Composition and method for increasing wet and dry paper strength

Patent metadata

Field	Value
Publication number	US-11028538-B2
Application number	US-201916288477-A
Country	US
Kind code	B2
Filing date	Feb 28, 2019
Priority date	Feb 28, 2019
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

A composition for increasing paper strength includes a dialdehyde-modified polyacrylamide strengthening agent, a water soluble compound that is soluble at about 5 wt % or greater in water at about 25° C., and water. The water soluble compound is typically present in a weight amount that is greater than a weight amount of the strengthening agent. The composition is formed by combining the strengthening agent and the water soluble compound in aqueous media to form the composition, wherein on a dry basis the water soluble compound is typically present in a greater amount than the strengthening agent, drying the composition to form a powder or paste that has a water content of less than about 10 weight percent and is stable after storage at about room temperature for about six months, and reconstituting the powder or paste by adding water thereto. The reconstituted composition may then be used to make paper.

First claim

What is claimed is:

1. A composition for increasing paper strength, said composition comprising:
A. a dialdehyde-modified polyacrylamide strengthening agent; and
B. a water soluble compound that comprises one or more hydroxyl or amide moieties and that is soluble at 5 wt % or greater in water at 25° C., and
C. water present in an amount of less than 10 wt %,
wherein said water soluble compound is present in a weight amount that is greater than a weight amount of said dialdehyde-modified polyacrylamide strengthening agent, and
wherein said composition is powdered and has a shelf-life of at least six months such that wet strength and/or dry strength paper performance after six months is at least 80% of wet strength and/or dry strength paper performance measured within one month of manufacture of said composition.

2. The composition of claim 1 wherein said dialdehyde-modified polyacrylamide strengthening agent is a glyoxalated polyacrylamide comprising an aldehyde group.

3. The composition of claim 2 wherein said water soluble compound is chosen from a carbohydrate, a polyvinyl alcohol, an acrylamide containing polymer, or combinations thereof.

4. The composition of claim 1 wherein said water soluble compound is chosen from a carbohydrate, a polyvinyl alcohol, an acrylamide containing polymer, or combinations thereof.

5. The composition of claim 1 wherein said dialdehyde-modified polyacrylamide strengthening agent is cationic and is a copolymer comprising the reaction product of an acrylamide monomer and cationic monomer.

6. The composition of claim 1 that is soluble as an 1 to 5 wt % solution in water at 25° C.

7. The composition of claim 1 wherein said water soluble compound is present in a dry weight ratio with said dialdehyde modified polyacrylamide strengthening agent that is greater than 1:1, respectively.

8. The composition of claim 1 wherein said water soluble compound is present in a dry weight ratio with said dialdehyde modified polyacrylamide strengthening agent that is greater than 3:1, respectively.

9. The composition of claim 1 wherein said water soluble compound is further defined as a copolymer formed from reaction of organic monomers.

10. The composition of claim 1 wherein said water soluble compound is chosen from monosaccharides, disaccharides, polysaccharides, and combinations thereof.

11. The composition of claim 1 wherein said water soluble compound is maltodextrin.

12. The composition of claim 1 wherein said water soluble compound is an acrylamide containing polymer that has a cationic or anionic charge.

13. The composition of claim 1 wherein said water soluble compound is an amphoteric polyacrylamide.

14. The composition of claim 1 wherein said dialdehyde-modified polyacrylamide strengthening agent is the reaction product of:
glyoxal; and
a prepolymer that is the reaction product of a polyacrylamide monomer and a diallyldimethylammonium chloride monomer,
wherein an acrylamide to diallylmethylammonium chloride molar ratio is from 99:1 to 50:50, respectively, and
wherein 40 mol % of acrylamide groups of said polyacrylamide monomer are reacted and 15 mol % of acrylamide groups have active aldehyde functionality.

15. A method of forming a composition for increasing paper strength, said method comprising the steps of:
providing the powdered composition of claim 1 ; and
reconstituting the powdered composition by adding water thereto.

16. The method of claim 15 wherein the dialdehyde-modified polyacrylamide strengthening agent is a glyoxalated polyacrylamide comprising an aldehyde group.

17. The method of claim 15 wherein the water soluble compound is chosen from a carbohydrate, a polyvinyl alcohol, an acrylamide containing polymer, or combinations thereof and the water soluble compound is present in a dry weight ratio with said dialdehyde modified polyacrylamide strengthening agent that is greater than 1:1, respectively.

18. The method of claim 15 wherein the dialdehyde-modified polyacrylamide strengthening agent is the reaction product of:
glyoxal; and
a prepolymer that is the reaction product of a polyacrylamide monomer and a diallyldimethylammonium chloride monomer,
wherein an acrylamide to diallylmethylammonium chloride molar ratio is from 99:1 to 50:50, respectively, and
wherein 40 mol % of acrylamide groups of said polyacrylamide monomer are reacted and 15 mol % of acrylamide groups have active aldehyde functionality.

19. A method for increasing the wet and/or dry strength of paper, said method comprising the steps of:
providing the powdered composition of claim 1 ;
reconstituting the powdered composition;
providing an aqueous slurry of cellulosic fibers;
combining the reconstituted composition and the aqueous slurry of cellulosic fibers; and
forming the paper from the combination of the reconstituted composition and the aqueous slurry of cellulosic fibers wherein the paper has increased wet and/or dry strength as compared to a paper formed without the reconstituted composition.

20. A powdered composition for increasing paper strength, said composition comprising:
A. a GPAM resin that is the reaction product of poly(acrylamide-diallyldimethylammonium chloride) and glyoxal in a 95:5 to 90:10 mole ratio;
B. a water soluble compound; and
C. water present in an amount of less than 10 wt %,
wherein said GPAM resin is present in a dry weight ratio to said water soluble compound of 1:3 to 3:1,
wherein said composition has a shelf-life of at least six months such that wet strength and/or dry strength paper performance after six months is at least 80% of wet strength and/or dry strength paper performance measured within one month of manufacture of said composition, and
wherein the water soluble compound is selected from the group consisting of:
(1) maltodextrin,
(2) an amphoteric polyacrylamide that is the reaction product of acrylamide, acrylic acid, itaconic acid, and dimethylamino-ethylmethacrylate monomers, and
(3) a cationic polyacrylamide comprising a molar ratio of diallyldimethylammonium chloride to polyacrylamide of from 95:5 to 90:10.

Assignees

• Solenis Tech Lp

Inventors

• Borkar Sachin
• Varnell Daniel F

Classifications

• D21H21/36

  Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents · CPC title

• D21H21/20 Primary

  Wet strength agents · CPC title

• D21H17/455

  comprising tertiary amine or being at least partially quaternised · CPC title

• D21H17/375 Primary

  Poly(meth)acrylamide · CPC title

• D21H17/36

  Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters · CPC title