Zeolitic catalytic conversion of alcohols to hydrocarbons

Patent metadata

Field	Value
Publication number	US-9938467-B2
Application number	US-201615357039-A
Country	US
Kind code	B2
Filing date	Nov 21, 2016
Priority date	Jun 15, 2011
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.

First claim

What is claimed is:

1. A method for converting an alcohol to a mixture of hydrocarbon compounds useful as a fuel or as a blendstock component of a fuel, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein said alcohol can be produced by a fermentation process and is selected from the group consisting of ethanol, butanol, isobutanol, and combinations thereof and is a component of an aqueous solution in a concentration of no more than about 20%, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said mixture of hydrocarbon compounds, wherein said mixture of hydrocarbon compounds contains hydrocarbon compounds containing at least four carbon atoms, and at least a portion of said hydrocarbon compounds containing at least four carbon atoms are alkanes, wherein said mixture of hydrocarbon compounds substantially corresponds to a fuel selected from gasoline, kerosene, diesel, and jet propellant.

2. The method of claim 1 , wherein said alcohol comprises ethanol.

3. The method of claim 1 , wherein said concentration is no more than about 10%.

4. The method of claim 1 , wherein said alcohol is produced by a fermentation process.

5. The method of claim 4 , wherein said alcohol is a component of a fermentation stream when contacted with said metal-loaded zeolite catalyst.

6. The method of claim 4 , wherein said fermentation process produces said alcohol from a biomass source.

7. The method of claim 6 , wherein said biomass source comprises lignocellulosic matter.

8. The method of claim 4 , wherein said fermentation process produces said alcohol from a plant-based source of sugars.

9. The method of claim 1 , wherein said temperature is at least 200° C. and up to 500° C.

10. The method of claim 1 , wherein said temperature is at least 350° C. and up to 500° C.

11. The method of claim 1 , wherein said temperature is at least 350° C. and up to 450° C.

12. The method of claim 1 , wherein said temperature is at least 375° C. and up to 425° C.

13. The method of claim 1 , wherein said metal is selected from alkali metal, alkaline earth metal, copper, iron, vanadium, zinc, titanium, cadmium, gallium, indium, and combinations thereof.

14. The method of claim 1 , wherein said metal is selected from copper, iron, and vanadium.

15. The method of claim 1 , wherein said zeolite comprises a pentasil zeolite.

16. The method of claim 15 , wherein said pentasil zeolite comprises ZSM5.

17. The method of claim 1 , wherein said method is integrated with a fermentation process, wherein said fermentation process produces said alcohol as a component of a fermentation stream, and said fermentation stream is contacted with said metal-loaded zeolite catalyst.

18. The method of claim 1 , wherein said method is integrated with a biomass reactor that includes a fermentation process, wherein said fermentation process produces said alcohol as a component of a fermentation stream, and said fermentation stream is contacted with said metal-loaded zeolite catalyst.

19. The method of claim 1 , wherein said method further comprises distilling said mixture of hydrocarbon compounds to obtain a fraction of said mixture of hydrocarbon compounds.

20. The method of claim 1 , wherein said alcohol is produced from a biomass source.

21. The method of claim 20 , wherein said biomass source comprises lignocellulosic matter.

22. The method of claim 20 , wherein said biomass source comprises starch or sugar.

23. The method of claim 1 , wherein the alcohol comprises n-butanol or isobutanol.

Assignees

• Ut Battelle Llc

Inventors

• Narula Chaitanya K
• Davison Brian H
• Keller Martin

Classifications

• C10G2400/04

  Diesel oil · CPC title

• B01J29/7861

  MRE-type, e.g. ZSM-48 · CPC title

• C10G2400/02

  Gasoline · CPC title

• B01J29/69

  containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• B01J29/072

  Iron group metals or copper · CPC title