portion of the second set of products as fuel for combustion; and wherein the fuel provides heat for a heat engine.

4. The method of claim 2 further comprising providing at least a portion of the second set of products to a fuel cell.

5. The method of claim 2 further comprising cooling the first set of products and then providing the first set of products to the first exothermic reactor.

6. A method of storing solar energy, the method comprising:
providing reactants to a first endothermic reactor to produce a first set of products, wherein the first endothermic reactor receives at least some concentrated solar energy as a heat source; further reacting the first set of products in a first exothermic reactor to produce a second set of products, wherein the heat of the reaction from the first exothermic reactor is provided to the first set of reactants; and further wherein the endothermic reactor is a radial reactor comprising outward flowing channels comprising an inlet at the center of the reactor and flow in a radial direction toward outlets at the periphery of the reactor.

7. The method of claim 6 further comprising a vaporizer for receiving heat from the first exothermic reactor to produce a portion of the first set of reactants.

8. The method of claim 7 wherein the first exothermic reactor provides heat to the vaporizer and produces syngas and a liquid hydrocarbon product.

9. The method of claim 8 wherein the syngas and liquid hydrocarbon product are passed to a separator where a liquid hydrocarbon product is recovered.

10. The method of claim 6 further comprising the counterflow microchannel recuperative heat exchanger with a minimum exergetic efficiency of 85% and a heat transfer power density of about 10 watts/cm 2 .

11. The method of claim 1 wherein the reactants comprise water and methane.

12. The method of claim 1 wherein the first exothermic reactor comprises a methanol synthesis reactor.

13. The method of claim 12 wherein the fuel comprises methanol.

14. The method of claim 1 wherein, prior to the step of further reacting, the first set of reactants are cooled in a heat exchanger.

15. The method of claim 6 comprising inward flowing channels adjacent the outward flowing channels which enter at the periphery and exit toward the center of the reactor.

16. The method of claim 15 further comprising a passive structure adapted to provide passive flow control within the reactor; wherein the passive structure comprises an orifice cover blocking an outlet orifice of the outward flowing channels; wherein the orifice cover comprises a material having a higher or lower thermal expansion as compared with the outward flowing channels.

17. The method of claim 6 wherein methanol or hydrogen is synthesized in the first exothermic reactor in a methanol synthesis reaction or in a reverse water gas shift reaction that provides heat to vaporize water in a vaporizer.

18. The method of claim 15 wherein half of the reactants enter at the center of the reactor and flow through catalyst to the periphery of the reactor and the other half of the reactants enter at the periphery and flow toward the center of the reactor.

19. The method of claim 17 wherein the method further comprises a step of vapor compression, sorption, or thermoelectric heat pumping that provides additional heat to the vaporizer.

Assignees

• Battelle Memorial Institute

Inventors

• Wegeng Robert S
• Humble Paul H
• Krishnan Shankar
• Leith Steven D
• Palo Daniel R
• Dagle Robert A

Classifications

• Y02P20/133

  Renewable energy sources, e.g. sunlight · CPC title

• Y10T137/8593

  Systems · CPC title

• F22B1/006

  using solar heat · CPC title

• C10G2/30

  from carbon monoxide with hydrogen · CPC title

• C10K3/04

  reducing the carbon monoxide content {, e.g. water-gas shift [WGS]} · CPC title