Laminated glass article and method for forming the same

Patent metadata

Field	Value
Publication number	US-10399304-B2
Application number	US-201515309055-A
Country	US
Kind code	B2
Filing date	May 7, 2015
Priority date	May 7, 2014
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

A glass article includes a glass core layer and a glass cladding layer adjacent to the core layer. An average coefficient of thermal expansion (CTE) of the core layer is greater than an average CTE of the cladding layer. An effective 10 9.9 P temperature of the glass article is at most about 750° C.

First claim

What is claimed is:

1. A glass article comprising:
a glass core layer; and
a glass cladding layer adjacent to the core layer and comprising a first cladding layer adjacent to a first major surface of the core layer and a second cladding layer adjacent to a second major surface of the core layer opposite the first major surface;
wherein an average coefficient of thermal expansion (CTE) of the core layer is greater than an average CTE of each of the first cladding layer and the second cladding layer, and an effective 10 9.9 P temperature of the glass article is at most about 750° C.

2. The glass article of claim 1 , wherein a degradation rate of the cladding layer in response to exposure to a 5 vol % aqueous HCl solution at 95° C. for 6 h is at most about 0.018 mg/cm 2 or at most about 0.009 mg/cm 2 .

3. The glass article of claim 1 , wherein a degradation rate of the cladding layer in response to exposure to a 1 M aqueous HNO 3 solution at 95° C. for 24 h is at most about 0.08 mg/cm 2 or at most about 0.06 mg/cm 2 .

4. The glass article of claim 1 , wherein a degradation rate of the cladding layer in response to exposure to a 0.02 N aqueous H 2 SO 4 solution at 95° C. for 24 h is at most about 0.04 mg/cm 2 or at most about 0.02 mg/cm 2 .

5. The glass article of claim 1 , wherein a ratio of a thickness of the core layer to a thickness of the glass article is at least about 0.7.

6. The glass article of claim 1 , further comprising a thickness of about 0.2 mm to about 3 mm.

7. The glass article of claim 1 , wherein the effective 10 9.9 P temperature of the glass article is at most about 725° C.

8. The glass article of claim 1 , wherein the glass article is substantially free of a non-glass bonding material disposed between the core layer and the cladding layer.

9. The glass article of claim 1 , wherein:
the core layer comprises from about 45 mol % to about 80 mol % SiO 2 , from about 5 mol % to about 25 mol % Al 2 O 3 , and from about 9 mol % to about 16 mol % Na 2 O; and
the cladding layer comprises from about 65 mol % to about 80 mol % SiO 2 , from about 1 mol % to about 11 mol % Al 2 O 3 , from about 1 mol % to about 11 mol % Na 2 O, and from about 0.1 mol % to about 10 mol % CaO.

10. The glass article of claim 1 , wherein:
the core layer comprises from about 70 mol % to about 80 mol % SiO 2 , from about 5 mol % to about 10 mol % Al 2 O 3 , and from about 9 mol % to about 13 mol % Na 2 O; and
the cladding layer comprises from about 75 mol % to about 80 mol % SiO 2 , from about 1 mol % to about 5 mol % Al 2 O 3 , from about 9 mol % to about 16 mol % B 2 O 3 , from about 2 mol % to about 5 mol % Na 2 O, and from about 0.1 mol % to about 1 mol % CaO.

11. An automotive glazing, a display, or an architectural panel comprising the glass article of claim 1 .

12. The automotive glazing of claim 11 , further comprising a conductive pattern printed on a surface thereof, the pattern comprising at least one of an ink or an enamel.

13. The automotive glazing of claim 12 , wherein the glass article is a shaped glass article, and the conductive pattern comprises a fired enamel.

Assignees

• Corning Inc

Inventors

• Cleary Thomas Michael
• Gomez Sinue
• Hu Guangli
• Schaut Robert Anthony
• Smith Charlene Marie
• Venkataraman Natesan

Classifications

• C03C3/097

  containing phosphorus, niobium or tantalum · CPC title

• C03C3/093

  containing zinc or zirconium · CPC title

• C03C3/091

  containing aluminium · CPC title

• B32B17/06 Primary

  comprising glass as the main or only constituent of a layer, next to another layer of a specific {material} · CPC title

• C03C3/087

  containing calcium oxide, e.g. common sheet or container glass · CPC title