Method for producing tetraalkoxysilane

Patent metadata

Field	Value
Publication number	US-11028106-B2
Application number	US-201816955271-A
Country	US
Kind code	B2
Filing date	Dec 25, 2018
Priority date	Dec 27, 2017
Publication date	Jun 8, 2021
Grant date	Jun 8, 2021

Abstract

An object of the present invention is to provide a method capable of producing a tetraalkoxysilane with a high energy efficiency and with a high yield. The present invention provides a method for producing a tetraalkoxysilane, the method including: a first step of reacting an alcohol with a silicon oxide; and a second step of bringing a vaporized component of the reaction mixture obtained in the first step into contact with a molecular sieve.

First claim

The invention claimed is:

1. A method for producing a tetraalkoxysilane, the method comprising:
a first step of reacting an alcohol with a silicon oxide; and
a second step of bringing a vaporized component of the reaction mixture obtained in the first step into contact with a molecular sieve;
wherein:
the first step is carried out in a reactor whose temperature (T 1 ) is controlled within the range of 200° C.<T 1 <300° C.;
the second step is carried out in a container whose temperature (T 3 ) is controlled within the range of 10° C.≤T 3 ≤150° C., and which includes the molecular sieve provided therein;
the vaporized component moves from the reactor to the container through an outward flow path whose temperature (T 2 ) is controlled within the range of 190° C.≤T 2 ≤300° C.; and
a component which has been brought into contact with the molecular sieve in the second step moves from the container to the reactor through an inward flow path.

2. The method for producing a tetraalkoxysilane according to claim 1 , wherein the first step is carried out in the presence of an alkali metal compound and/or an alkaline earth metal compound.

3. The method for producing a tetraalkoxysilane according to claim 2 , wherein the alkali metal compound is at least one selected from the group consisting of an alkali metal hydroxide, an alkali metal halide, an alkali metal carbonate and an alkali metal bicarbonate.

4. The method for producing a tetraalkoxysilane according to claim 1 , wherein the reaction mixture does not comprise a compound for carrying out an azeotropic distillation.

5. The method for producing a tetraalkoxysilane according to claim 3 , wherein the alkali metal compound is at least one selected from the group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, calcium hydroxide, cesium hydroxide, lithium carbonate, sodium carbonate, potassium carbonate, cesium carbonate, sodium fluoride, potassium fluoride and cesium fluoride.

6. The method for producing a tetraalkoxysilane according to claim 1 , wherein the temperature (T 2 ) is controlled within the range of 210° C.≤T 2 ≤300° C., and the temperature (T 2 ) is higher than the temperature (T 1 ).

7. The method for producing a tetraalkoxysilane according to claim 1 , wherein the molecular sieve is 3A zeolite or 4A zeolite.

8. The method for producing a tetraalkoxysilane according to claim 1 , wherein the alcohol is an alcohol having 1 to 10 carbon atoms.

9. The method for producing a tetraalkoxysilane according to claim 2 , wherein the reaction mixture does not comprise a compound for carrying out an azeotropic distillation.

10. The method for producing a tetraalkoxysilane according to claim 2 , wherein the temperature (T 2 ) is controlled within the range of 210° C.≤T 2 ≤300° C., and the temperature (T 2 ) is higher than the temperature (T 1 ).

11. The method for producing a tetraalkoxysilane according to claim 2 , wherein the molecular sieve is 3A zeolite or 4A zeolite.

12. The method for producing a tetraalkoxysilane according to claim 2 , wherein the alcohol is an alcohol having 1 to 10 carbon atoms.

13. The method for producing a tetraalkoxysilane according to claim 3 , wherein the reaction mixture does not comprise a compound for carrying out an azeotropic distillation.

14. The method for producing a tetraalkoxysilane according to claim 3 , wherein the temperature (T 2 ) is controlled within the range of 210° C.≤T 2 ≤300° C., and the temperature (T 2 ) is higher than the temperature (T 1 ).

15. The method for producing a tetraalkoxysilane according to claim 3 , wherein the molecular sieve is 3A zeolite or 4A zeolite.

16. The method for producing a tetraalkoxysilane according to claim 3 , wherein the alcohol is an alcohol having 1 to 10 carbon atoms.

17. The method for producing a tetraalkoxysilane according to claim 4 , wherein the temperature (T 2 ) is controlled within the range of 210° C.≤T 2 ≤300° C., and the temperature (T 2 ) is higher than the temperature (T 1 ).

18. The method for producing a tetraalkoxysilane according to claim 4 , wherein the molecular sieve is 3A zeolite or 4A zeolite.

19. The method for producing a tetraalkoxysilane according to claim 4 , wherein the alcohol is an alcohol having 1 to 10 carbon atoms.

Assignees

• Aist

Inventors

• Fukaya Norihisa
• Choi Seong-Jib
• Choi Jun-Chul
• Horikoshi Toshio
• Kataoka Sho
• Nguyen Thuy
• Sato Kazuhiko
• Hasegawa Minoru
• Kumai Hiroshi

Classifications

• C07F7/04 Primary

  Esters of silicic acids · CPC title

• B01J2208/00017

  Controlling the temperature · CPC title

• B01J8/082

  Controlling processes · CPC title