Zeolitic catalytic conversion of alcohols to olefins

Patent metadata

Field	Value
Publication number	US-11053181-B2
Application number	US-201916530397-A
Country	US
Kind code	B2
Filing date	Aug 2, 2019
Priority date	Aug 9, 2018
Publication date	Jul 6, 2021
Grant date	Jul 6, 2021

Abstract

A catalyst composition for converting an alcohol to olefins, the catalyst composition comprising the following components: (a) beta zeolite; (b) at least one element selected from the group consisting of zinc, magnesium, calcium, strontium, sodium, and potassium; and (c) at least one element selected from the group consisting of hafnium, yttrium, zirconium, tantalum, niobium, and tin; wherein the components (b) and (c) are independently within or on a surface of said beta zeolite. The catalyst may also further include component (d), which is copper or silver. Also described herein is a method for converting an alcohol to one or more olefinic compounds, the method comprising contacting the alcohol with a catalyst at a temperature of at least 100° C. and up to 500° C. to result in the alcohol being converted to the one or more olefinic compounds.

First claim

What is claimed is:

1. A catalyst composition for converting an alcohol to olefins, the catalyst composition comprising the following components:
(a) beta zeolite;
(b) at least one element selected from the group consisting of zinc, magnesium, calcium, strontium, sodium, and potassium; and
(c) at least one element selected from the group consisting of hafnium, yttrium, zirconium, tantalum, niobium, and tin;
wherein the components (b) and (c) are independently within said beta zeolite or on a surface of said beta zeolite.

2. The catalyst composition of claim 1 , further comprising component (d), which is copper or silver.

3. The catalyst composition of claim 1 , wherein said beta zeolite has a silicon to aluminum ratio of at least 10.

4. The catalyst composition of claim 1 , wherein said component (b) comprises zinc.

5. The catalyst composition of claim 1 , wherein said component (c) comprises hafnium or yttrium.

6. The catalyst composition of claim 1 , wherein said component (b) comprises zinc and said component (c) comprises hafnium or yttrium.

7. The catalyst composition of claim 2 , wherein at least one of said copper or silver is on a surface of said beta zeolite.

8. The catalyst composition of claim 7 , wherein zinc and at least one of said copper or silver are on a surface of said beta zeolite.

9. The catalyst composition of claim 1 , wherein the catalyst composition includes copper, hafnium, and zinc independently within said beta zeolite or on a surface of said beta zeolite.

10. The catalyst composition of claim 1 , wherein said catalyst is in admixture with a second catalyst capable of converting said alcohol to olefins, the second catalyst comprising metal oxide particles having on their surfaces copper and at least one element selected from the group consisting of platinum, palladium, and nickel, and wherein said metal oxide is selected from the group consisting of aluminum oxide, zirconium oxide, cerium oxide, titanium oxide, silicon oxide, and zinc oxide.

11. A method for converting an alcohol to one or more olefinic compounds, the method comprising contacting the alcohol with a catalyst at a temperature of at least 100° C. and up to 500° C. to result in said alcohol being converted to said one or more olefinic compounds, wherein said catalyst comprises the following components:
(a) beta zeolite;
(b) at least one element selected from the group consisting of zinc, magnesium, calcium, strontium, sodium, and potassium; and
(c) at least one element selected from the group consisting of hafnium, yttrium, zirconium, tantalum, niobium, and tin;
wherein the components (b) and (c) are independently within said beta zeolite or on a surface of said beta zeolite.

12. The method of claim 11 , wherein said alcohol has one to four carbon atoms.

13. The method of claim 11 , wherein said alcohol is ethanol.

14. The method of claim 11 , wherein said olefinic compounds are comprised of butenes and 1,3-butadiene.

15. The method of claim 14 , wherein said olefinic compounds include butenes produced in at least 40% yield.

16. The method of claim 14 , wherein said olefinic compounds include 1,3-butadiene produced in at least 40% yield.

17. The method of claim 11 , wherein said catalyst further comprises component (d), which is copper or silver.

18. The method of claim 11 , wherein said beta zeolite has a silicon to aluminum ratio of at least 10.

19. The method of claim 11 , wherein said component (b) comprises zinc.

20. The method of claim 11 , wherein said component (c) comprises hafnium or yttrium.

21. The method of claim 11 , wherein said component (b) comprises zinc and said component (c) comprises hafnium or yttrium.

22. The method of claim 17 , wherein at least one of said copper or silver is on a surface of said beta zeolite.

23. The method of claim 22 , wherein zinc and at least one of said copper or silver are on a surface of said beta zeolite.

24. The method of claim 11 , wherein the catalyst composition includes copper, hafnium, and zinc independently within said beta zeolite or on a surface of said beta zeolite.

25. The method of claim 11 , wherein said catalyst is in admixture with a second catalyst capable of converting said alcohol to said one or more olefinic compounds, the second catalyst comprising metal oxide particles having on their surfaces copper and at least one element selected from the group consisting of platinum, palladium, and nickel, and wherein said metal oxide is selected from the group consisting of aluminum oxide, zirconium oxide, cerium oxide, titanium oxide, silicon oxide, and zinc oxide.

26. The method of claim 25 , wherein the method converts the alcohol to said one or more olefinic compounds in the absence of hydrogen.

27. The method of claim 11 , wherein the method further comprises converting the olefinic compounds to a synthetic fossil fuel by contacting said olefinic compounds, at a temperature of at least 100° C. and up to 500° C., to an additional catalyst capable of converting the olefinic compounds to a synthetic fossil fuel.

Assignees

• Ut Battelle Llc

Inventors

• Li Zhenglong

Classifications

• Y02P30/40

  Ethylene production · CPC title

• Y02P30/20

  using bio-feedstock · CPC title

• B01J2229/16

  to increase the Si/Al ratio; Dealumination · CPC title

• B01J29/7415 Primary

  Zeolite Beta · CPC title

• B01J29/7007

  Zeolite Beta · CPC title