Metal-air battery and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-11043709-B2
Application number	US-201916567029-A
Country	US
Kind code	B2
Filing date	Sep 11, 2019
Priority date	Oct 17, 2018
Publication date	Jun 22, 2021
Grant date	Jun 22, 2021

Abstract

A metal-air battery including an anode layer; a solid electrolyte layer; and a cathode layer directly contacting the solid electrolyte layer. The solid electrolyte layer and the cathode layer are a single unitary and indivisible body with no physical interlayer boundary between the solid electrolyte layer and the cathode layer. A portion of the cathode layer may be within the solid electrolyte layer. The cathode layer may protrude from the solid electrolyte layer. The method of manufacturing a metal-air battery may include forming a solid electrolyte layer on an anode layer and chemically reducing solid electrolyte in a part of the solid electrolyte layer.

First claim

What is claimed is:

1. A metal-air battery comprising:
an anode layer;
a solid electrolyte layer; and
a cathode layer directly contacting the solid electrolyte layer,
wherein the solid electrolyte layer and the cathode layer are a single unitary and indivisible body with no physical interlayer boundary between the solid electrolyte layer and the cathode layer, and
wherein the cathode layer comprises chemically reduced material of the solid electrolyte layer.

2. The metal-air battery of claim 1 , wherein a portion of the cathode layer is within the solid electrolyte layer.

3. The metal-air battery of claim 1 , wherein the cathode layer has a shape protruding from the solid electrolyte layer.

4. The metal-air battery of claim 3 , wherein a portion of the cathode layer is within the solid electrolyte layer.

5. The metal-air battery of claim 1 , wherein the cathode layer comprises a plurality of separated patterns.

6. The metal-air battery of claim 5 , wherein the plurality of separated patterns have a periodic arrangement.

7. The metal-air battery of claim 5 , wherein each of the plurality of separated patterns has a column shape or a cylindrical shape.

8. The metal-air battery of claim 7 , wherein the cylindrical shape comprises a single cylindrical shape or a double cylindrical shape.

9. The metal-air battery of claim 7 , wherein the cylindrical shape comprises a circular cylindrical shape or a non-circular cylindrical shape.

10. The metal-air battery of claim 1 , wherein the cathode layer is a single layer covering an entire upper surface of the solid electrolyte layer.

11. The metal-air battery of claim 1 , wherein the cathode layer has a zigzag shape on the solid electrolyte layer.

12. The metal-air battery of claim 1 , wherein the cathode layer comprises:
a first cathode layer; and
a second layer that is on and surrounds the first cathode layer.

13. The metal-air battery of claim 1 , wherein the cathode layer has a spiral plane shape.

14. The metal-air battery of claim 1 , wherein an electron conductivity of the cathode layer is greater than 10 −4 siemens per meter.

15. A method of manufacturing a metal-air battery, the method comprising:
disposing a solid electrolyte layer on an anode layer; and
changing a portion of the solid electrolyte layer into a cathode layer to manufacture the metal-air battery of claim 1 .

16. The method of claim 15 , wherein the changing of the portion of the solid electrolyte layer into the cathode layer comprises:
defining a region of the solid electrolyte layer; and
chemically reducing solid electrolyte in the defined region to change the portion of the solid electrolyte layer into the cathode layer.

17. The method of claim 16 , wherein the chemically reducing the solid electrolyte in the defined region comprises contacting the defined region with a reducing material layer that chemically reduces solid electrolyte in the solid electrolyte layer.

18. The method of claim 16 , wherein the chemically reducing the solid electrolyte in the defined region comprises heat treating the defined region under a hydrogen atmosphere.

19. The method of claim 15 , wherein the changing of the portion of the solid electrolyte layer into the cathode layer comprises:
disposing a protrusion in a region of the solid electrolyte layer; and
chemically reducing solid electrolyte in the protrusion.

20. The method of claim 19 , wherein the chemically reducing the solid electrolyte in the protrusion comprises contacting the protrusion with a reducing material layer that chemically reduces solid electrolyte in the solid electrolyte layer.

21. The method of claim 15 , wherein the changing of the portion of the solid electrolyte layer into the cathode layer comprises chemically reducing the solid electrolyte in a selected portion of an entire upper portion of the solid electrolyte layer, the entire upper portion comprising an upper surface of the solid electrolyte layer.

22. The method of claim 21 , further comprising dividing chemically reduced solid electrolyte in the upper portion into a plurality of patterns separated from each other.

23. The method of claim 21 , wherein the chemically reducing the solid electrolyte in the selected portion of the entire upper portion, comprising the upper surface, of the solid electrolyte layer comprises contacting the entire upper surface of the solid electrolyte layer with a reducing material layer.

24. The method of claim 21 , wherein the chemically reducing the solid electrolyte in the selected portion of the upper part, comprising the upper surface, of the solid electrolyte layer comprises heat treating the solid electrolyte layer under a hydrogen atmosphere.

25. The method of claim 22 , wherein the dividing comprises:
forming a mask on the chemically reduced upper portion of the solid electrolyte, the mask covering regions of the chemically reduced solid electrolyte corresponding to a plurality of patterns separated from each other;
exposing a remaining region of the chemically reduced solid electrolyte; and
etching the exposed part of the chemically reduced solid electrolyte.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Lee Hyunpyo
• Kwon Hyukjae
• Ma Sangbok
• Lee Heungchan
• Im Dongmin
• Choi Wonsung

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M12/06

  with one metallic and one gaseous electrode · CPC title

• H01M4/8663

  Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers · CPC title