Method for producing coated nickel-based lithium-nickel composite oxide particles

Patent metadata

Field	Value
Publication number	US-11031585-B2
Application number	US-201716073496-A
Country	US
Kind code	B2
Filing date	Jan 27, 2017
Priority date	Jan 28, 2016
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

To provide: coated nickel-based lithium-nickel composite oxide particles which are able to be handled in the atmosphere and enable the achievement of a coating film of a lithium ion conductor having no adverse effects on battery characteristics; and a method for producing the coated nickel-based lithium-nickel composite oxide particles. A method for producing coated nickel-based lithium-nickel composite oxide particles, which comprises: an organic compound radicalization step wherein a radicalized organic compound is obtained by introducing an organic compound having 8 or less carbon atoms into a reaction gas, which has been excited into a plasma in the atmosphere, together with a carrier gas and radicalizing the organic compound; and a coating step wherein the surface of each nickel-based lithium-nickel composite oxide particle is covered with a coating film that contains an organic compound of a polymer or copolymer by bringing the radicalized organic compound into contact with the surfaces of the nickel-based lithium-nickel composite oxide particles.

First claim

The invention claimed is:

1. A method for producing a coated nickel-based lithium-nickel composite oxide particle, comprising:
an organic compound radicalization step of obtaining a radicalized organic compound by introducing an organic compound having 8 or less carbon atoms into a reaction gas, which has been excited into a plasma under the atmosphere, together with a carrier gas and radicalizing the organic compound; and
a coating step of coating a surface of a nickel-based lithium-nickel composite oxide particle with a coat film that contains an organic compound of a polymer or copolymer by bringing the radicalized organic compound into contact with the surface of the nickel-based lithium-nickel composite oxide particle.

2. The method for producing a coated nickel-based lithium-nickel composite oxide particle according to claim 1 , wherein the organic compound having 8 or less carbon atoms is an organic compound including at least one or more kinds selected from the group consisting of an aliphatic compound having 4 or less carbon atoms and an alicyclic compound having 4 or less carbon atoms.

3. The method for producing a coated nickel-based lithium-nickel composite oxide particle according to claim 1 , wherein the organic compound having 8 or less carbon atoms is an organic compound including at least one or more kinds selected from the group consisting of an aliphatic compound having 5 or more to 8 or less carbon atoms, an alicyclic compound having 5 or more to 8 or less carbon atoms, and an aromatic compound having 5 or more to 8 or less carbon atoms.

4. The method for producing a coated nickel-based lithium-nickel composite oxide particle according to claim 1 , wherein the reaction gas includes at least one or more gases selected from the group consisting of argon, helium, nitrogen, oxygen, and air.

5. The method for producing a coated nickel-based lithium-nickel composite oxide particle according to claim 1 , wherein the carrier gas includes at least one or more gases selected from the group consisting of argon, helium, and nitrogen.

6. The method for producing a coated nickel-based lithium-nickel composite oxide particle according to claim 1 , wherein the nickel-based lithium-nickel composite oxide particle is represented by the following Formula (1),
Li x Ni (1-y-z) M y N z O 2   (1)

wherein x is a value of from 0.80 to 1.10, y is a value of from 0.01 to 0.20, z is a value of from 0.01 to 0.15, and 1-y-z is a value exceeding 0.65, and M represents at least one element selected from Co or Mn, and N represents at least one element selected from Al, In or Sn.

7. A coated nickel-based lithium-nickel composite oxide particle for a lithium-ion battery positive-electrode active substance, wherein a coat film of a polymer or copolymer of an aliphatic hydrocarbon compound, or a polymer or copolymer containing an alicyclic hydrocarbon compound is formed all over the surface of a nickel-based lithium-nickel composite oxide particle, so that the coat film prevents the composite oxide particle from contacting the air when the coated nickel-based lithium-nickel composite oxide particle is exposed to the air, wherein a thickness of the coat film is in a range of 4 nm or more to 200 nm or less.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Ota Yosuke

Classifications

• H01M4/366

  as layered products · CPC title

• C01P2004/32

  Spheres · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title