Base stocks and lubricant compositions containing same

Patent metadata

Field	Value
Publication number	US-11060040-B2
Application number	US-201916529319-A
Country	US
Kind code	B2
Filing date	Aug 1, 2019
Priority date	Dec 29, 2016
Publication date	Jul 13, 2021
Grant date	Jul 13, 2021

Abstract

Systems and methods are provided for block operation during lubricant and/or fuels production from deasphalted oil. During “block” operation, a deasphalted oil and/or the hydroprocessed effluent from an initial processing stage can be split into a plurality of fractions. The fractions can correspond, for example, to feed fractions suitable for forming a light neutral fraction, a heavy neutral fraction, and a bright stock fraction, or the plurality of fractions can correspond to any other convenient split into separate fractions. The plurality of separate fractions can then be processed separately in the process train (or in the sweet portion of the process train) for forming fuels and/or lubricant base stocks. This can allow for formation of unexpected base stock compositions.

First claim

The invention claimed is:

1. A lubricant base stock composition comprising a viscosity index of 80 or more; a saturates content of 95 wt % or more; a sulfur content of 300 wppm or less; a kinematic viscosity at 100° C. of 8.5 cSt to 15 cSt; 2.8 wt % or less of 4+-ring naphthenes; 9.0 epsilon carbon atoms or less per 100 carbon atoms in the composition; and 0.82 or less terminal and pendant propyl groups per 100 carbon atoms in the composition.

2. The composition of claim 1 , further comprising a cycloparaffin performance ratio of 1.20 to 1.34.

3. The composition of claim 1 , further comprising 74.0 wt % or more of total naphthenes relative to the total weight of saturates and aromatics in the composition.

4. The composition of claim 1 , further comprising 1.6 wt % or less of 4-ring naphthenes relative to the total weight of saturates and aromatics in the composition.

5. The composition of claim 1 , wherein the composition comprises 2.6 wt % or less of 4+-ring naphthenes relative to the total weight of saturates and aromatics in the composition; or wherein the composition comprises 10.0 wt % or less of 3+-ring naphthenes; or a combination thereof.

6. A lubricant base stock composition comprising a viscosity index of 80 or more; a saturates content of 98 wt % or more; a sulfur content of 300 wppm or less; a kinematic viscosity at 100° C. of 3.5 cSt to 6.5 cSt; a total naphthenes content of 81.0 wt % or more; 41.0 wt % or more of 1-ring naphthenes; and 8 epsilon carbon atoms or less per 100 carbon atoms in the composition.

7. The composition of claim 6 , wherein the composition further comprises 9.0 wt % or less of 3-ring naphthenes relative to the total weight of saturates and aromatics in the composition; or wherein the composition further comprises 1.9 wt % or less of 4-ring naphthenes; or a combination thereof.

8. The composition of claim 6 , wherein the composition comprises 83.0 wt % or more of naphthenes relative to the total weight of saturates and aromatics in the composition.

9. The composition of claim 6 , wherein the composition comprises 43.0 wt % or more of 1-ring naphthenes relative to the total weight of saturates and aromatics in the composition.

10. The composition of claim 6 , wherein the composition further comprises 2.9 wt % or less of 4+-ring naphthenes relative to the total weight of saturates and aromatics in the composition; or wherein the composition further comprises 11.0 wt % or less of 3+-ring naphthenes relative to the total weight of saturates and aromatics in the composition; or a combination thereof.

11. The composition of claim 6 , further comprising 16.0 wt % or less of multi-branched paraffins relative to the total weight of saturates and aromatics in the composition.

12. The composition of claim 6 , wherein the composition comprises a kinematic viscosity at 100° C. of 4.0 cSt to 6.0 cSt.

13. The composition of claim 6 , wherein the composition further comprises a pour point of −12° C. or less.

14. The composition of claim 6 , further comprising at least one additive to form a formulated lubricant.

15. A lubricant base stock composition comprising a viscosity index of 80 or more; a saturates content of 98 wt % or more; a sulfur content of 300 wppm or less; a kinematic viscosity at 100° C. of 3.5 cSt to 6.5 cSt; 1.8 wt % or less of 4-ring naphthenes; 0.9 wt % or less of 5-ring naphthenes; and 8.0 epsilon carbon atoms or less per 100 carbon atoms in the composition.

16. The composition of claim 15 , further comprising 0.5 wt % or less of monomethyl paraffins relative to a weight of saturates and aromatics in the composition.

17. The composition of claim 15 , wherein the composition comprises 1.6 wt % or less of 4-ring aromatics relative to a weight of saturates and aromatics in the composition; or wherein the composition comprises 0.6 wt % or less of 5-ring aromatics relative to a weight of saturates and aromatics in the composition; or a combination thereof.

18. The composition of claim 15 , wherein the composition comprises 2.0 wt % or less of 4+-ring aromatics relative to a weight of saturates and aromatics in the composition; or wherein the composition comprises 0.7 wt % or less of 5+-ring aromatics relative to a weight of saturates and aromatics in the composition; or a combination thereof.

19. The composition of claim 15 , wherein the composition comprises 45.0 wt or more of 1-ring naphthenes relative to the total weight of saturates and aromatics in the composition.

20. The composition of claim 15 , wherein the composition comprises 81.0 wt % or more of naphthenes relative to the total weight of saturates and aromatics in the composition.

21. The composition of claim 1 , further comprising dimethyl paraffins.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Yeh Lisa I-Ching
• Shukla Yogi V
• Watkins-Curry Pilanda
• Henderson Camden N
• Fruchey Kendall S
• Carroll Michael B
• Diebold Adrienne R

Classifications

• B01D3/14

  Fractional distillation {or use of a fractionation or rectification column} · CPC title

• C10M101/02

  Petroleum fractions · CPC title

• C10G45/38

  in combination with chromium, molybdenum or tungsten metals, or compounds thereof · CPC title

• C10G65/12 Primary

  including cracking steps and other hydrotreatment steps · CPC title

• C10N2070/00

  Specific manufacturing methods for lubricant compositions · CPC title