Laminated glass article with determined modulus contrast and method for forming the same

Patent metadata

Field	Value
Publication number	US-11034134-B2
Application number	US-201615773981-A
Country	US
Kind code	B2
Filing date	Nov 4, 2016
Priority date	Nov 5, 2015
Publication date	Jun 15, 2021
Grant date	Jun 15, 2021

Abstract

A laminated glass article includes a glass core layer having a core modulus E core and a glass cladding layer adjacent to the core layer and having a cladding modulus E clad . E clad can be at least 5 GPa less than E core . A modulus ratio E core /E clad can be at least 1.08. The cladding layer can have a compressive stress resulting from a coefficient of thermal expansion (CTE) contrast between the core layer and the cladding layer and/or subjecting the laminated glass article to an ion exchange treatment to form an ion exchanged region at an outer surface of the cladding layer.

First claim

What is claimed is:

1. A laminated glass article comprising:
a glass core layer comprising a core modulus E core ; and
a glass cladding layer adjacent to the core layer and comprising a cladding modulus E clad that is at least 5 GPa less than E core ;
wherein the glass cladding layer comprises an alkali aluminosilicate glass and wherein:
the core layer comprises a core coefficient of thermal expansion CTE core ; and the cladding layer comprises a cladding coefficient of thermal expansion CTE clad that is greater than or equal to CTE core .

2. The laminated glass article of claim 1 , wherein the core layer comprises a liquidus viscosity of at least about 30 kP.

3. The laminated glass article of claim 1 , wherein a difference between CTE core and CTE clad is at most 60×10 −7 /° C.

4. The laminated glass article of claim 1 , wherein a difference between CTE core and CTE clad is greater than or equal to −1×10 −7 /° C.

5. The laminated glass article of claim 1 , wherein E core /E clad is at least 1.08.

6. The laminated glass article of claim 1 , wherein E clad is at least 12 GPa less than E core .

7. The laminated glass article of claim 1 , comprising an estimated retained strength with a 10 μm deep flaw formed therein of at least about 10% greater than a reference glass article comprising a reference core modulus and a reference cladding modulus that are equal to one another.

8. The laminated glass article of claim 1 , wherein the cladding layer comprises a compressive stress resulting at least in part from subjecting the laminated glass article to an ion exchange treatment to form an ion exchanged region at an outer surface of the cladding layer.

9. The laminated glass article of claim 1 , wherein the cladding layer comprises a first cladding layer and a second cladding layer, and the core layer is disposed between the first cladding layer and the second cladding layer.

10. The laminated glass article of claim 1 , wherein 1.08≤E core /E clad ≤1.77.

11. A laminated glass article according to claim 1 , wherein
a modulus ratio E core /E clad of at least 1.08; and
an estimated retained strength with a 10 μm deep flaw formed therein of at least about 10% greater than a reference glass article comprising a reference core modulus and a reference cladding modulus that are equal to one another.

12. The laminated glass article of claim 11 , further comprising a modulus contrast E core −E clad of at least 12 GPa.

13. The laminated glass article of claim 11 , wherein the core layer comprises a liquidus viscosity of at least about 30 kP.

14. The laminated glass article of claim 11 , wherein E core /E clad is at least 1.18.

15. The laminated glass article of claim 11 , wherein the cladding layer comprises a compressive stress resulting at least in part from subjecting the laminated glass article to an ion exchange treatment to form an ion exchanged region at an outer surface of the cladding layer.

16. A consumer electronic device, an architectural glass, or an automotive glass comprising the laminated glass article of claim 1 .

17. A method comprising:
contacting a molten core glass with a molten clad glass to form a laminated glass article comprising a glass core layer and a glass cladding layer, the glass core layer comprising a core modulus E core , and the glass cladding layer comprising a cladding modulus E clad ; and
subjecting the laminated glass article to an ion exchange treatment to generate or increase a surface compressive stress of the laminated glass article, wherein
the cladding modulus E clad is at least 5 GPa less than E core , and wherein the glass cladding layer comprises an alkali aluminosilicate glass and wherein:
the core layer comprises a core coefficient of thermal expansion CTE core ; and the cladding layer comprises a cladding coefficient of thermal expansion CTE clad that is greater than or equal to CTE core .

18. The method according to claim 17 , wherein comprising:
the laminated glass article comprises a modulus ratio E core /E clad of at least 1.08.

Assignees

• Corning Inc

Inventors

• Harris Jason Thomas
• Hu Guangli
• Shih Po-Jen
• Zhang Bin
• Zhou Chunfeng

Classifications

• C03C21/002

  to perform ion-exchange between alkali ions (C03C21/005 takes precedence) · CPC title

• C03C17/02

  with glass (C03C17/34, C03C17/44 take precedence) · CPC title

• C03B17/06

  Forming glass sheets · CPC title

• C03B17/02

  Forming {molten} glass coated with coloured layers; {Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts} · CPC title

• B32B17/06 Primary

  comprising glass as the main or only constituent of a layer, next to another layer of a specific {material} · CPC title