Dialdehyde Modified Acrylamide Type Polymer and Method for Preparing Same

Patent metadata

Field	Value
Publication number	US-2016273167-A1
Application number	US-201415033351-A
Country	US
Kind code	A1
Filing date	Oct 13, 2014
Priority date	Oct 31, 2013
Publication date	Sep 22, 2016
Grant date	—

Abstract

The invention provides a dialdehyde modified acrylamide type polymer for paper making, which is obtained by reacting a dialdehyde with an acrylamide type base polymer, wherein the acrylamide type base polymer is formed by copolymerization of an acrylamide type monomer, a cationic monomer and/or an anionic monomer and a cross linking agent. The invention further provides a method for preparing said dialdehyde modified acrylamide type polymer. The dialdehyde modified acrylamide type polymer according to the invention has improved stability while maintains excellent enhanced performance.

First claim

1 . A dialdehyde modified acrylamide type polymer for paper making, which is obtained by reacting a dialdehyde with an acrylamide type base polymer, wherein the acrylamide type base polymer is formed by copolymerization of an acrylamide type monomer, a cationic monomer and/or an anionic monomer, and a cross linking agent,
wherein the total amount of the cationic monomer and anionic monomer is from 9 mol % to 50 mol %, and wherein the cross linking agent is a monomer having at least two unsaturated double bonds.

2 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein the amount of the cross linking agent is from 0.00001 mol % to 0.1 mol % of the acrylamide type base polymer.

3 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein the cross linking agent is selected from triallylamine, diallylamine, methylenediacrylamide, methylene di(meth)acrylic acid or an ester thereof, diglycol di(meth)acrylic acid or an ester thereof, or glycol di(meth)acrylic acid or an ester thereof.

4 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein the weight average molecular weight of the acrylamide type base polymer is from 6,000 to 20,000 g/mol.

5 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein the acrylamide type base polymer is cationic or amphoteric.

6 . (canceled)

7 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein the cationic monomer is selected from diallyl-N,N-disubstituted ammonium chloride monomer, diallyldimethyl ammonium chloride, N-(3-dimethylaminopropyl)methacrylamide, N-(3-dimethylaminopropyl)acrylamide, methylacroloyloxyethyltrimethyl ammonium chloride, acroloyloxyethyltrimethylammonium chloride, methylacroloyloxyethyldimethylbenzyl ammonium chloride, acroloyloxyethyldimethylbenzyl ammonium chloride, (3-acrylamidepropyl)trimethyl ammonium chloride, methacrylamide propyltrimethylammonium chloride, 3-acrylamido-3-methylbutyltrimethylammonium chloride, 2-vinylpyridine, methacrylate 2-(dimethylamino)ethyl ester, acrylate 2-(dimethylamino) ethyl ester and glycol acrylate, and combinations thereof.

8 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein the anionic monomer is selected from acrylic acid, methacrylic acid, itaconic acid, maleic acid, maleic anhydride, salts thereof, and combinations thereof.

9 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein acrylamide type monomer is acrylamide, methacrylamide, and combinations thereof.

10 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein the dialdehyde is selected from glyoxal, malondialdehyde, succinic aldehyde, glutaraldehyde, and combinations thereof.

11 . The dialdehyde modified acrylamide type polymer of claim 1 , wherein the molar ratio between dialdehyde and the acrylamide monomer is from 0.2 to 0.8.

12 . A method for preparing a dialdehyde modified acrylamide type polymer comprising
(a) copolymerizing an acrylamide type monomer, a cationic monomer and/or anionic monomer, and a cross linking agent to form an acrylamide type base polymer, wherein the total amount of the cationic monomer and anionic monomer is from 9 mol % to 50 mol % of the acrylamide type base polymer, and wherein the cross linking agent is a monomer having at least two vinyls; and (b) reacting the acrylamide type base polymer with a dialdehyde to form the dialdehyde modified acrylamide type polymer.

13 . The method of claim 12 , wherein the cross linking agent comprises from 0.0001 mol % to 0.01 mol % of the base polymer.

14 . The method of claim 12 , wherein the cross linking agent is selected from triallylamine, diallylamine, methylenediacrylamide, methylene diacrylic acid or an ester thereof, or glycol diacrylate, and combinations thereof.

15 . The method of claim 12 , wherein the weight average molecular weight of the acrylamide type base polymer is from 6,000 to 20,000 g/mol.

16 . The method of claim 12 , wherein the acrylamide type base polymer is cationic or amphoteric.

17 . (canceled)

18 . The method of claim 12 , wherein the cationic monomer is selected from diallyl-N,N-disubstituted ammonium chloride, diallyldimethylammonium chloride, N-(3-dimethylaminopropyl)methacrylamide, N-(3-dimethylaminopropyl)acrylamide, methylacroloyloxyethyltrimethylammonium chloride, acroloyloxyethyltrimethylammonium chloride, methylacroloyloxyethyldimethylbenzylammonium chloride, acroloyloxyethyldimethylbenzylammonium chloride, (3-acrylamidepropyl)trimethylammonium chloride, methacrylamidepropyltrimethylammonium chloride, 3-acrylamido-3-methylbutyltrimethylammonium chloride, 2-vinylpyridine, methacrylate-2-(dimethylamino) ethyl ester, acrylate 2-(dimethylamino) ethyl ester and glycol acrylate, and combinations thereof.

19 . The method of claim 12 , wherein the anionic monomer is selected from acrylic acid, methacrylic acid, itaconic acid, maleic acid, maleic anhydride and sails of these acids, and combinations thereof.

20 . The method of claim 12 , wherein the acrylamide type monomer is acrylamide, methacrylamide, and combinations thereof.

21 . The method of claim 12 , wherein the dialdehyde is selected from glyoxal, malondialdehyde, succinic aldehyde, glutaraldehyde, and combinations thereof.

22 . The method of claim 12 , wherein the molar ratio of the dialdehyde to the acrylamide monomer is from 0.3 to 0.5.

23 - 24 . (canceled)

25 . The dialdehyde polymer of claim 1 , wherein the total amount of cationic and anionic monomer is from 10 mol % to 25 mol % of the acrylamide type base polymer.

26 . The dialdehyde polymer of claim wherein the cross linking agent is a monomer having at least two vinyls.

27 . (canceled)

28 . The dialdehyde modified polymer of claim 11 , wherein the molar ratio of dialdehyde to acrylamide monomer is from 0.3 to 0.5.

29 . The method of claim 12 , wherein the cross linking agent is from 0.0001 mol % to 0.001 mol % of the acrylamide type base polymer.

Assignees

• Ecolab Usa Inc

Inventors

• Zhang Meng
• Zhu Bo
• Zhao Yulin
• Shen Jian Kun
• Xu Na

Classifications

• D21H17/00 Primary

  Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution · CPC title

• D21H21/20 Primary

  Wet strength agents · CPC title

• D21H17/375

  Poly(meth)acrylamide · CPC title

• C08F8/00

  Chemical modification by after-treatment (graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C) · CPC title

• C08G69/00

  Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule (products obtained from isocyanates or isothiocyanates C08G18/00; polyamide-imides C08G73/14) · CPC title