Helium purification process and unit

Patent metadata

Field	Value
Publication number	US-11021366-B2
Application number	US-202016894205-A
Country	US
Kind code	B2
Filing date	Jun 5, 2020
Priority date	Jun 6, 2019
Publication date	Jun 1, 2021
Grant date	Jun 1, 2021

Abstract

In a helium purification process, a stream containing at least 10% of helium, at least 10% of nitrogen in addition to hydrogen and methane is separated to form a helium-enriched stream containing hydrogen, a first stream enriched in nitrogen and in methane and a second stream enriched in nitrogen and in methane, the helium-enriched stream is treated to produce a helium-rich product and a residual gas containing water, the residual gas is treated by adsorption (TSA) to remove the water and the regeneration gas from the adsorption is sent to a combustion unit (O).

First claim

What is claimed is:

1. A helium purification process, comprising the steps of:
separating, by partial condensation and/or distillation at a partial condensation process and/or distillation process, respectively, a feed stream that contains at least 10% of helium, at least 10% of nitrogen in addition to hydrogen and methane, and which contains no carbon dioxide or only contains carbon dioxide as minor component, to form a helium-enriched stream containing hydrogen, a first stream enriched in nitrogen and in methane, and a second stream enriched in nitrogen and in methane;
sending the helium-enriched stream to a catalytic unit in the presence of oxygen to reduce its hydrogen content;
treating the helium-enriched to at least partly remove water generated by catalysis in the catalytic unit;
purifying, by adsorption in a first adsorption unit, the helium-enriched stream from which at least part of the water has been removed to produce a helium-rich gas comprising at least 95 mol % of helium and a helium-depleted residual gas containing water;
separating the helium-depleted residual gas containing water by adsorption in a second adsorption unit to remove the water, thereby producing a residual gas from which water is removed;
sending the first stream enriched in nitrogen and in methane to a combustion unit to participate in combustion thereof, thereby producing combustion gases that are discharged to the atmosphere or recovered;
sending the second stream enriched in nitrogen and in methane, as regeneration gas, to the second adsorption unit, thereby producing a spent regeneration gas; and
sending the spent regeneration gas to the combustion unit to participate in combustion thereof.

2. The process of claim 1 , further comprising the step of sending the residual gas to the partial condensation process and/or distillation process.

3. The process of claim 2 , wherein the residual gas and the feed stream are compressed upstream of the partial condensation process and/or distillation process in a same compressor.

4. The process of claim 1 , wherein the first and second streams have a same composition.

5. The process of claim 1 , wherein the feed stream contains at least 30 mol % of helium.

6. The process of claim 5 , wherein the feed stream contains at least 40 mol % of helium.

7. The process of claim 1 , wherein the second stream contains at least 85 mol % of nitrogen.

8. The process of claim 1 , wherein the second stream contains at least 1 mol % of methane.

9. The process of claim 1 , in which the first adsorption unit is a pressure swing adsorption unit.

10. The process of claim 1 , in which the second adsorption unit is a temperature swing adsorption unit.

11. A helium purification unit, comprising:
a separation unit for separation by partial condensation and/or by distillation;
a catalytic unit adapted and configured to receive a helium-enriched stream from the separation unit and reduce a hydrogen content thereof in the presence of oxygen;
a cooling unit adapted and configured to receive, from the catalytic unit, the hydrogen-reduced helium-enriched stream, the cooling unit further being adapted and configured to at least partly remove water from the hydrogen-reduced helium-enriched stream, by condensation thereof, that is generated by catalysis in the catalytic unit;
a first adsorption unit adapted and configured to receive an at least partially water-removed and hydrogen-reduced helium-enriched stream from the cooling unit, the first adsorption unit being a pressure swing adsorption unit, the first adsorption unit being further adapted and configured to produce, from the at least partially water-removed and hydrogen-reduced helium-enriched stream, a helium-rich gas comprising at least 95 mol % of helium and a helium-depleted residual gas containing water;
a second adsorption unit adapted and configured to: a) receive helium-depleted residual gas from the first adsorption unit, b) separate the helium-depleted residual gas containing water by adsorption remove water therefrom, thereby producing a residual gas from which water is removed, and c) receive a second stream enriched in nitrogen and in methane from the separation unit, as regeneration gas, and produce a spent regeneration gas, the second adsorption unit being a temperature swing adsorption unit; and
a combustion unit adapted and configured to: a) receive a first stream enriched in nitrogen and in methane, from the separation unit, b) receive the spent regeneration gas, c) producing combustion gases from combustion of the first stream and the spent regeneration gas, and d) discharge the combustion gases to the atmosphere or allow the combustion gases to be recovered.

Assignees

• Air Liquide

Inventors

• Le Guludec Erwan
• Hernandez Antoine

Classifications

• F25J3/08

  Separating gaseous impurities from gases or gaseous mixtures {or from liquefied gases or liquefied gaseous mixtures}(cold traps B01D8/00) · CPC title

• F25J3/0209

  Natural gas or substitute natural gas · CPC title

• C01B23/0021

  by oxidation · CPC title

• B01D53/047

  Pressure swing adsorption · CPC title

• B01D53/0462

  Temperature swing adsorption · CPC title